• Title/Summary/Keyword: AEM

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Preparation and Characterization of Pt-Fe/Carbon Black Nanocatalyst for Anion Exchange Membrane in Alkaline Electrolysis (음이온 교환막 수전해용 Pt-Fe/카본블랙 나노 촉매 제조 및 특성)

  • SUNGKOOK CHO;JAEYOUNG LEE;HONGKI LEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.6
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    • pp.715-722
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    • 2022
  • Pt-Fe/carbon black nanocatalysts were prepared by spontaneous reduction reaction of Platinum(II) acetylacetonate and Iron(II) acetylacetonate in a nucleophilic solvent and they were characterized by scanning electron microscopy (SEM), energy dispersive X-ray analyzer (EDS), thermogravimetric analyzer (TGA), transmission electron microscopy (TEM), Brunauer, Emmett and Teller (BET) surface area analysis and anion exchange membrane (AEM) water electrolysis test station. The distribution of the Pt and Fe nanoparticles on carbon black was observed by TEM, and the loading weight of Pt-Fe nanocatalysts on the carbon black was measured by TGA. Elemental ratio of Fe:Pt was estimated by EDS and it was found that elemental ratio of Pt and Fe was changed in the range of 1:0 to 0:1, and the loading weight of Pt-Fe nanoparticles on the carbon black was 5.95-6.78 wt%. Specific surface area was greatly reduced because Pt-Fe nanocatalysts blocked the pores. I-V characteristics were estimated.

Electricity Generation and Microbial Community Structure Variation Depending on Separator Types and Cathode Characteristics in Air-cathode MFC (공기환원전극 미생물연료전지에서 분리막 종류 및 환원전극 특성에 따른 전기발생 및 미생물 군집구조 변화)

  • Yu, Jae-Cheul;Lee, Chang-Yeol;Kim, Sun-Ah;Cho, Hae-In;Cho, Sun-Ja;Lee, Tae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.2
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    • pp.113-120
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    • 2010
  • Air-cathode microbial fuel cell consisted of 4 unit cells were operated under batch condition and electricity generation and microbial community structure variation were investigated, depending on separator types and cathode characteristics: A) PEM(Proton Exchange Membrane)-30% Wet proofing Carbon Cloth(WC), B) AEM(Anion Exchange Membrane-WC, C) CEM(Cation Exchange Membrane)-WC, D) PEM-No Wet proofing Carbon Cloth(NC). Maximum power densities of PEM-WC, AEM-WC and CEM-WC were 510.9, 522.1 and 504.8 $mW/m^2$, respectively. But PEM-NC showed relatively lower maximum power density of 218.3 $mW/m^2$. And PEM-WC, AEM-WC and CEM-WC showed similar internal resistances(20.0-28.2 ${\Omega}$). PCRDGGE, PCA and diversity indices showed that uncultured bacteria which reported in previous MFC studies were detected in suspended growth bacteria and attached growth bacteria would be affected not by separator type but by cathode characteristic. Thus, cathode characteristic can be one of the critical factors for power generation in air-cathode MFC using PEM, AEM, and CEM as separator.

Detection of Earnings Management as a Measure of Income Smoothing on Fluctuations in Exchange Rates: Managerial Implications for Korean Exporters

  • Ji, Sang-Hyun
    • Journal of Korea Trade
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    • v.23 no.6
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    • pp.66-92
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    • 2019
  • Purpose - Foreign Exchange Rates (FER) have been one of the most significant factors for both Korean exporters and the economy of Korea. The purpose of this study is to evaluate whether exporters with a high level of Exchange Rate Elasticity of Sales (ERES) make the use of earnings management for Income Smoothing (IS). Design/methodology - Income smoothing was obtained using the methodology suggested by Leuz, Nanda and Wysocki (2003). Accruals-based Earnings Management (AEM) was estimated using Discretionary Accruals (DA) calculated by the operant Jones Model developed by Dechow, Sloan and Sweeney (1995). Real Earnings Management (REM) was obtained using the methodologies suggested by Roychowdhury (2006) and Cohen and Zarowin (2010). Data were 2,402 firm years of public listed companies on the KRX, which were not in the financial industry and had a settlement of accounts in December for the period from 2013 to 2017. Findings - Results of the evaluation are as follows. First, companies with higher levels of ERES have relatively lower levels of smoothing of reported income. This might be because a fluctuation in sales caused by an exchange rate fluctuation has a direct impact on the volatility of the reported income. Second, companies with high levels of both ERES and IS have a positive correlation with both AEM and REM. This might be because companies with high levels of IS engage in earnings management to smooth reported income. Specifically, it is possible to assume that for smoothing the reported income, not only AEM but also REM is practiced. Third, companies with high levels of ERES but low levels of IS have a negative correlation with both AEM and REM. This could be interpreted as companies exhibiting low levels of IS due to higher levels of ERES tend to control IS. In addition, such results were supported by firms relying highly on exporting, and are consequently sensitive to exchange rate fluctuation. Therefore, it may conclude that companies with high levels of ERES make the use of earnings management as a means of IS. Originality/value - This study can find its significance from the fact that it is the first study, empirically verifying that companies of Korea, where exportation is a large part, use both AEM and REM as a means for smoothing reported income upon facing exchange rate fluctuations. In addition, it is highly expected that the results of this study could be useful for participants of financial markets when making IS-related decisions.

Photopolymerization efficiency of dental resin composites with solid amine photoinitiators (고체 amine 광개시제에 따른 치과용 복합수지의 중합효율)

  • Sun, Gum-Ju
    • Journal of Technologic Dentistry
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    • v.28 no.1
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    • pp.43-52
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    • 2006
  • Three t-amines, 4-(dimethylamino)benzoic acid (ABA), 4-(dimethylamino)benzaldehyde (MBA), 4-(dimethylamino)benzophenone (MBP), were investigated as new visible light photoinitiators for a dental resin composite of UDMA in order to improve photopolymerization effect. Three t-amines mixed with three photosensiizers, CQ, PD and DA, respectively. And the photopolymerization effect of photoinitiators were compared with that of 4-(dimethylamino)ethyl methacrylate (AEM), the most widely used photoinitiator. The photopolymerization efficiency of UDMA containing the photoinitiator increased with irradiation time. The increase was in the order: MBP

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Application of Advanced Blast Demolition Simulation Method to the Drill and Blast Design for Demolishing Cylindrical Structures (원통형 구조물의 발파해체설계에 대한 최신 발파해체 시뮬레이션 기법의 적용)

  • Park, Hoon;Suk, Chul-Gi;Kim, Seung-Kon
    • Explosives and Blasting
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    • v.26 no.1
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    • pp.7-14
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    • 2008
  • In order to complete successfully the demolition of a silo structure by means of felling method, structural properties and the geometric design of blast mouth have to be considered. In this study, a commercial software, 3-dimensional applied element analysis (3D AEM), was used to investigate the effect of the geometrical parameters of blast mouth on the collapse behavior of the silo structure.

Reaction Bonding of $ZrO_2$ and NiTi : Reaction Products Analyses on $ZrO_2/NiTi$ Bonding Interface with AEM ($ZrO_2$와 NiTi 합금의 반응접합 : 분석투과전자현미경을 이용한 $ZrO_2/NiTi$ 접합층 반응생성물 분석)

  • Kim, Young-Jung;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.949-954
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    • 1993
  • Microstructural development at the ZrO2/NiTi bonding interface and reaction products were examined and identified with SEM and AEM. Ti-oxide, Ti2Ni and Ni2Ti layer were observed whose thickness depends on bonding temperature typically. The development of Ti-oxide layer is related with oxygen ion in ZrO2 and liquid phase Ti2Ni. It is considered that compositional deviation from homogeneity and residual stress caused by thermal expansion mismatch are closely related with the formation of the Ti2Ni phase.

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ADAPTABLE ELLIPSE METHOD FOR BRIDGE COATING DEFECT RECOGNITION

  • Po-Han Chen;Ya-Ching Yang;Luh-Maan Chang
    • International conference on construction engineering and project management
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    • 2009.05a
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    • pp.449-456
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    • 2009
  • Image processing has been applied to steel bridge defect recognition since 1990s. Compare to human visual inspection, image processing provides a more objective and accurate way of assessment. Since shade and shadow may sometimes occur when taking bridge coating images, non-uniform illumination problems should be considered. By means of color image processing, this paper aims to mitigate the illumination effect for bridge coating assessment. Furthermore, the adaptable ellipse method (AEM) is proposed to recognize mild rust colors. Finally, AEM will be compared to the K-Means algorithm, a popular recognition method, to show its advantage.

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Cation exchange membrane and anion exchange membrane aided electrolysis processes for hypochlorite generation

  • Seong K. Kim;Dong-Min Shin;Ji Won Rhim
    • Membrane and Water Treatment
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    • v.14 no.2
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    • pp.55-63
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    • 2023
  • In this study, the influence of different IEMs (ion exchange membranes) to performance of the hypochlorite electrolysis unit with Cl2 recovery stream was investigated. More specifically, Nafion 117-a representative cation exchange membrane (CEM)-and aminated polypheylene oxide (APPO)-an anion exchange membrane (AEM)-were installed in the hypochlorite electrolysis unit, and the performance and the energy efficiency of the units were evaluated and compared. Regardless of whether CEM (Nafion 117) or AEM (APPO) was installed, the rate of hypochlorite generation was increased (by up to 24.3% and 22.2% for Nafion 117 and APPO, respectively) compared with the unit without an IEM. On the other hand, the power efficiency and the optimum operation condition of hypochlorite production units seem to depend on the conductivity and stability of the installed IEM. As the result, between Nafion 117 and APPO, higher performance and efficiency were achieved with Nafion 117, due to excellent conductivity and stability of the membrane.