• Korean Chemical Engineering Research
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• v.47 no.3
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• pp.380-385
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• 2009

The absorption rate of carbon dioxide with 2-amino-2-methyl-1-propanol(AMP) was measured in such non-aqueous solvents as methanol, ethanol, n-propanol, n-butanol, ethylene glycol, propylene glycol, and propylene carbonate, and in water at 298 K and 101.3 kPa using a semi-batch stirred tank with a plane gas-liquid interface. The overall reaction rate constant, obtained under the condition of fast reaction regime, from the measured rate of absorption was used to get the elementary reaction rate constants in complicated reactions represented by reaction mechanism of carbamate formation and the order of overall reaction of $CO_2$ with amine. The correlation between the elementary reaction rate constant and the solubility parameter of the solvent was also presented.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.2 no.1
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• pp.85-90
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• 1998

The reaction rate of $CO_2$ with 2-amino-2-methyl-1-propanol (AMP), MEA monoethanolamine(MEA) and diethanolamine (DEA) in aqueous solutions has been determined using a stirred vessel with a plane gas-liquid interface over a wide range of concentrations of amines at different temperatures. The results show that the overall reaction rate is first order with respect to both $CO_2$ and amine. The reaction rate constant varies with temperature according to the relationship which agrees with the experimental data. The proposed interpretation is that the kinetic rate determining step is a reaction of $CO_2$ with amine to form carbamic acid which is then totally and immediately ionized.

• Journal of Environmental Science International
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• v.2 no.1
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• pp.85-90
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• 1993

The reaction rate of $CO_2$ with 2-amino-2-methyl-1-propanol (AMP), MEA monoethanolamine (MEA) and diethanolamine (DEA) in aqueous solutions has been determined using a stirred vessel with a plane gas-liquid interface over a wide range of concentrations of amines at different temperatures. The results show that the overall reaction rate is first order with respect to both $CO_2$ and amino. The reaction rate constant varies with temperature according to the relationship which agrees with the experimental data. The proposed interpretation is that the kinetic rate determining step is a reaction of $CO_2$ with amine to form carbamic acid which is then totally and immediately ionized.

• Korean Chemical Engineering Research
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• v.56 no.2
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• pp.204-211
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• 2018

In this study, densities of water + N-Methyldiethanolamine (MDEA), Water + 2-Amino-2-Methyl-1-Propanol (AMP), MDEA + AMP binary systems and Water+MDEA+AMP ternary system were measured over the full range of composition at temperatures from 303.15 K to 333.15 K by using an Anton Paar digital vibrating tube densimeter (DMA4500). The experimental excess volumes have been obtained from the experimental density results and have been fitted using the Redlich-Kister-Muggianu expression. The parameters obtained from the binary excess volume data were used for the correlation of ternary system with one additional ternary parameter for each isotherm. All investigated binary and ternary systems are completely miscible, because the values of excess volume are negative under the examined conditions.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• v.2 no.1
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• pp.79-84
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• 1998

The rates of absorption of carbon dioxide into aqueous solutions of 2-amino-2-methyl-1-propanol (AMP) were measured using a semibatch stirred vessel with a plane gas-liquid interface at $25^{\circ}C.$ The absorption rates under the fast reaction regime were analysed using chemical absorption theory. The reaction was found to be first order with respect to both $CO_2$ and the amine.

• Journal of Environmental Science International
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• v.2 no.1
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• pp.79-84
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• 1993

The rates of absorption of carbon dioxide into aqueous solutions of 2-amino-2-methyl-1 propanol (AMP) were measured using a semibatch stirred vessel with a plane gas-liquid interface at $25^{\circ}C$. The absorption rates under the fast reaction regime were analysed using chemical absorption theory. The reaction was found to be first order with respect to both $CO_2$ and the amine.

• Transactions on Semiconductor Engineering
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• v.2 no.2
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• pp.1-9
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• 2024

CMP (Chemical Mechanical Polishing) processes have become essential for creating multilayered component structures in semiconductor manufacturing. Typically, the slurry composition in CMP processes involves a balance of three components such as ceria, dispersant, and deionized water. In this study, we conducted research on the stability of ceria slurries using an amphoteric surfactant with controlled concentrations of AMP (2-Amino-2-methyl-1-propanol). The results indicated pH stabilization influenced by carboxylic (-COOH) groups depending on the AMP concentration. Additionally, there was no occurrence of aggregation in the ceria slurry, confirming the absence of dispersion stability issues.

• Korean Chemical Engineering Research
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• v.45 no.2
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• pp.197-202
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• 2007

This research was basically carried out to extend the application of $CO_2$ absorption processes for flue-gas system, which are mainly applied to a reforming process in petro-chemical industries. In general, MEA absorbent has some problems in flue-gas treatment, such as, degradation, regeneration energy and absorption capacities. As we known, sterical hindered amine, typically AMP (2-amino 2-methyl 1-propanol), have a good potential to improve these problems. In this paper, the characteristics of $CO_2$ absorption in aqueous AMP solution were measured and compared with that of MEA. It has been found that the $CO_2$ absorption capacity in AMP is double than that of MEA in the low $CO_2$ partial pressure system such as flue-gas. Also, the equilibriums of $CO_2$-AMP system were partially suggested, which are essentially needed to design the absorption process.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.185-189
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• 2009

Absorption rate of carbon dioxide into aqueous ammonia absorbent(10 wt%) was measured in the temperature range from 293 K to 337 K using a stirred-cell reactor. The reaction rate constant was correlated with the Arrehnius equation and the activation energy was 50.42 kJ/mol. $CO_2$ absorption rate into modified ammonia absorbent was also investigated. For the modified ammonia absorbent, 1 wt% sterically hindered amines of 2-amino-2-methyl-1-propanol(AMP), 2-amino-2-methyl-1,3-propandiol(AMPD) and 2-amino-2-ethyl-1,3-propandiol(AEPD) were used as additives. The $CO_2$ absorption rate increased by adding 1 wt% of the amine additive, in the case of AMP additive, the absorption rate enhanced by about 53%.

• Korea-Australia Rheology Journal
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• v.20 no.1
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• pp.1-6
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• 2008

Absorption rate of carbon dioxide was measured in the aqueous xanthan gum (XG) solution in the range of 0-0.15 wt% containing 2-amino-2-methyl-1-propanol (AMP) of $0-2\;kmol/m^3$ in a flat-stirred vessel with an impeller of 0.05m and agitation speed of 50rpm at $25^{\circ}C$ and 0.101 MPa. The volumetric liquid-side mass transfer coefficient ($k_La$) of $CO_2$, which was correlated with the viscosity and the elastic behavior of XG solution containing Deborah number as an empirical formula, was used to estimate the chemical absorption rate of $CO_2\;(R_A)$. $R_A$, which was estimated by mass transfer mechanism based on the film theory using the physicochemical properties and the kinetics of reaction between $CO_2$ and AMP, was compared with the measured rate. The aqueous XG solution with elastic property of non-Newtonian liquid made $R_A$ increased compared with Newtonian liquid based on the same viscosity of the solution.