• Title/Summary/Keyword: A batch experiment

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Transport and Fate of Benzene in a Sandy Soil (사질토양에서의 Benzene의 이동성에 관한 연구)

  • 백두성;김동주
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.2
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    • pp.95-100
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    • 1999
  • Hydrocarbon compounds in vadose zone soils caused by adsorption onto the surfaces of solid particles are generally considered to show retardation effect. In this study, we investigated the retardation effect on the transport of Benzene in a sandy soil by conducting batch and column tests. The batch test was conducted by equilibrating dry soil mass with Benzene solutions of various initial concentrations. and by analyzing the concentrations of Benzene in initial and equilibrated solutions using HPLC. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used KCl and Benzene solutions with the concentration of 10 g/L and 0.88 g/L as a tracer, and injected them into the inlet boundary of the soil sample as a square pulse type respectively, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and HPLC. From the batch test, we obtained a distribution coefficient assuming that a linear adsorption isotherm exists and calculated the retardation factor based on the bulk density and porosity of the column sample. We also predicted the column BTC curve using the retardation factor obtained from the distribution coefficient and compared with the measured BTC of Benzene. The results of the column test showed that i) the peak concentration of Benzene was much smaller than that of KCl and ⅱ) the travel times of peak concentrations for the two tracers were more or less identical. These results indicate that adsorption of Benzene onto the sand panicles occurred during the pulse propagation but the retardation of Benzene caused by adsorption was not present in the studied soil. Comparison of the predicted with the measured BTC of Benzene resulted in a poor agreement due to the absence of the retardation phenomenon. The only way to describe the absolute decrease of Benzene concentration in the column leaching experiment was to introduce a decay or sink coefficient in the convection-dispersion equation (CDE) model to account for an irreversible sorption of Benzene in the aqueous phase.

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Characteristics of Aerobic Granular Activated Sludge According to Electron Acceptors in Sequencing Batch Reactor Process (SBR공정에서 전자수용체에 따른 호기성 입상활성슬러지의 공정별 특성)

  • Kim, I-Tae;Lee, Hee-Ja;Bae, Woo-Keun
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.480-487
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    • 2004
  • This study was conducted to find the effect of electron acceptors on the formation of granular sludge by using four different types of electron acceptors. The phosphorous uptake, denitrification, and sulfate reduction in anoxic modes were simultaneously occured because of the presence of the polyphosphate accumultating organism(PAO) that utilize nitrate and sulfate as an electron acceptor in the anoxic zone. Denitrirying phosphorous removal bacteria(DPB) was enriched under anaerobic/anoxic/aerobic condition with a nitrate as an electron acceptor, and desulfating phosphorous removal bacteria(DSPB) was enriched under anaerobic/anoxic/aerobic condition with a sulfate as an electron acceptor. Polyphosphate accumulating organism(PAO) were enriched in the anaerobic/aerobic SBR. PAO took up acetate faster than DPB and DSPB during the aerobic phase. The sludge with nitrate and sulfate as an electron acceptors grew as a granules which possessed high activity and good settleability. In the anaerobic/aerobic modes, typical floccular growth was observed. In the result of bench-scale experiment, simultaneous reactions of phosphorus uptake, denitrification and sulfate reduction were observed under anoxic condition with nitrate and sulfate as an electron acceptors. These results demonstrated that the anaerobic/anoxic modes with nitrate and sulfate as an electron acceptors played an important role in the formation of the sludge granulation.

EFFECT OF HEPATOCYTE GROWTH FACTOR ON THE REPAIR OF DEFECT IN THE ARTICULAR DISC IN RABBIT TEMPOROMANDIBULAR JOINT (가토의 측두하악관절원판 결손에서 간세포 성장인자가 치유에 미치는 영향)

  • Kim, Bok-Joo;Seong, Hwa-Sik;Kim, Chul-Hoon;Kim, Gyoo-Cheon;Hwang, Hee-Sung;Shin, Sang-Hun
    • Maxillofacial Plastic and Reconstructive Surgery
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    • v.31 no.1
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    • pp.1-7
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    • 2009
  • Purpose: The purpose of this study is to investigate the therapeutic use of Hepatocyte growth factor(Adv.CMV.HGF) in temporomandibular joint disc defect. Materials and methods: Twelve New Zealand white rabbits, weighing 2.5 - 3.0 kg, were used in this experiment. Defects(2 mm in diameter) were created in their TMJ discs. Recombinant Adv.CMV.HGF with gelatin sponge($Gelfoam^{(R)}$) as carrier was implanted in the defects. We divided the rabbits into four batches according to the duration of the implantation - of 1, 4, 8, 12 weeks - and both left and right TMJ of each rabbit in all groups were used in the research : left joints were used as experiment group and right were control group. Each batch of rabbits was killed one, four, eight and twelve weeks after the experimentation respectively, and called Group A, B, C, and D. (Group A = 1 wk, B = 4 wks, C = 8 wks, and D = 12 wks) Results: The experimental group showed a significant increase in the number of chondroblasts and active cell differentiation at the margin of the defects. Compared to the control group, in the experiment group chondroblasts increased and chondrocytes showed a columnar arrangement, which is witnessed at the time of cell differentiation. Conclusion: This study supports the case that Avd.CMV.HGF may be useful in the repair of articular disc of the rabbit TMJ.

A Study of the Development of Liquid-liquid Static Contactor Using Capillary Phenomena Induced by Highly Packed Fiber Bundle and its Characteristics (고밀집 섬유 집합체에 의해 유도된 모세관 현상을 이용한 정적 액-액 접촉장치의 개발과 그 특성 연구)

  • Kim, Kwang-Wook;Byeon, Kee-Hoh;Lee, Eil-Hee;Yoo, Jae-Hyung;Park, Hyun-Soo
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.743-749
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    • 1996
  • A new static contractor using capillary phenomena induced by a highly packed fiber bundle was developed for the solvent extraction. When two immiscible phases being cocurrently and forcedly fed into the packed fiber bundle, the contactor brings about a very large liquid-liquid contact area for mass transfer within a small definite space without any turbulence and drop phenomena. In order to test the characteristics and stability of the static contractor system, continuous extraction experiments of TBP-uranyl ion-nitric acid system were done and compared with the batch extraction experiment of the same chemical system. The performance of the static contractor were the same as that of the ideal batch extractor with the same extraction condition. For the increase of the extraction yield by the contactor, the increase of organic flow rate was required at a fixed aqueous flow rate, and a certain residence time of the aqueous phase flow within the contactor system had to be maintained to meet the performance of the batch system of the same phase ratio. The residence time in the case of TBP-uranyl ion-nitric acid system was about 1.9 minutes. This system was confirmed to be effective and stable enough for purposes of the kinetic study of solvent extraction as well as the mutual separation and purification of ordinary materials because of good reproducibility and the stable and large static liquid-liquid contact area.

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A study of SO2 Removal Efficiency from Traditional Herbal Medicine Using Traditional & Electronic Medicine Boilers (전통약탕기와 전자약탕기를 이용한 이산화황 제거효율 연구)

  • Yang, Seung-Hee;Ryu, Seok-Gyu
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.5
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    • pp.1133-1140
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    • 2009
  • The purpose of this study is to determine the most efficient method of removing sulfur dioxide from traditional herbal medicine (hanyak) by slow boiling using a traditional pipkin and an electronic slow boiler. By boiling a hanyak batch containing] 56.4ppm of sulfur dioxide for one hour using a traditional pipkin, 96.7 percent of the sulfur dioxide was removed, while two hours of slow boiling removed ]00 percent. Among different cover materials placed over the pipkin during the slow boiling process including the traditional Korean paper (hanji), regular hanji, filter paper and regular paper, the traditional hanji produced the best performance of sulfur dioxide removal. The initial pH level of the traditional hanji was] 0.03. After one hour of slow boiling hanyak batches in a traditional pipkin covered with traditional hanji, where each batch contained sulfur dioxide of 48ppm, 193ppm, 753ppm and 1,506ppm respectively, the pH level of the hanji cover material was reduced to 9.37, 9.14, 8.9 and 8.03 in respective cases. Our experiment using an electronic medicine slow boiler showed 82.8 percent removal of sulfur dioxide after one hour of slow boiling a hanyak batch containing 753ppm of sulfur dioxide. When hanyak batches were boiled by placing traditional hanji, filter paper, active carbon and hardwood charcoal separately in the middle area within the electronic slow boiler, the sulfur dioxide removal rate was 73.6 percent, 72.8 percent, 73.9 percent and 69.5 percent, respectively. When charcoal was added so as to remove toxic materials from the hanyak, its presence impeded the sulfur dioxide flow and thus reduced the removal efficiency contrary to our anticipation.

Shipboard sewage treatment by Sequence Batch Reactor utilizing Beneficial Microorganisms (유용미생물을 적용한 선박오수용 SBR공정에 관한 연구)

  • Kim, In-Soo;Lee, Eon-Sung;Ha, Shin-Young;Oh, Yeom-Jae;Ekpeghere, Kelvin I.;Koh, Sung-Cheol
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2010.10a
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    • pp.36-37
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    • 2010
  • Lab scale experiment was carried out to study applicability of BM (Beneficial Microorganisms) to the conventional SBR system for the shipboard sewage treatment. BM has been successfully applied to the wastewater treatment by the SBR process and hence this system maintained a stable effluent quality together with an increased treatment efficiency, meeting the requirements of IMO regulations. The SBR system facilitated by BM would be a suitable process for cruise ships in terms of the malodor control, treatment efficiency and operation conveniences.

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Analysis on the distribution of nitrogen and phosphorus removing microorganisms and nitrifying activity in a trickling filter (살수여상에서의 질소, 인 제거 미생물 분포 및 질산화 활성 조사)

  • Kim, Dong-Jin;Yoo, Ik-Keun;Ahn, Dae-Hee
    • Journal of Environmental Science International
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    • v.18 no.6
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    • pp.691-698
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    • 2009
  • Trickling filter has been extensively studied for the domestic wastewater treatment especially for the small scale plants in rural area. The performance of the trickling filter depends on the microbial community and their activity in the biofilms on the media. Nitrification. denitrification, and phosphorus removal of the trickling filter from the wastewater depend on the activity and the amount of the specific microorganisms responsible for the metabolism. For the estimation of the performance of a trickling filter, batch nitrification experiment and fluorescence in situ hybridization (FISH) were carried out to measure the microbial activity and its distribution on the media of the trickling filter. Batch nitrification activity measurement showed that the top part of the 1st stage trickling filter had the highest nitrification activity and the maximum activity was 0.002 g $NH_4$-N/g MLVSS${\cdot}$h. It is thought that higher substrate (ammonia) concentration yields more nitrifying bacteria in the biofilms. The dominant ammonia oxidizer and nitrite oxidizer in the biofilm were Nitrosomonas species and genus Nitrospira, respectively, by FISH analysis. Less denitrifiers were found than nitrifiers in the biofilm by the probe Rrp1088 which specifically binds to Rhodobacter, Rhodovulum, Roseobacter, and Paracoccus. Phosphorus accumulating bacteria were mostly found at the surface of the biofilm by probe Rc988 and PAO651 which specifically binds to Rhodocyclus group and their biomass was less than that of nitrifiers.

Feasibility of Natural Attenuation for TCE Anaerobic Reductive Dechlorination Using Microsized Corn-Oil Droplet as an Activator (Microsized Corn-Oil Droplet (MOD)의 Trichloroethylene (TCE) 생물학적 탈염소화 분해 자연저감 완효성 촉진제 적용성 평가)

  • Kyungjin Han;Huiyun Kim;Sooyoul Kwon;Young Kim
    • Journal of Korean Society on Water Environment
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    • v.40 no.1
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    • pp.11-18
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    • 2024
  • Recently, enhanced in situ bioremediation using slow substrate release techniques has been actively researched for managing TCE-contaminated groundwater. This study conducted a lab-scale batch reactor experiment to evaluate the feasibility of natural attenuation for TCE dechlorination using microsized corn-oil droplet (MOD) as an activator considering the following three factors: 1) TCE dechlorination in the presence or absence of MOD; 2) TCE dechlorination in the presence or absence of inactivator of native microbial activity; and 3) MOD concentration effects on TCE dechlorination. Batch reactors were constructed using site groundwater and soil in which Dehalococcoides bacteria were present. Without MOD, TCE was decomposed into dichloroethylene (DCE). However, other by-products of TCE dechlorination were not detected. With MOD, DCE, vinyl chloride (VC), and ethylene (ETH) were sequentially observed. This result confirmed that MOD effectively supplied electrons to complete dechlorination of TCE to ETH. However, when an excess of MOD was provided, it formed unfavorable conditions for anaerobic digestion because dechlorination reaction did not proceed while propionic acid was accumulated after DCE was generated. Therefore, if an appropriate amount of MOD is supplied, MOD can be effectively used as a natural reduction activator to promote biodegradation in an aquifer contaminated by TCE.

Host Mussel Utilization for Spawning of the Oily Shinner, Sarcocheilichthys variegatus wakiyae (Pisces: Cyprinidae), Inhabiting the Dalcheon, Namhangang (river) from Korea (남한강 달천에 서식하는 참중고기 Sarcocheilichthys variegatus wakiyae (Pisces: Cyprinidae)의 산란숙주조개 이용에 관한 연구)

  • Kim, Hyeong Su;Yoon, Jung Do;Yang, Hyun;Park, Jong Young
    • Korean Journal of Ichthyology
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    • v.26 no.4
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    • pp.288-294
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    • 2014
  • Host mussel utilization for spawning of the oily shinner, Sarcocheilichthys variegatus wakiyae (Pisces: Cyprinidae), from Korea was investigated in part of the Dalcheon (river) in Cheongcheon-myeon, Goesan-gun, Chungcheongbuk-do, Korea from April to June 2011, 2013. The non-synchronicity of mature and immature eggs obtained from females of S. v. wakiyae and the number of spawned eggs found was less than those in the mussels, suggesting that these fish may be batch spawners. Five species of freshwater mussels - Unio douglasiae sinuolatus, Lanceolaria grayana, Anodonata arcaeformis flavotincta, Lamprotula leai, Corbicula fluminea - were found at the survey area (wild conditions) but three species of freshwater mussels - A. a. flavotincta (oviposition rate, 50.0%), U. d. sinuolatus (16.2%), L. leai (11.1%) - were host of S. v. wakiyae. Spawning of S. v. wakiyae occurred mainly in the mantle cavity (wild conditions, 77.4%; experiment, 62.8%) of the mussels that were connected more to the inhalant siphon than the suprabranchial cavity (22.6%; 31.8%) that linked to the exhalant siphon. Bitterlings prefer to lay eggs in L. leai and S. v. wakiyae prefers A. a. flavotincta as a spawning host. These were considered to be the result of niche partitioning.

Investigation of Manufacturing Parameters for Non-fibrous Ceramic Brake Pads using Taguchi Method (다꾸치법에 의한 무섬유 세라믹 브레이크 마찰재의 제조변수에 대한 고찰)

  • Yeo Jeong-Gu;Choi Sung-Churl
    • Korean Journal of Materials Research
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    • v.14 no.1
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    • pp.59-66
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    • 2004
  • In the present study, ceramic brake pads without fiber phases were manufactured by the low temperature heat treatment below$ 700 ^{\circ}C$. The manufacturing parameters of ceramic brake pads and those levels were investigated by the analysis results of signal-to-noise ratios, ANOVA based upon the Taguchi method. The ceramic brake pads prepared in the Mg experiment had a friction coefficient of 0.30~0.55 very close to the target coefficient (0.35~0.45) of commercial brake pads utilized in the automobiles. The frictional properties of ceramic brake pads could be stabilized with the adjustment of amounts of lubricating additives. The optimum preparation conditions as well as batch formulations for the fabrication of non-fibrous ceramic brake pads were finally determined using Taguchi method in this study.