• Title/Summary/Keyword: AL-8

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Synthesis and Luminescent Characteristics of Sr4Al14O25 Phosphor (Sr4Al14O25 형광체의 합성과 발광특성)

  • Han Sang Hyuk;Kim Young Jin
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.529-534
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    • 2004
  • $Sr_{4}Al_{14}O_{25}$ was synthesized by solid state reaction with flux. $H_{3}BO_3$ was used to synthesize $SrO-Al_{2}O_{3}$ phosphor system as a flux. The effect of doping system such as Eu+Dy, Eu, and Ce on the luminescent properties of $Sr_{4}Al_{14}O_{25}$ was investigated. Both PL spectra of $Sr_{4}Al_{14}O_{25}$:Eu and $Sr_{4}Al_{14}O_{25}$:Eu+Dy excited at 390 nm showed greenish-blue emission at about 490 nm, while the emission wavelength was shifted to 400 nm by doping Ce. The reduction of $Eu^{3+}$ ions to $Eu^{2+}$ could be accomplished by the annealing process under $N_{2}^{+}$ vacuum atmosphere, and attributed to the emission at 490 nm. It is verified that $Sr_{4}Al_{14}O_{25}$:Eu phosphor is suitable for white LEDs became of a broad absorption band peaking at 390 nm.

Structural, Electrical and Magnetic Properties of Wide Bandgap Diluted Magnetic Semiconductor CuAl1-xMnxO2 Ceramics (널은 띠간격 묽은 자성반도체 CuAl1-xMnxO2 세라믹스의 구조 및 전자기 특성)

  • Ji Sung Hwa;Kim Hyojin
    • Korean Journal of Materials Research
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    • v.14 no.8
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    • pp.595-599
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    • 2004
  • We investigated the structural, electrical and magnetic properties of Mn-doped $CuAlO_2$ delafossite ceramics ($CuAl_{1-x}Mn_{x}O_2,\;0\le\;x\;\le0.05$), synthesized by solid-state reaction method in an air atmosphere at a sintering temperature of $1150^{\circ}C$. The solubility limit of Mn ions in delafossite $CuAlO_2$ was found to be as low as about 3 $mol\%$. Positive Hall coefficient and the temperature dependence of conductivity established that non-doped $CuAlO_2$ ceramic is a variable-range hopping p-type semiconductor. It was found that the Mn-doping in $CuAlO_2$ rapidly reduced the hole concentration and conductivity, indicating compensation of free holes. The analysis of the magnetization data provided an evidence that antiferromagnetic superexchange interaction is the dominant mechanism of the exchange coupling between Mn ions in $CuAl_{1-x}Mn_{x}O$ alloy, leading to an almost paramagnetic behavior in this alloy.

Texture and Plastic Strain Ratio Changes with the Number of Passes of Asymmetric Rolling in AA1050 Al Alloy Sheet (비대칭 압연 패스 회수에 따른 AA1050 Al 판재의 집합조직과 소성변형비 변화)

  • Nam, Su-Kwon;Jeong, Hae-Bong;Kim, In-Soo
    • Transactions of Materials Processing
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    • v.19 no.8
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    • pp.502-507
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    • 2010
  • The physical and mechanical properties and formability of sheet metals depend on preferred crystallographic orientations (texture). In this research work, the texture development and formability (plastic strain ratios) of AA1050 Al alloy sheets after 3 and 10 passes of asymmetric rolling and subsequent heat treatment were investigated. The plastic strain ratios of 10 passes asymmetrically rolled and subsequent heat treated samples are 1.3 times higher than those of the initial AA1050 Al alloy sheets. The ${\Delta}r$ of 10 passes of asymmetrically rolled and subsequent heat treated samples is 1/30 times lower than those of the initial AA1050 Al alloy sheets. The plastic strain ratios of 10 passes of asymmetrically rolled and subsequent heat treated Al sheets are higher than those of 3 passes ones. These results could be attributed to the formation of $\gamma$-fiber, ND//<111>, and the other texture components by means of asymmetric rolling in Al sheets.

Hydrothermal Stability of (Y, Nb)-TZP/$Al_2O_3$ Composites

  • Lee, Deuk-Yong;Kim, Dae-Joon;Lee, Seung-Jae
    • The Korean Journal of Ceramics
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    • v.5 no.4
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    • pp.371-374
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    • 1999
  • Y2O3 and Nb2O5 co-doped tetragonal zirconia polycrystals((Y, Nb)-TZP) containing 10 to 30 vol% $Al_2O_3$ were prepared and hydrothermal stability of the composites was evaluated after aging for 5 h at the temperature range of $150^{\circ}C$ $250^{\circ}C$ under 4 MPa $H_2O$ vapor pressure in an autoclave. The (Y, Nb)-TZP/Al2O3 composites showed excellent phase stability under the hydrothermal conditions, as compared with the 3Y-TZP/$Al_2O_3$ composites, due to the combined effects of the Y-Nb ordering in the $t-ZrO_2$ lattice, the reduction of oxygen vacancy concentration, and the $Al_2O_3$ addition. The strength and fracture toughness of the (Y, Nb)-TZP/$Al_2O_3$ composite, containing 20 vol% of 2.8 $Al_2O_3$ particles, were 700 MPa and 8.1 MP.$am^{1/2}$, respectively.

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Fabrication and Wear Behavior of Nano-sized Metal Particle Dispersed Al2O3 Nanocomposites (나노크기 금속입자가 분산된 Al2O3 나노복합재료의 제조 및 마모거동)

  • Oh Sung-Tag;Yoon Se-Joong;Jeong Young-Keun
    • Korean Journal of Materials Research
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    • v.15 no.8
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    • pp.503-507
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    • 2005
  • Microstructure and wear behavior of A1203-based nanocomposites with Cu and Ni-Co dispersions were investigated. $Al_2O_3/Cu$ and $Al_2O_3/Ni-Co$ nanocomposites were fabricated by hydrogen reduction and sintering method using metal oxide and metal nitrates. The nanocomposites showed increased mechanical properties compared with monolithic $Al_2O_3$. In particular, high toughness and hardness were measured for the $Al_2O_3/Ni-Co$ nanocomposite consolidated by spark plasma sintering. A minimum value of wear coefficient comparable to the monolithic $Al_2O_3$ was obtained for $Al_2O_3/Ni-Co$ nanocomposite. Wear behavior is discussed in terms of microstructure and mechanical properties of nanocomposites

Effect of Al Doping on the Properties of ZnO Nanorods Synthesized by Hydrothermal Growth for Gas Sensor Applications

  • Srivastava, Vibha;Babu, Eadi Sunil;Hong, Soon-Ku
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.399-405
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    • 2020
  • In the present investigation we show the effect of Al doping on the length, size, shape, morphology, and sensing property of ZnO nanorods. Effect of Al doping ultimately leads to tuning of electrical and optical properties of ZnO nanorods. Undoped and Al-doped well aligned ZnO nanorods are grown on sputtered ZnO/SiO2/Si (100) pre-grown seed layer substrates by hydrothermal method. The molar ratio of dopant (aluminium nitrate) in the solution, [Al/Zn], is varied from 0.1 % to 3 %. To extract structural and microstructural information we employ field emission scanning electron microscopy and X-ray diffraction techniques. The prepared ZnO nanorods show preferred orientation of ZnO <0001> and are well aligned vertically. The effects of Al doping on the electrical and optical properties are observed by Hall measurement and photoluminescence spectroscopy, respectively, at room temperature. We observe that the diameter and resistivity of the nanorods reach their lowest levels, the carrier concentration becomes high, and emission peak tends to approach the band edge emission of ZnO around 0.5% of Al doping. Sensing behavior of the grown ZnO nanorod samples is tested for H2 gas. The 0.5 mol% Al-doped sample shows highest sensitivity values of ~ 60 % at 250 ℃ and ~ 50 % at 220 ℃.

Influences of Precipitation of Secondary Phase by Heat Treatment on Thermal Properties of Al-4.5%Cu Alloy (열처리에 따른 제2상 석출이 Al-4.5%Cu 합금의 열 물성에 미치는 영향)

  • Choi, Se-Weon
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.435-440
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    • 2020
  • The relationship between the precipitation of secondary phase and the thermal properties of Al-4.5%Cu alloy (in wt.%) after various heat treatments has been studied. Solid solution treatment of alloy was performed at 808 K for 6 hours, followed by warm water quenching; then, the samples were aged in air at 473 K for different times. The thermal diffusivity of the Al-4.5%Cu alloy changed with the heat treatment conditions of the alloy at temperatures below 523 K. The as-quenched specimen had the lowest thermal diffusivity, and as the artificial aging time increased, the thermal diffusivity of the specimen increased in the temperature range between 298 and 523 K. For the specimen aged for five hours, the thermal conductivity was 12% higher than that of the as-quenched specimens at 298 K. It is confirmed that the thermal diffusivity and thermal conductivity of the Al-4.5%Cu alloy significantly depend on their thermal history at temperatures below 523 K. The precipitation and dissolution of the Al2Cu phase were confirmed via DSC for the alloys, and the formation of coefficient of thermal expansion peaks in TMA was caused by precipitation. The precipitation of supersaturated solid solution of Al-4.5%Cu alloys had an additional linear expansion of ≈ 0.05 % at 643 K during thermal expansion measurement.

Effects of Na2O Content on Characteristics of $\beta$-Al2O3 ($\beta$-Al2O3의 특성에 미치는 Na2O의 영향)

  • 윤기현;김응수;송효일
    • Journal of the Korean Ceramic Society
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    • v.24 no.1
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    • pp.9-16
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    • 1987
  • Physical and electrical properties of ${\beta}$-Al2O3 were investigated as function of Na2O content from 6.67 wt.% to 13.19 wt.%. The majority phase is ${\beta}$-Al2O3 and the small amount of ${\beta}$"-Al2O3 exists in the specimens sintered at 1600$^{\circ}$for 30 mins. In the case of specimens with 8.54 wt.% Na2O sintered at 1600$^{\circ}C$, the relative amount of ${\beta}$-Al2O3 phase increases and that of ${\beta}$"-Al2O3 phase decreases with increasing sintering time, and then ${\beta}$"-Al2O3 phase does not exist if sintering time is over 8 hrs. As the Na2O content is increased, the 3-Point MOR and the resistivity are decreased. However, density and 3-Point MOR with increasing sintering time are decreased due to increasing the enclosed pore trapped inside of the exaggerated grains. As the sintering time is increased, the average grain size and the duplexity of microstructure are increased, and the resistivity is slightly decreased.

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Momentum Effect in the Oman Stock Market Over the Period of 2005-2018

  • GHARAIBEH, Omar Khlaif;AL-KHAZALI, Ahmad;AL-QURAN, Ali Zkariya
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.2
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    • pp.711-724
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    • 2021
  • The purpose of this paper is to investigate the profitability of the momentum effects on the Oman Stock Market (OSM). This study uses the monthly returns of all stocks listed on the OSM, with a total of 107 companies used in the study for the period from 2005 to 2018. According to the methodology developed by Jegadeesh and Titman (1993), this study builds momentum portfolios based on various sizes. Moreover, the January effect is also examined to recognize if this effect is related to the momentum effect. The results find that there is evidence of momentum returns and these returns are statistically and economically significant. The sub-periods confirmed the profitability of the momentum strategy. This paper shows that momentum returns are evident at different sizes; big, medium, and small-sized portfolios. Besides, the result shows that the classic January effect does not play an important role in the momentum returns. Thus, the implication is that the momentum should not take into account the annual, seasonal, and size returns. The capital asset pricing model (CAPM) or the three-factor model cannot explain momentum returns generated by individual stocks in the Oman Stock Market. These results are useful to academia and investors alike.

Characterization of Oxide Scales Formed on Fe3Al, Fe3Al-Cr, Fe3Al-Cr-Mo, Ni3Al and Ni3Al-Cr Alloys (Fe3Al, Fe3Al-Cr, Fe3Al-Cr-Mo, Ni3Al 및 Ni3Al-Cr 합금표면에 형성된 산화물 특성분석)

  • Shim, Woung-Shik;Lee, Dong-Bok
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.845-849
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    • 2002
  • Alloys of $Fe_3$Al, $Fe_3$Al-6Cr, $Fe_3$Al-4Cr-1Mo, $Ni_3$Al, and $Ni_3$Al-2.8Cr were oxidized at $1000^{\circ}C$ in air, and the oxide scales formed were studied using XRD. SEM, EPMA, and TEM. The oxide scales that formed on $Fe_3$Al-based alloys consisted primarily of $\alpha$-$Al_2$$O_3$ containing a small amount of dissolved Fe and Cr ions, whereas those that formed on $Ni_3$Al-based alloys consisted primarily of $\alpha$-$Al_2$$O_3$, together with a small amount of $NiAl_2$$O_4$, NiO and dissolved Cr ions. For the entire alloys tested, nonadherent oxide scales formed, and voids were inevitably existed at the scale-matrix interface.