Kim, Ji-Seok;Park, Eon-Sang;Ann, Ki-Yong;Cho, Won-Jung
Journal of the Korean Recycled Construction Resources Institute
/
v.9
no.2
/
pp.152-160
/
2021
Converter steel slag(BOF slag) is a vast amount of solid waste generated in the steelmaking process which has very low utilization rate in Korea. Due to the presence of free CaO which can derive bad volume stability in BOF slag, it usually land filled. For recycling BOF and identify its applicability as fine aggregate, this study investigates the fundamental characteristics of mortar with cement replaced ferronickel slag(FNS), which has the potential to be used as a binder. The results suggest that the mineral phases of BOF slag mainly include larnite(CaSiO4), mayenite(Ca12Al14O33) and wuestite(FeO) while olivine crystallines are shown in FNS. The results of flow and setting time reveals that the flowability and process of hardening increased when the amount of FNS and BOF slag incorporated was increased. The length change shows that the amount of change in the length of the mortar was almost constant regardless of mix proportion while compressive strength was reduced. Micro structure test results revealed that FNS or/and BOF slag mix took a long time to react in the cement matrix to form a complete hydration products. To achieve the efficient utilization of B OF slag as construction materials, proper replacement rate is necessary.
Chaiyabutr, N.;Thammacharoen, S.;Komolvanich, S.;Chanpongsang, S.
Asian-Australasian Journal of Animal Sciences
/
v.15
no.10
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pp.1445-1452
/
2002
The present experiment was carried out to study the utilization of substrates in the mammary gland of crossbred Holstein Friesian during feeding on different types of roughage. Sixteen pregnant crossbred Holstein heifers consisted of two breed types of eight animals each; Holstein Friesian${\times}$Red Sindhi (50:50=50%HF) and Holstein Friesian${\times}$Red Sindhi (87.5:12.5=87.5%HF). Animals were divided into four groups of the same breed type in each group which were fed with either rice straw treated with 5% urea or pangola hay (Digitaria decumbens) as the source of roughage throughout the experiments. Four consecutive experimental periods were carried out in late pregnancy (20-23 days before parturition), early lactation (30 days postpartum), mid-lactation (120 days postpartum) and late lactation (210 days postpartum). Measurement of mammary blood flow in combining with measurement of AV difference was performed for the mammary uptake of substrates. In the period of lactation, udder blood flow was nearly three times higher than that of late pregnant period (p<0.05) in both 50%HF and 87.5%HF feeding on either hay or urea treated rice straw. During mid- and late lactation of both groups of 87.5%HF animals, mammary blood flow and milk yield showed decrease when compared to those during the early lactating period while the trends for persistency were apparent in both groups of 50%HF animals throughout experimental periods. The mean arterial plasma concentrations of glucose, acetate, $\beta$-hydroxybutyrate and free glycerol in each group remained constant throughout experimental periods. During late pregnancy in all groups, the AV difference and extraction ratio of glucose, $\beta$-hydroxybutyrate and triacylglycerol across the mammary gland markedly lowered (p<0.05), which coincided with a lower net uptake by the mammary gland in comparison to the early lactating period. The mean arterial plasma concentration, AV difference and extraction ratio for acetate showed no significant differences between late pregnancy and the early lactating period. The AV difference of free glycerol showed apparent release from mammary tissue during late pregnancy in all groups. In mid- and late lactation, the mammary uptake for glucose, acetate and $\beta$-hydroxybutyrate in both groups of 87.5%HF animals showed apparent decrease as compared to that in the early lactating period, whereas no appearances were observed in 50%HF animals feeding either hay or urea treated rice straw. The mean arterial plasma concentrations for free fatty acid (FFA) and triacylglycerol (C16 to C18) were higher in late pregnancy than in early lactation in both types of crossbred animals. The values of AV difference and the net uptake by the mammary gland for FFA were variable during late pregnancy and lactating periods in all groups. There were no significant differences for AV difference, extraction ratio and net uptake of triacylglycerol during lactation advance in both groups of 50%HF and 87.5%HF animals feeding either hay or urea treated rice straw. These results suggest that the adaptations to either hay or urea treated rice straw by the mammary gland of crossbred HF animals allow for an adequate nutrient supply during pregnancy and lactation. There is no difference in the mode of mammary uptake of substrates in the same crossbred animals in response to feeding hay or urea treated rice straw. The differences in utilizing nutrients by the mammary gland for milk production between 87.5%HF and 50%HF animals would be dependent on changes in both intra-mammary factors and extra-mammary factors.
KSCE Journal of Civil and Environmental Engineering Research
/
v.34
no.1
/
pp.107-116
/
2014
A volume density of roughness correction blocks in a channel is defined and the corresponding roughness coefficient(n) is estimated by analyzing the diverse hydraulic characteristics of VR, the product of the average velocity and the hydraulic radius, block Reynolds number ($Re^*$), drag coefficient ($\acute{C}_D$), and the roughness coefficient ($n_b$) of bottom shear. The increase of VR and block Reynolds number causes the exponential decrease of roughness coefficient converged to a constant value as expected. The drag coefficient also exponentially decreases as block Reynolds number increases as well. The drag force is governed by the block shape defined by volume density in high block Reynolds number of turbulent flow region. For more accurate estimation of roughness coefficient the use of the correlation equation of it is required by block Reynolds number and volume density. The regression equations for n-VR, $\acute{C}_D-Re^*$, and $n_b-\acute{C}_D$ are presented. The regression equations of roughness coefficient are also presented by block Reynolds number and volume density. The developed equation of roughness coefficient by block Reynolds number and volume density has practical use by confirming the coincidence between the experimental results and the results of HEC-RAS using the developed equation.
Bae, Mun Joo;Roh, Jae Hoon;Cho, Young Bong;Kim, Choon Sung;Chun, Mi Ryoung;Kim, Chi Nyon
Journal of Korean Society of Occupational and Environmental Hygiene
/
v.6
no.1
/
pp.28-37
/
1996
Benzidine, an aromatic amine used primarily in the manufacture of azo dyes, is recognized as a urinary bladder carcinogen in humans. In rats, mice, and hamsters, chronic exposure to benzidine resulted in tumors of the liver. The present study was undertaken to suggest analyzing the metabolites of benzidine with the optimal condition, identify the metabolites of benzidine, and observe time variance of the metabolites in the isolated perfusated rat liver. N-acetylbenzidine was synthesized by acetylation of benzidine with acetic anhydride and separated by thin layer chromatography(TLC) and high performance liquid chromatography(HPLC). To analysis benzidine and the metabolites of benzidine, HPLC operating condition has been optimized by means of preliminary experiment. The mobile phase consisted of acetonitrile(37%) in phosphate buffer, flow rate maintained at 1.0 ml/min. Optimal detective conditions were electrochemicaldetector(ECD) at 0.75 V for benzidine and N-acetylbenzidine and ultravioletdetector(UVD) at 287 nm for N,N'-diacetylbenzidine. The separation system was composed of a guard column and a separation column(Polymer C18, $4.6{\times}250cm$) at a temparature of $40^{\circ}C$. The perfusion system was equilibrated for 30 minutes before addition of benzidine to the perfusate. Samples of the perfusate were collected at time intervals(0, 10, 20, 30, 60, 90, 120 min) during the 2 hour perfusion. Before analyzing samples by HPLC/ECD/UVD, samples had been treated with sep-pak. Samples of perfusate analyzed by HPLC/ECD/UVD and the metabolites of benzidine in the isolated perfused rat liver were N-acetylbenzidine and N,N'-diacetylbenzidine. Benzidine metabolized over 60% during the initial 30 minutes of perfusion, extensively by 1 hour, and was undetectable in the perfusate. N-acetylbenzidine increased by 30 minutes of perfusion, declined. N,N'-diacetylbenzidine increased the 0-90 minutes period, remained constant during the 90-120 minutes period.
The objective of the present study is to verify the validity of a new truss model for evaluating the contribution by arch action to shear resistance in shear-critical reinforced concrete beams. The new truss model is based on the relationship between shear and bending moment in a beam subjected to combined shear and bending. The compatibility condition of the shear deformation that deviates from Bernoulli bending plane is formulated utilizing the smeared truss idealization with an inclined compression chord. The Modified Compression Filed Theory is employed to calculate the shear deformation of the web, and the relative axial displacements of the compression and the tension chord by the shear flow are also calculated. From this shear compatibility condition in a beam, the shear contribution by the arch action is numerically decoupled. Then the validity of the model is examined by applying the model to some selected test beams in literatures. On the basis of the analytical results, the contribution by the web to shear resistance can be constant and have an excellent linear correlation with the web reinforcement ratio. The present decoupling approach may provide a simple way for the assessment of the role of each parameter or mechanism that affects the ultimate shear behavior of reinforced concrete beams.
Journal of Korean Society of Environmental Engineers
/
v.35
no.9
/
pp.654-659
/
2013
This study was conducted to identify an optimal ratio of carbon to nitrogen (C/N ratio) for denitrification of nitrate using molasses as an external carbon source. A series of batch and column tests was conducted using an indigenous bacterium Pseudomonas sp. KY1 isolated from a nitrate-contaminated soil. For the initial nitrate-nitrogen concentration of 100 mg-N/L, batch test results indicated that C/N ratio of 3/1 was the optimal ratio with a relatively high pseudo-first-order reaction constant of $0.0263hr^{-1}$. At C/N ratio of 3/1, more than 80% of nitrate-nitrogen concentration of 100 mg-N/L was removed in 100 hrs. Results of column tests with a flow velocity of 0.3 mL/min also indicated that the C/N ratio of 3/1 was optimal for denitrification with minimizing remaining molasses concentrations. After 172 hrs of column operation (35 pore volumes) with an influent nitrate-nitrogen concentration of 100 mg-N/L, the effluent met the drinking water standard (i.e., 10 mg $NO_3$-N/L).
Journal of Korean Society of Environmental Engineers
/
v.28
no.5
/
pp.511-521
/
2006
Homologue and isomer patterns of polychlorinated dibenzo-p-dioxins(PCDDs) and polychlorinated dibenzofurans(PCDFs) congeners formed from phenols in the gas-phase at $600{\sim}700^{\circ}C$ and via particle-mediated reactions at $400^{\circ}C$ were studied in an isothermal flow reactor. A mixture of 20 phenols in relative concentrations found in a municipal waste incinerator(MWI) stack gas was used for this study. PCDDs and PCDFs homologue and isomer patterns obtained from the phenol. From the phenol experiments, gas-phase formation at $600{\sim}700^{\circ}C$ favors PCDFs formation whereas particle-mediated formation at $400^{\circ}C$ favors PCDDs formation. DD and DF were most abundant homologue groups, PCDDs and PCDFs homologue fraction decreased with increasing number of chlorine substituents. PCDDs and PCDFs homologue and isomer fractions were almost constant from gas-phase formation and particle-mediated formation. Unsubstituted phenol, which was present in high concentration, played a significant role in the formation of PCDD/Fs congeners under both sets of experimental conditions.
In this study, we setup a ground-based scatterometer using an antenna of which the center frequency is 9.5 GHz (X-band), and measured radar backscatterings from air/ice and ice/water interfaces to extract ice thickness. Both of air/ice and ice/water interfaces make strong radar backscatterings and so we can clearly identify two peaks in measured data by scatterometer. By using the distance of two peaks and refractive index of ice, we confirmed that it is possible to measure ice thickness. Field survey was performed at the downstream of Jiam River flowing into Chuncheon Lake. We measured radar backscattering from river ice along a survey path and extracted ice thickness. The ice thickness map of the downstream of Jiam River was produced by using kriging which is one of well known interpolation methods. The ice thickness was about 50 cm along the mainstream while ice was thin as 30 ~ 40 cm at a fast-flowing meander. Ice thickness was particularly thinner at some locations than that of surrounding areas even in the mainstream region of constant flow. This was because of impurities in ice or artificially formed refrozen holes after fishing. We expect that this study helps to expand utilization field of X-band SAR and airborne scatterometer system.
Traffic volumes are fundamental data widely used in various traffic analysis, such as origin-and-destination establishment, total traveled kilometer distance calculation, congestion evaluation, and so on. The low number of links collecting the traffic-volume data in a large urban highway network has weakened the quality of the analyses in practice. This study proposes a method to estimate the traffic volume data on a highway link where no collection device is available by introducing a spatial statistic technique with (1) the traffic-volume data from TOPIS, and National Transport Information Center in the Ministry of Land, Infrastructure, and (2) the navigation data from private navigation. Two different component models were prepared for the interrupted and the uninterrupted flows respectively, due to their different traffic-flow characteristics: the piecewise constant function and the regression kriging. The comparison of the traffic volumes estimated by the proposed method against the ones counted in the field showed that the level of error includes 6.26% in MAPE and 5,410 in RMSE, and thus the prediction error is 20.3% in MAPE.
Park, Jin-Seok;Cho, Yeon-Jin;Jeong, Yu-Rin;Chun, Byung-Soo
Clean Technology
/
v.25
no.4
/
pp.275-282
/
2019
In this study, the extraction of Conger myriaster oil by using supercritical carbon dioxide (SC-CO2) and organic solvent was investigated. The extraction conditions conducted for SC-CO2 varied for pressure (25, 30 MPa) and temperature (45, 55 ℃), while the SC-CO2 flow rate was kept constant during the experiment (27 g min-1) and hexane was used as a conventional organic solvent. The extraction yield indicated that the best extraction condition would be SC-CO2 at 55 ℃ and 30 MPa, resulting in the highest yield of 37.73 ± 0.14%. The oils were characterized for their fatty acid (FAs) composition using gas chromatography, while it was revealed that the major FAs were mystric acid, palmitoleic acid, oleic acid, electroosapentaenoic acid (EPA), and docosahexaenoic acid (DHA). The oxidation stability of the extracted C. myriaster oil was evaluated by measuring the acid value, peroxide value, and free fatty acid. The best oxidative stability was obtained from SC-CO2 extracted oil at 30 MPa and 55 ℃. There was a significant difference in the color properties of the SC-CO2 and hexane extracted oils, with the SC-CO2 extracted oil showing better chromaticity than the oil extracted using hexane. Extracting oils from C. myriaster with SC-CO2 could bring better economic benefits than using organic solvents. When supercritical carbon dioxide was used, there was no post-treatment process; thus, it was confirmed that this is a more environmentally friendly oil extraction method.
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