• Title/Summary/Keyword: A2058

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Synthesis of m-Oxo and Bis( m-alkoxo) Bridged Diiron(III) Complexes Using a Tripodal Ligand, Bis(2-benzimidazolylmethy)ethanolamine

  • Gwak, Byeong Hun;Lee, Myeong Su
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.65-68
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    • 2000
  • A $\mu-oxo$ diiron(III) complex and two bis( $\mu-alkoxo)$ diiron(III) complexes with biomimetic tripodal ligand containing mixed N/O donor atoms were synthesized using a mononuclear iron(III) complex as starting material. Depending on the amounts and kinds of bases used, we obtained various kinds of diiron (III) complexes. The reaction of $[$Fe^{III}$(Hbbea)Cl_2]Cl$, 1, with an equivalent amount of $KO_2$ or NaOAc produced $[$Fe^{III}$_2O(Hb-bea)_2Cl_2]Cl_2$, 2. An additional equivalent amount of NaOBz or NaOAc converts complex 2 to complex 3 or complex 4 depending on the base used. The addition of two equivalent amounts of NaOBz orNaOAc directly converts complex 1 to $[$Fe^{III}$_2(bbea)_2(OBz)_2]Cl_2$, 3, or $[$Fe^{III}$_2(bbea)_2(OAc)_2]Cl_2$, 4, depending on the base used. Crystal data are as follows: [$Fe^{III}_2O(Hbbea)_2Cl_2]Cl_2$, 2: monoclinic space group $$P2_1/n$$, a = 8.421 (1) $\AA$, b = 18.416 (2) $\AA$, c = 13.736 (1) $\AA$, $\beta$ = 104.870 $(7)^{\circ}$, V = 2058.9 (4) $\AA^3$, Z = 2, R1 = 0.0469 and wR2 = 0.1201 for reflections with I > 2 ${\sigma}$(I).

A Study on Advertisement Design of Men's Fashion Products (남성패션제품 광고디자인에 대한 연구)

  • Shin, Su-Yun;Lee, Jung-Im
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.7
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    • pp.1082-1094
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    • 2008
  • The present study analyzed the differences of advertisement design, expression method, and appeal types in the men's fashion product advertisement from men's magazines between 1996 and 2006, according to the year, season, and the type of the magazine. The magazines chosen for the analysis were Korean Esquire, GQ, and Shin-dong-a. 2058 advertisement out of 88 sample magazines were chosen and analyzed by frequency, and chi-square using SPSS statistic package. The results of the study were as follows. First of all, there were more advertisements without copy, and even when the copy was used, it was used as a headline only. Secondly the poster style layout was used more frequently than other layouts, and one male model wearing the product was the most popular. Thirdly the types of appeal in advertisement, sensuous appeal was most frequently used. The results of the study showed that there is little advertisement differentiation in men's fashion product advertisement. Therefore in order to draw consumer's attention. various and unique advertisement design should be implemented.

Design of Tx 3OGHz/ Rx 20GHz dual feeding circular polarized patch antenna (송신 30GHz/ 수신 20GHz 이중급전 원형편파 패치 안테나 설계)

  • Kim, Sung-Nam;Oh, Min-Seok;Cheon, Young-Min;Choi, Jae-Ick;Pyo, Cheol-Sig;Lee, Song-Moon;Cheon, Chang-Yul
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.2058-2060
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    • 2004
  • In this paper, circular polarized antennas of Tx 30GHz and Rx 20GHz are implemented in LTCC process. Tx antenna has a circular patch structure and Rx antenna has a ring patch structure. The feeding line of Tx antenna is placed in the center hole of Rx ring patch antenna which is printed under Tx circular patch antenna layer. It makes antenna size smaller. Tx antenna's return loss in under -10dB level from 30GHz to 31GHz and Rx antenna is under -10 dB from 20GHz to 21GHz. The isolation between two antennas is less than -20dB. Axial ratio is less than 3dB though out each band.

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Optimum Cam Profile Design and Experimental Verification on an OHC Type Cam-valve System (OHC형 캠-밸브 기구의 최적 캠 형상설계 및 실험적 검증)

  • 김성훈;김원경;박윤식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.11
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    • pp.2049-2058
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    • 1992
  • In this work, a 6 degree of freedom lumped mass model is constructed for an OHC-type cam valve train analysis, and the model is verified experimentally. Using the verified model, an optimum cam profile is designed to minimize the maximum contact force between cam and follower under the constraints such as cam lift and cam event angle. The designed cam was carefully machined and tested experimentally. As operating the designed cam shaft on the test rig, the valve motion was precisely measured with laser displacement meter and the contact force was indirectly monitored by measuring strain at a certain point of the finger follower. Judging from the model simulation and experiment results, the maximum contact force can be reduced as much as more than 16.7 percent under maintaining the original valve flow area by adopting the optimum cam profile.

Establishment on management system for greenhouse gas emission of Railroad (철도교통부문 온실가스배출 관리체계 구축방안에 관한 연구)

  • Kim, Yong-Ki;Lee, Jae-Young;Lee, Cheul-Gyu;Lee, Young-Ho
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.2058-2063
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    • 2010
  • United Nations Framework Convention on Climate Change(UNFCCC) is one of the international environmental convention with the goal of stabilizing Greenhouse Gas(GHG) concent in the atmosphere and preventing potentially dangerous change in the earth's climate. The purpose of this convention is to reduce fossil fuel consumption and to prevent GHG emission. The Republic of Korea was one of the Annex-II parties submitted its national communication to the UNFCCC. As a developing county, there is no GHG emission reduction commitments made by South Korea during first commitment period(2008~2012). On the contrary, South Korea' status as an OECD member, joining in 1996, ranks 6th in GHG emission. Furthermore the rate of increase of GHG is first among OECD countries in year 2005. As a result, Korea will probably be incorporated into Annex-I in second commitment period (after 2013). So, Korea government established and announced Voluntary GHG Reduction scheme to reduce emissions of 4%(accounting for 30% reduction base on Business As Usual) from the 2005 level by the year 2020 for mitigation of reduction duty impact. In specific case of Korea, transportation section occupied almost 21% of total energy consumption and nearly 17% of total GHG emission at 2005, so systematic emission management is required. To do so, in this research, we focus on systematic way of GHG management system to handle GHG reduction duties in Railroad section.

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An Optimal ERP and Antenna HAAT Of 8-VSB for Digital Multimedia Broadcasting

  • Kim, Seon-Mi;Park, Jung-Jin;Choi, Dong-You;Ryu, Kwang-Jin;Choi, Dong-Woo;Park, Chang-Kyun
    • Proceedings of the IEEK Conference
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    • 2002.07c
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    • pp.2055-2058
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    • 2002
  • It designs the general description of 8-VSB DTV transmission system will be installed and operated in future on the basis of NTSC TV transmission system in operation now. First of all, it investigates a condition that can maintain optimum received field in case of ground wave broadcasting with analog NTSC and digital 8-VSB DTV. Also it calculates critical value of minimum field strength fur receiving by using field strength calculation method of Longley-Rice. The 8-VSB DTV transmission sets its goal in transmission of data with 19.39Mbps at high speed in order to be available of HDTV in the band of NTSC 6MHz. Accordingly, the optimum of field strength between transmission and receiving points most of all is important problem. So,8-VSB DTV transmission should be enlarged or effective compared with NTSC service coverage. This study is to calculate the transmission power necessary in switching from NTSC VHF to DTV UHF and from NTSC UHF to DTV UHF for maintaining service coverage that NTSC is equal to 8-VSB DTV as a result of calculation.

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Experimental Study on Design Verification of New Concept for Integral Reactor Safety System (일체형원자로의 신개념 안전계통 실증을 위한 실험적 연구)

  • Chung, Moon-Ki;Choi, Ki-Yong;Park, Hyun-Sik;Cho, Seok;Park, Choon-Kyung;Lee, Sung-Jae;Song, Chul-Hwa
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2053-2058
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    • 2004
  • The pressurized light water cooled, medium power (330 MWt) SMART (System-integrated Modular Advanced ReacTor) has been under development at KAERI for a dual purpose : seawater desalination and electricity generation. The SMART design verification phase was followed to conduct various separate effects tests and comprehensive integral effect tests. The high temperature / high pressure thermal-hydraulic test facility, VISTA(Experimental Verification by Integral Simulation of Transient and Accidents) has been constructed to simulate the SMART-P (the one fifth scaled pilot plant) by KAERI. Experimental tests have been performed to investigate the thermal-hydraulic dynamic characteristics of the primary and the secondary systems. Heat transfer characteristics and natural circulation performance of the PRHRS (Passive Residual Heat Removal System) of SMART-P were also investigated using the VISTA facility. The coolant flows steadily in the natural circulation loop which is composed of the steam generator (SG) primary side, the secondary system, and the PRHRS. The heat transfers through the PRHRS heat exchanger and ECT are sufficient enough to enable the natural circulation of the coolant.

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Expression, Secretion and Purification of Histidine-Tagged Autotaxin (NPP2) from Insect Cells Media (곤충세포 배지로부터 히스티딘이 융합된 Autotaxin(NPP-2)의 발현, 분비 및 정제)

  • 이종한;송재휘;이종흔;안영민;김수영;이석형;박원상;유남진;홍성렬
    • YAKHAK HOEJI
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    • v.47 no.6
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    • pp.410-416
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    • 2003
  • Autotaxin(ATX) was originally purified from conditioned media of A2058 human melanoma cells and shown to be a potent cell motility-stimulating factor, possessing a type II nucleotide pyrophosphatase/phosphodiesterase (NPP2) activity. Recombinant ATX has recently demonstrated that human plasma lysophosholipase D is identical to ATX and uses lysophosphatidylcholine as a substrate to mediate various biological functions including tumor cell growth and motility through G-protein coupled receptor. However, despite pivotal roles of ATX on physiological or pathophysiological states, the production of ATX is solely depends on complicated purification method which employs multiple column steps, but resulted in very poor yield. This limited the use of ATX for extensive analysis. We, therefore, expressed six histidine-tagged recombinant human ATX(His-ATX) in High Five TM insect cells to improve the generation of ATX and to make simple the purification of ATX. The signal sequence of the human ATX gene was truncated and replaced with sequence of insect cell secretion signal within expression vector. In addition, codons for six histidines were added to the C-termini of 120kDa ATX cDNA construct. A simple purification scheme utilizing two-step affinity column chromatography was designed to purify His-ATX to homogeneity from the culture supernatant of transfected insect cells. Homogenous His-ATX was detected and isolated from the concentrated insect cell medium using concanavalin A agarose and nickel affinity chromatography. Purified His-ATX was in full length with ATX capacity. A combination of this expression system and purification scheme would be useful for production and purification of high-quality functional ATX for research and practical application of multiple functional motogen, ATX/NPP-2.

Three-Dimensional Evaluation of Skeletal Stability following Surgery-First Orthognathic Approach: Validation of a Simple and Effective Method

  • Nabil M. Mansour;Mohamed E. Abdelshaheed;Ahmed H. El-Sabbagh;Ahmed M. Bahaa El-Din;Young Chul Kim;Jong-Woo Choi
    • Archives of Plastic Surgery
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    • v.50 no.3
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    • pp.254-263
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    • 2023
  • Background The three-dimensional (3D) evaluation of skeletal stability after orthognathic surgery is a time-consuming and complex procedure. The complexity increases further when evaluating the surgery-first orthognathic approach (SFOA). Herein, we propose and validate a simple time-saving method of 3D analysis using a single software, demonstrating high accuracy and repeatability. Methods This retrospective cohort study included 12 patients with skeletal class 3 malocclusion who underwent bimaxillary surgery without any presurgical orthodontics. Computed tomography (CT)/cone-beam CT images of each patient were obtained at three different time points (preoperation [T0], immediately postoperation [T1], and 1 year after surgery [T2]) and reconstructed into 3D images. After automatic surface-based alignment of the three models based on the anterior cranial base, five easily located anatomical landmarks were defined to each model. A set of angular and linear measurements were automatically calculated and used to define the amount of movement (T1-T0) and the amount of relapse (T2-T1). To evaluate the reproducibility, two independent observers processed all the cases, One of them repeated the steps after 2 weeks to assess intraobserver variability. Intraclass correlation coefficients (ICCs) were calculated at a 95% confidence interval. Time required for evaluating each case was recorded. Results Both the intra- and interobserver variability showed high ICC values (more than 0.95) with low measurement variations (mean linear variations: 0.18 mm; mean angular variations: 0.25 degree). Time needed for the evaluation process ranged from 3 to 5 minutes. Conclusion This approach is time-saving, semiautomatic, and easy to learn and can be used to effectively evaluate stability after SFOA.

Evaluation of Time-Temperature Integrators (TTIs) with Microorganism- Entrapped Microbeads Produced Using Homogenization and SPG Membrane Emulsification Techniques

  • Mijanur Rahman, A.T.M.;Lee, Seung Ju;Jung, Seung Won
    • Journal of Microbiology and Biotechnology
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    • v.25 no.12
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    • pp.2058-2071
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    • 2015
  • A comparative study was conducted to evaluate precision and accuracy in controlling the temperature dependence of encapsulated microbial time-temperature integrators (TTIs) developed using two different emulsification techniques. Weissela cibaria CIFP 009 cells, immobilized within 2% Na-alginate gel microbeads using homogenization (5,000, 7,000, and 10,000 rpm) and Shirasu porous glass (SPG) membrane technologies (10 μm), were applied to microbial TTIs. The prepared micobeads were characterized with respect to their size, size distribution, shape and morphology, entrapment efficiency, and bead production yield. Additionally, fermentation process parameters including growth rate were investigated. The TTI responses (changes in pH and titratable acidity (TA)) were evaluated as a function of temperature (20℃, 25℃, and 30℃). In comparison with conventional methods, SPG membrane technology was able not only to produce highly uniform, small-sized beads with the narrowest size distribution, but also the bead production yield was found to be nearly 3.0 to 4.5 times higher. However, among the TTIs produced using the homogenization technique, poor linearity (R2) in terms of TA was observed for the 5,000 and 7,000 rpm treatments. Consequently, microbeads produced by the SPG membrane and by homogenization at 10,000 rpm were selected for adjusting the temperature dependence. The Ea values of TTIs containing 0.5, 1.0, and 1.5 g microbeads, prepared by SPG membrane and conventional methods, were estimated to be 86.0, 83.5, and 76.6 kJ/mol, and 85.5, 73.5, and 62.2 kJ/mol, respectively. Therefore, microbial TTIs developed using SPG membrane technology are much more efficient in controlling temperature dependence.