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The Behavior of Microamounts of Americium in Aqueous Solution (수용액중 급위량 Am의 거동)

  • Jae, Won-Mok
    • Nuclear Engineering and Technology
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    • v.18 no.3
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    • pp.194-199
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    • 1986
  • The behavior of micro amount of Am in aqueous solution were investigated with centrifugation method as a function of pH. In the studies described here, equilibration times were extended to 2-3 weeks to know the aging effect in radiocolloid formation. Also, the effect of the addition of foreign materials, e. g. silica gel and Fe$^{3+}$ were examined as well as the effect of presence of concentrated electrolyte. In the results, Am appeared to be rapidly adsorbed on to impurity particles for pH < 6 and probably on the container walls by an ionic sorption process. The addition of foreign material increased the fraction of Am while the addition of concentrated electrolyte hindered the process. For pH > 7 Am behaved quite differently than for pH < 6. There appeared to be rapid sorption of some Am from solution probably on the container walls followed by partial desorption that occurred over a period of 1-2 days.s.

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Effects of Dietary Herb Products(Animunin Powder$^{?}$) on Egg Characteristic, Blood Components, and Nutrient Digestibility in Laying Hens (허브제품(Animunin Powder$^{?}$)의 급여가 산란계의 계란품질과 혈액성상 및 영양소 소화율에 미치는 영향)

  • Shon K. S.;Kwon O. S.;Min B. J.;Cho J. H.;Chen Y. J.;Kim I. H.;Kim H. S.
    • Korean Journal of Poultry Science
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    • v.31 no.4
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    • pp.237-244
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    • 2004
  • This study was conducted to investigate the effects of dietary Animunin Powder$^{?}$ on the egg quality characteristics, blood components and nutrient digestibility in laying hens. A total of two hundred seventy laying hens were randomly allocated into three treaments with fifteen replications for eight weeks. Dietary treaments included 1) Control (CON), 2) Control + $0.1\%$ Animunin Powder$^{?}$ (AM1), 3) Control + $0.2\%$ Animunin Powder$^{?}$ (AM2). During the period of 0~4weeks, the birds fed the AM1 diet had an improved egg production compared to the birds fed the CON (P<0.05). During the period of 4~8weeks the birds fed AM1 diet showed a statistically improved egg production compared to the CON (P<0.05). However, no significant differences were founded in the egg weight. During the period of $4\~8$ weeks the hens fed the AM2 diet had improved egg yolk color compared to the hens fed CON and AM1 diets (P<0.05). In the Haugh unit for the period of $0~4$$weeks, the AM2 treatment showed significantly improved results compared to the CON (P<0.05). Average egg shell breaking showed no significant differences through the experiment period, but in the period of $4\~8$weeks the AM2 treatment tended to be improved compared to the CON and AM1 treatment (P<0.05). There was no significant differences in egg shell thickness. In the serum cholesterol, the AM1 and AM2 treatments were significantly lower than the CON (P<0.05). The concentration of RBC and WBC in the AM treatments tended to increase but there were no significant differences. For the differences of lymphocytes between the end and initiation of the experiment, the hens fed the AM1 treatment were significantly different compared to the hens fed the CON and AM2 treatment (P<0.05). During the period of the experiment, the hens fed the AM1 diet were tended to show higher DM digestibility than the hens fed the CON and AM2 diet, but it was not statistically different. In conclusion, dieatry fed of Animunin Powder$^{?}$ could improve egg production, egg yolk color, and haugh unit.

Spectroscopic Characterization of Aqueous and Colloidal Am(III)-CO3 Complexes for Monitoring Species Evolution

  • Hee-Kyung Kim
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.4
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    • pp.371-382
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    • 2022
  • Carbonates are inorganic ligands that are abundant in natural groundwater. They strongly influence radionuclide mobility by forming strong complexes, thereby increasing solubility and reducing soil absorption rates. We characterized the spectroscopic properties of Am(III)-carbonate species using UV-Vis absorption and time-resolved laser-induced fluorescence spectroscopy. The deconvoluted absorption spectra of aqueous Am(CO3)2- and Am(CO3)33- species were identified at red-shifted positions with lower molar absorption coefficients compared to the absorption spectrum of aqua Am3+. The luminescence spectrum of Am(CO3)33- was red-shifted from 688 nm for Am3+ to 695 nm with enhanced intensity and an extended lifetime. Colloidal Am(III)-carbonate compounds exhibited absorption at approximately 506 nm but had non-luminescent properties. Slow formation of colloidal particles was monitored based on the absorption spectral changes over the sample aging time. The experimental results showed that the solubility of Am(III) in carbonate solutions was higher than the predicted values from the thermodynamic constants in OECD-NEA reviews. These results emphasize the importance of kinetic parameters as well as thermodynamic constants to predict radionuclide migration. The identified spectroscopic properties of Am(III)-carbonate species enable monitoring time-dependent species evolution in addition to determining the thermodynamics of Am(III) in carbonate systems.

Radioanalytical and Spectroscopic Characterizations of Hydroxo- and Oxalato-Am(III) Complexes (방사분석과 분광학을 이용한 Am(III) 가수분해와 옥살레이트 착물 화학종 연구)

  • Kim, Hee-Kyung;Cho, Hye-Ryun;Jung, Euo Chang;Cha, Wansik
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.397-410
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    • 2018
  • When considering the long-term safety assessment of spent-nuclear fuel management, americium is one of the most radio-toxic actinides. Although spectroscopic methods are widely used for the study of actinide chemistry, application of those methods to americium chemistry has been limited. Herein, we purified $^{241}Am$ to obtain a highly pure stock solution required for spectroscopic studies. Quantitative and qualitative analyses of purified $^{241}Am$ were carried out using liquid scintillation counting, and gamma and alpha radiation spectrometry. Highly sensitive absorption spectrometry coupled with a liquid waveguide capillary cell and time-resolved laser fluorescence spectroscopy were employed for the study of Am(III) hydrolysis and oxalate (Ox) complexation. $Am^{3+}$ ions under acidic conditions exhibit maximum absorbance at 503 nm, with a molar absorption coefficient of $424{\pm}8cm^{-1}{\cdot}M^{-1}$. $Am(OH)_3(s)$ colloidal particles formed under near neutral pH conditions were identified by monitoring the absorbance at around 506-507 nm. The formation of ${Am(Ox)_3}^{3-}$ was detected by red-shifts of the absorption and luminescence spectra of 4 and 5 nm, respectively. In addition, considerable enhancements of the luminescence intensities were observed. The luminescence lifetime of ${Am(Ox)_3}^{3-}$ increased from 23 to 56 ns, which indicates that approximately six water molecules are replaced by carboxylate ligands in the inner-sphere of the Am(III). These results suggest that ${Am(Ox)_3}^{3-}$ is formed through the bidentate coordination of the oxalate ligands.

Linear Characteristics Improvement of X-band TWT Amplifier for Satellite Communication with Linearizer (선형화기를 이용한 위성통신용 X-밴드 TWT 증폭기 선형특성 개선)

  • Choi, Won;Yang, Hong-Sun;Koo, Kyung-Heon
    • Journal of Advanced Navigation Technology
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    • v.15 no.5
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    • pp.789-794
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    • 2011
  • This paper has analyzed the AM-AM and AM-PM characteristics of 7.9 GHz~8.4 GHz X-band TWT used for satellite communication and improved its linearity and IMD performance by using linearizer. The TWT amplifier with the linearizer shows better AM-AM and AM-PM conversion, and has increased 1 dB compression point by 12.3 dB and $2.0^{\circ}/dB$ phase distortion point by 10 dB. The 3rd order intermodulation distortion, IMD3 is measured to be 37.0 dBc that is 16.2 dB improvement at the operating output. This paper also proposed the measurement method of IMD for high power amplifier, and that TWT amplifier can have better linearity and output power by compensating for the AM-PM characteristics.

Initial oxidation of the alkali metal-adsorbed Si(111) surface (알칼리금속이 흡착된 Si(111)$7\times7$ 계의 초기 산화 과정 연구)

  • 황찬국;안기석;김정선;박래준;이득진;장현덕;박종윤;이순보
    • Journal of the Korean Vacuum Society
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    • v.6 no.2
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    • pp.159-164
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    • 1997
  • We have studied initial oxidation of the alkali metal(AM)/Si(111) surface using X-ray photoelectron spectroscopy(XPS) and reflection high energy electron diffraction(RHEED) at room temperature(RT) and high temperature(HT)(300~50$0^{\circ}C$). The oxidation of the Si(111)7$\times$7 surface was promoted by the adsorption of 1 momolayer(ML) AM, whereas no promotion occurred for submonolayer(<0.5 ML) adsorbed Si(111)7$\times$7 surface at RT. O Is core level spectra were measured with increasing oxygen exposure. It was found that the oxygen adsorbed on the Si(111)7$\times$7-AM surface have two different bond configuration, Si-O and Am-O, respectively. From these results, we discussed the role of AM-O bonding in the promoted oxidation. At HT(300~50$0^{\circ}C$), the AM-adsorbed surface became very inactive with the structural transformation to the 3$\times$1-AM. We present the results of the oxidation of the Si(111)3$\times$1-AM(Na, K, Cs) surface.

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Assessment of Dietary Requirement of Broiler Chicks for Available Methionine during Summer

  • Nadeem, M.A.;Gilani, A.H.;Khan, A.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.5
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    • pp.772-775
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    • 1999
  • A six week growth performance trial involving 450 birds was conducted to determine the dietary requirement of broiler chicks for available methionine (AM). Body weight gain was significantly (p<0.01) lower on high AM diet (1411 g/bird) than low AM (1470 g/bird) and normal AM (1466 g/bird) diets. The feed intake by birds ranged from $3241{\pm}25.69$ in high AM diet to $3321{\pm}25.69g/bird$ in low AM diet. The feed efficiency for the three diets having low, normal and high level of AM were $2.26{\pm}0.02$, $2.24{\pm}0.02$ and $2.30{\pm}0.02$, respectively. The results indicated that the birds fed high AM diet consumed significantly (p<0.01) more feed per unit body weight gain as compared to birds on low and normal AM diets.

Analysis of Amplitude Distortion in Super Wide-Band AM Signal Transmission (초광대역 AM 신호전송에서의 진폭왜율해석)

  • 이충웅
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.8 no.3
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    • pp.27-32
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    • 1971
  • This paper presents the analysis of the amplitude distortion occurring in the transmission of super wideband AM signal when the amplitude and phase variations of the upper and lower sidebands of the AM signal are symmetrical, and odd symmetrical with respect to the carrier. It is shown that the case where the amplitude variations of the upper and lower sidebands of AM signal are symmetrical with respect to the carrier while the phase variations of the upper and lower sidebands are odd symmetrical with respect to the carrier induce, no amplitude distortion in AM signal transmission.

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A Study on Power Saving Effect Through Introduction of AM Radio High Efficient Transmission System (AM 라디오 고효율전송의 전력 절감 효과 분석)

  • Lee, SangWoon
    • Journal of Broadcast Engineering
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    • v.24 no.4
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    • pp.670-675
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    • 2019
  • AM radio broadcasting has the advantage that the sound quality is lower than that of FM radio but the service area is wide and at night it can be transmitted even to overseas due to ionospheric reflection. AM radio broadcasts usually transmit large amounts of several tens to several hundreds of kilowatts (KW), requiring a lot of power, which is a financial burden on broadcasters. Recently, it is required to introduce a way to reduce the power of AM radio broadcasting in Korea. Therefore, it is possible to save a certain amount of power compared to the conventional AM radio broadcasting, and it is possible to maintain the existing license service area and sound quality, and what policies are needed to introduce the technology. In this paper, we predict the reduction of transmission power when a high efficiency transmission system is applied to existing AM radio broadcasting transmission system. As a result of the research, AMC adopting the high efficiency transmission method instead of the conventional AM radio transmission method, and when the modulation ratio of AM radio is 70%, if -3 dB companding is applied, the annual transmission power charge is decreased from 5,185,838,160Won to 3,528,900,086Won with saving of 32.0%, When -6 dB companding is applied, it is expected to be reduced to 2,608,378,934Won, which is 49.7% savings.

Demodulation and Performance of Multicomponent Undersampled AM, FM and AM-FM Signals (다중 성분의 저표본화된 AM, FM 및 AM-FM 신호들의 복조와 성능)

  • Son, Tae-Ho;Hwang, Ui-Cheon
    • The Transactions of the Korean Institute of Electrical Engineers D
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    • v.49 no.7
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    • pp.399-406
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    • 2000
  • We propose an nonlinear demodulation algorithm for undersampled multicomponent AM(Amplitude Modulation), FM(Frequency Modulation) and AM-FM signals. First, we derive respectively undersampling frequency of the AM, FM and AM-FM using undersampling scheme, and separate respectively monocomponent signals from multicomponent signals using periodic algebraic separation algorithm. In this case augmented separation matrix is very regular and sparse, it has a special structure. The proposed demodulation algorithm detects respectively message signals of the IA(Instantaneous Amplitude) and IF(Instantaneous Frequency) from descrete monocomponent AM, FM and AM-FM signals with an undersampling frequency to be controllable. Verifying the RMS(Root Mean Squares) errors of the detected signals, we show that the performance is excellent.

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