• Title/Summary/Keyword: ACETYLENE

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Formation of Shell-Shaped Carbon Nanoparticles through Critical Transition in Irradiated Acetylene (레이저가 조사된 아세틸렌에서의 임계전이를 거쳐서 형성된 쉘 형상 카본 나노입자에 관한 연구)

  • Choi, Man-Soo;Altman, Igor S.;Kim, Young-Jeong;Pikhitsa, Peter V.;Lee, Sang-Hoon
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1158-1161
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    • 2004
  • Shell shaped hollow carbon nanoparticles are synthesized in the oxygen-hydrogen diffusion flame with $C_{2}H_{2}$ as precursor when it is irradiated with $CO_{2}$ laser of certain power. Below this power of laser, we couldn't get any other but amorphous soot. This shell shaped hollow carbon nanoparticles shows outer wall of high degree of crystallinity with void space inside of itself. And size distribution of these nanoparticles is measured with TEM image analysis. Also the structural comparison between this carbon nanoparticle and soot is done by Raman and XRD measurement. These results show this carbon nanoparticles are of grapheme structure, which means it has good crystallinity when compared with soot.

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Transformation of cis-1,2-Dichlororethylene and its Epoxide by a Butane-Grown Mixed Culture

  • Kim, Young;Lewis Semprini
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.147-152
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    • 2004
  • Aerobic cometabolism of cis-1,2-dichloroethylene (c-DCE) and c-DCE epoxide by a butane-grown mixed culture was evaluated. Transformation of c-DCE resulted in the concomitant generation of c-DCE epoxide. Chloride release studies showed nearly complete oxidative dechlorination of c-DCE (approximately 75%). Mass spectrometry confirmed tile presence of a compound with mass-to-charge-fragment ratios of 112, 83, 48, and 35. The values are in agreement with the spectra of a chemically synthesized c-DCE epoxide. Some evidences indicating the involvement of the monooxygenase in the transformation of c-DCE epoxide are: 1) $O_2$ requirement for c-DCE transformation and butane degradation; 2) butane inhibition on c-DCE transformation and vice versa; 3) the inactivation of c-DCE and c-DCE epoxide transformations by acetylene (a known monooxygenase inactivator); and 4) tire inhibition of c-DCE epoxide transformation by c-DCE.

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Associated Nitrogen Fixation in the Rhizosphere of Rice in Saline and Reclaimed Saline Paddy Soil -1. Enumeration of aerobic heterotrophic bacteria associated in histosphere of grasses and rice (간척지토양(干拓地土壤)의 수도근권(水稻根圈)에서 협생질소고정(協生窒素固定)에 관(關)한 연구(硏究) -제(第)1보(報) 수도(水稻) 및 자연생잡초(自然生雜草) 근조직내(根組織內) 협생질소고정균(協生窒素固定菌)의 분리동정(分離同定))

  • Lee, Sang Kyu;Suh, Jang Sun;Ko, Jae Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.1
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    • pp.69-76
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    • 1987
  • The aerobic heterotrophic bacteria in the histosphere associated with grasses (Gramineae, Caryphyllaceae, Crucifereae) and rice cultivars in saline and reclaimed saline paddy soils were varied with species and rice cultivars. The fraction of aerobic heterotrophic $N_2$-fixing bacteria to the total aerobic heterotrophic bacteria were averaged to eighteen percent in the histosphere of grasses and rice. Acetylene reducing activity of these bacteria were ranged from 1 to 24 n mole/tube/hr. Most of the bacteria strains were predominated of hydrogen utilizing bacteria. The majority of these bacteria were closed to Pseudomonas, Azospirillum, Klebsiella and Agrobacter.

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Synthesis of Stepped Carbon Nanotubes in Anodic Aluminum Oxide Templates (알루미나 형틀을 이용한 서로 다른 직경을 갖는 모양을 가진 탄소나노튜브의 합성)

  • Im Wan-soon;Cho You-suk;Choi Gu seok;Kim Dojin
    • Korean Journal of Materials Research
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    • v.14 no.9
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    • pp.664-669
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    • 2004
  • Anodic aluminum oxide (AAO) with pores of various diameter, density, and thickness values was obtained through control of the anodization parameters including voltage, temperature, pore widening time, anodization time, etc. The pore diameter was controlled by a pore widening in an etchant, and alumina templates having stepped nano-channels were fabricated by repetition of anodization and pore widening processes. Stepped carbon nanotubes (CNTs) were then grown on the stepped AAO templates by pyrolysis of acetylene without using the catalyst. High-resolution transmission electron microscopy images revealed that CNTs have a multi-wall structure made of graphite flakes of several nm sizes. The current-voltage characteristic of the sloped and linear CNTs were also examined.

Development of Power Transformer Maintenance System Using Intelligent Dissolved Gas in Oil Analysis (지능형 유중가스분석법을 이용한 전력용 변압기 관리시스템 개발)

  • Sun, Jong-Ho;Kim, Kwang-Hwa
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2004.11a
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    • pp.87-90
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    • 2004
  • This paper describes development of power transformer maintenance system using intelligent dissolved gases in oil analysis. The used gases are acetylene(C2H2), hydrogen(H2), ethylene(C2H4), methane(CH4), ethane(C2H6), carbon monoxide(CO) and carbon dioxide(CO2). The rule and neural network based gas analysis methods are used for artificial intelligent diagnosis. It is indicated that this program is efficient for diagnosis of oil immersed transformers diagnosis from application of gas analysis data of serviced transformer which has local overheating

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Study on the Splat Formation of Ni-based Thermal Sprayed Coatings (니켈기 용사코팅의 스플랫 형성에 관한 연구)

  • Kim, K.T.;Lee, S.S.;Lee, D.H.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.16 no.2
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    • pp.49-53
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    • 2012
  • Thermal spray coatings developed by deposition of splats, it formed by impacting molten droplets on substrates during thermal spray process. In this study, the Ni-based coatings were fabricated by thermal spray process with two different process parameters, oxygen gas flow and acetylene gas flow, with three different levels of each parameters. The morphology of splats and microstructure were observed by optical microscope. Hardness test were performed on the Ni-based coatings. It was confirmed that process parameters of thermal spray process have effect in morphology of splats. These effects also have important implications on the deposit microstructure and properties of Ni-based coatings.

Optimization for Thermal spray Process by Taguchi Method (다구찌 기법을 이용한 용사코팅의 공정 최적화)

  • Kim, K.T.;Kim, Y.S.
    • Journal of Power System Engineering
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    • v.16 no.2
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    • pp.54-59
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    • 2012
  • In the present study, process optimization for thermal-sprayed Ni-based alloy coating has been performed using Taguchi method and analysis of variance(ANOVA). Ni-based alloy coatings were fabricated by flame spray process on steel substrate, and the hardness test and wear test were performed. Experiments were designed as per Taguchi's L9 orthogonal array and tests were conducted with different Oxygen gas flow, Acetylene gas flow, Powder feed rate and Spray distance. Multi response signal to noise ratio (MRSN) was calculated for the response variables and the optimum combination level of factors was obtained simultaneously using Taguchi's parametric design.

Preparation of fluorescent nucleic acids generating unique emission by primer extension reaction using pyrene-labeled deoxyuridine triphosphate derivatives

  • Takada, Tadao;Tanimizu, Yosuke;Nakamura, Mitsunobu;Yamana, Kazushige
    • Rapid Communication in Photoscience
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    • v.3 no.4
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    • pp.76-78
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    • 2014
  • Fluorescent nucleic acids were prepared utilizing the polymerase extension (PEX) reaction to incorporate fluorescent molecules. 2'-Deoxyuridine triphosphate (dUTP) derivatives possessing pyrene molecules as fluorophores were synthesized using the aqueous-phase Sonogashira coupling between 5-Iodo-dUTP and acetylene-linked pyrene molecules. The incorporation of the pyrene (Py)-labeled deoxyuridine triphosphates (PyU) into DNA by polymerase was evaluated by polyacrylamide gel electrophoresis, demonstrating that the PyU can work as a good substrate for the PEX reaction. The fluorescent properties of the functionalized DNA prepared by the PEX reaction were characterized by steady-state fluorescence measurements. The Py-conjugated DNA showed typical emission spectra of the pyrene, and the DNA with two pyrene molecules connected to each other by a diethylene glycol linker exhibited a broadened emission attributed to the electronic interaction between the Py molecules.

Characterization of a Rhizobacterium Promoting Early Growth in Maize (옥수수 초기 성장을 촉진하는 근류세균의 특성)

  • Lee Sang-Eun;Yi Hwe-Su;Park Seung-Hwan;Ghim Sa-Youl
    • Microbiology and Biotechnology Letters
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    • v.33 no.1
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    • pp.70-73
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    • 2005
  • A soil bacterium was isolated from maize roots cultivated in Korea (KNUC153). The isolate was partially classified on basis of l6S rDNA sequence analysis as Stenotrophomonas maltophilia. By the acetylene reduction assay (ARA), the strain KNUC153 contained nitrogen-fixing abilities. The amount of auxin produced by the strain KNUC153 was $77.6\;{\mu}g/ml$. The strain KNUC153 produced 4 times higher amount of l-amino-cyclopropane-l-carboxy­lic acid deaminase than that of the other known strain Azospirillum sp. KNUC82. Inoculation treatment with the strain KNUC153 for maize seeds showed positive effect on early growth of the plants.

Effect of gas detonation on response of circular plate-experimental and theoretical

  • Babaei, Hashem;Mostofi, Tohid Mirzababaie;Sadraei, Seyed Hamidreza
    • Structural Engineering and Mechanics
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    • v.56 no.4
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    • pp.535-548
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    • 2015
  • A series of experimental results on thin mild steel plates clamped at the boundary subjected to gas detonation shock loading are presented. Detonation occurred by mixing Acetylene (C2H2)-Oxygen (O2) in various volume ratio and different initial pressure. The applied impulse is varied to give deformation in the range from 6 mm to 35 mm. Analytical modeling using energy method was also performed. Dependent material properties, as well as strain rate sensitivity, are included in the theoretical modeling. Prediction values for midpoint deflections are compared with experimental data. The analytical predictions have good agreement with experimental values. Moreover, it has been shown that the obtained model has much less error compared with those previously proposed in the literature.