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Variations of Temperature, Chemical Component and Helium Gas of Geothermal Water by Earthquake Events in Pohang Area (포항 지열수의 지진에 의한 수온, 화학성분 및 헬륨가스의 변화)

  • Lee, Yong Cheon;Jeong, Chan Ho;Lee, Yu Jin;Kim, Young-Seog;Kang, Tae-Seob
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.647-658
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    • 2021
  • In this study, the change of temperature, chemical composition, and helium gas of thermal water in Pohang area was observed from January 2018 to June 2019 in order to interpret the relationship with earthquake events. During observation period earthquakes above M 2.0 within 100 km in a radius from a geothermal well occurred 58 including two earthquake events with a magnitude of 3.0~3.9 and two earthquake events with a magnitude of 4.0~4.9. We introduce a q-factor and earthquake effectiveness (ε) to express the influence of each earthquake as magnitude and distance factors. The geothermal well of 715 m deep was developed in the Bulguksa biotite granite, and the water temperature was observed in the variation from 51.8 to 56.3℃ during monitoring period. At M 4.1 and M 4.6 earthquake events, the increase of geothermal water temperature (𝜟T 2.6~4.5℃) was recorded, and slight change in specific ionic components such as SO4 and Cl, and of chemical types on the Piper diagram were observed. In the 3He/4He vs 4He/20Ne diagram, the original mixing ratio of helium isotope before and after the magnitude 4.1 earthquake was slightly changed from 83.0% to 83.2% of crust-origin 4He, and the from 16.3% to 16.7% of mantle-origin 3He. Hot-cold water mixing ratio before and after earthquakes by using the quartz and chalcedony solubility curves of the silica-enthalpy mixing model was calculated to interpret the temperature change of geothermal water. The model calculation shows the increase of 6.93~7.72% and 1.65~4.94% of hot water ratio at E1 and E2 earthquakes, respectively. Conclusively, the magnitude of earthquake for observable change in the temperature and helium isotope of thermal water is of 4.1 or higher and q-factor value of 30.0 or higher in the study site.

CHANDRA SPECTROSCOPY OF SUPERNOVA REMNANT 3C 391

  • CHEN YANG;SU YANG;SLANE PATRICK O.;WANG Q. DANIEL
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.211-214
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    • 2005
  • We performed a spatially resolved spectroscopic study of the thermal composite supernova remnant 3C 391 by the Chandra observation. Broad- and narrow-band X-ray images show a southeast-northwest elongated morphology and unveil a highly clumpy structure of the remnant. The spectral analysis for. the small-scale features indicates normal metal abundance and uniform temperature for the interior gas. The properties of the hot gas are largely in agreement with the cloudlet evaporation model as a main mechanism for the 'thermal composite' X-ray appearance, though radiative rim and thermal conduction may also be effective. An unresolved X-ray source, with a power-law spectrum, is observed on the northwest border. The equivalent width images reveal a faint finger-like protrusion in Si and S lines out of the southwest radio border.

One-step microwave synthesis of magnetic biochars with sorption properties

  • Zubrik, Anton;Matik, Marek;Lovas, Michal;Stefusova, Katarina;Dankova, Zuzana;Hredzak, Slavomir;Vaclavikova, Miroslava;Bendek, Frantisek;Briancin, Jaroslav;Machala, Libor;Pechousek, Jiri
    • Carbon letters
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    • v.26
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    • pp.31-42
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    • 2018
  • Adsorption is one of the best methods for wastewater purification. The fact that water quality is continuously decreasing requires the development of novel, effective and cost available adsorbents. Herein, a simple procedure for the preparation of a magnetic adsorbent from agricultural waste biomass and ferrofluid has been introduced. Specifically, ferrofluid mixed with wheat straw was directly pyrolyzed either by microwave irradiation (900 W, 30 min) or by conventional heating ($550^{\circ}C$, 90 min). Magnetic biochars were characterized by X-ray powder diffraction, $M{\ddot{o}}ssbauer$ spectroscopy, textural analysis and tested as adsorbents of As(V) oxyanion and cationic methylene blue, respectively. Results showed that microwave pyrolysis produced char with high adsorption capacity of As(V) ($Q_m=25.6mg\;g^{-1}$ at pH 4), whereas conventional pyrolysis was not so effective. In comparison to conventional pyrolysis, one-step microwave pyrolysis produced a material with expressive microporosity, having a nine times higher value of specific surface area as well as total pore volume. We assumed that sorption properties are also caused by several iron-bearing composites identified by $M{\ddot{o}}ssbauer$ spectroscopy ([super] paramagnetic $Fe_2O_3$, ${\alpha}-Fe$, non-stoichiometric $Fe_3C$, ${\gamma}-Fe_2O_3$, ${\gamma}-Fe$) transformed from nano-maghemite presented in the ferrofluid. Methylene blue was also more easily removed by magnetic biochar prepared by microwaves ($Q_m=144.9mg\;g^{-1}$ at pH 10.9) compared to using conventional techniques.

CYTOGENETIC ANALYSIS OF CHILDREN WITH AUTISM (자폐장애 환자의 세포유전학적 분석)

  • Jung, Chul-Ho;Lee, Je-Young;Park, Young-Nam;Park, Jong-Han;Kim, Jung-Bum;Kim, Jae-Ryong;Chun, Hyo-Jin
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.5 no.1
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    • pp.108-117
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    • 1994
  • Twenty nine children with autism and thirty children with mental retardation were examined for association between autism and chromosomal disorders including fragile X. The peripheral blood was cultured in Medium 199 with methotrexate and without methorexate for 70 hours. Thirty metaphase cells in each case were karyotyped in all samples. Chromosomal abnormalities were found in 11 cases(37.9%) of autistic disorder and 10 cases (33.3%) of mental retardation, but in none of fragile(X)(q27.3) from all cases. Chromosomal abnormalities were present on group A, C, D and X in autistic disorder and on group A, B, C, D, E and X in mental retardation. No specific chromosomal region was found in both autistic disorder and mental retardation. Types of chromosomal disorders were only fragile and/or gap but no numerical abnormality was present in all cases. Number of cells which revealed fragile sites were 31 cells(3.6%) out of 870 cells in autistic disorder and 29 cells(3.2%) out of 900 cells in mental retardation Number of cells which revealed gaps were 43 cells(4.9%) out of 870 cells in autistic disorder and 35 cells(3.9%) out of 900 cells in mental retardation. Autistic disorder may not be directly correlated with fragile X but with nonspecific chromosomal breakages from these data.

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Chromosome Imbalances and Alterations in the p53 Gene in Uterine Myomas from the Same Family Members: Familial Leiomyomatosis in Turkey

  • Hakverdi, Sibel;Demirhan, Osman;Tunc, Erdal;Inandiklioglu, Nihal;Uslu, Inayet Nur;Gungoren, Arif;Erdem, Duygu;Hakverdi, Ali Ulvi
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.2
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    • pp.651-658
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    • 2013
  • Uterine leiomyomas (UL) are extremely common neoplasms in women of reproductive age, and are associated with a variety of characteristic choromosomal aberrations (CAs). The p53 gene has been reported to play a crucial role in suppressing the growth of a variety of cancer cells. Therefore, the present study investigated the effects of CAs and the p53 gene on ULs. We performed cytogenetic analysis by G-banding in 10 cases undergoing myomectomy or hysterectomy. Fluorescence in situ hybridization (FISH) with a p53 gene probe was also used on interphase nuclei to screen for deletions. In patients, CAs were found in 23.4% of 500 cells analysed, significantly more frequent than in the control group (p<0.001). In the patients, 76% of the abnormalities were structural aberrations (deletions, translocations and breaks), and only 24% were numerical. Deletions were the most common structural aberration observed in CAs. Among these CAs, specific changes in five loci 1q11, 1q42, 2p23, 5q31 and Xp22 have been found in our patients and these changes were not reported previously in UL. The chromosome breaks were more frequent in cases, from high to low, 1, 2, 6, 9, 3, 5, 10 and 12. Chromosome 22, X, 3, 17 and 18 aneuploidy was observed to be the most frequent among all numerical aberrations. We observed a low frequency of p53 losses (2-11%) in our cases. The increased incidence of autosomal deletions, translocations, chromatid breaks and aneuploidy, could contribute to the progression of the disease along with other chromosomal alterations.

An Assessment of Dietary Fiber Intake in Preschool Children in Busan (부산지역 학령전 아동의 식이섬유섭취 상태평가)

  • 임화재;김정인
    • Korean Journal of Community Nutrition
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    • v.7 no.2
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    • pp.167-176
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    • 2002
  • To assess the dietary fiber intake of preschool children in Busan and to evaluate the relationship between of the intake of dietary fiber and nutrient intake. Nutrient intake using 24 hour recall, and total dietary fiber (TDF) intake based on tables of TDF of common Korean floods developed by the modified Prosky Method, were estimated for 176 preschool children. The mean daily intakes of TDF, and TDF after adjusting energy intake, were 10.20 g and 7.69 g/1,000 kcal, respectively. The mean daily intakes of TDF for children aged 1-3 and 4-6 years were 9.20 g and 11.08 g, respectively. The range of TDF intake was 1.86 to 22.16 g. The major sources of TDF were cereals (31.0%), vegetables (18.9%) and fruits (11.9%). The TDF intake showed positive correlations with nutrient adequacy ratios (NAR) of iron and Vitamin $B_1$, (p < 0.05, p < 0.05). The TDF intake per 1,000 kcal showed negative correlations with the NARs of protein, calcium, phosphate, iron, Vitamin A, vitamin $B_1$, Vitamin $B_2$, and niacin (p < 0.001, p < 0.001, p < 0.001, p < 0.05, p < 0.001, p < 0.001, p < 0.001, p < 0.001) and with the mean adequacy ratio (MAR, p < 0.001). When children were stratified into quartiles ($Q_1-Q_4$) on the basis of their fiber intake per 1,000 kcal, their NARs for calcium, phosphate, iron, Vitamin A, Vitamin $B_1, Vitamin $B_2$ and niacin (p < 0.05, p < 0.05, p < 0.001, p < 0.05, p < 0.05, p < 0.001, p < 0.001), and their MAR (p < 0.001) were significantly lower in the children with higher fiber intake per 1,000 kcal (the upper quartile). The NARs fur calcium (0.63), iron (0.60), Vitamin A (0.66), Vitamin $B_2$(0.74), niacin (0.64), Vitamin C (0.65) and the MAR (0.74) were lower than 0.75 in the children with fiber intakes of more than 9.25 g per 1,000 local (0,), the highest fiber intake per 1,000 kcal. Based on these results, the mean TDF intake of children was higher than the age (yr)+5g , the minimum recommended level for American children. Meals with a fiber intake of more than 9.25 g per 1,000 local ($Q_4$) could cause a decreased nutritional status for minerals and vitamins. The result of this study could contribute to the establishment of Recommended Dietary Allowances (RDA) for dietary fiber for Korean Preschool children.

Analysis of the Runoff Characteristics of Small Mountain Basins Using Rainfall-Runoff Model_Danyang1gyo in Chungbuk (강우-유출모형을 활용한 소규모 산지 유역의 유출특성 분석_충북 단양1교)

  • Hyungjoon Chang;Hojin Lee;Kisoon Park;Seonggoo Kim
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.12
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    • pp.31-38
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    • 2023
  • In this study, runoff characteristics analysis was conducted as a basic research to establish a forecasting and warning system for flood risk areas in small mountainous basins in South Korea. The Danyang 1 Bridge basin located in Danyang-gun, Chungcheongbuk-do was selected as the study basin, and the watershed characteristic factors were calculated using Q-GIS based on the digital elevation model (DEM) of the basin. In addition, nine heavy rainfall events were selected from 2020 to 2023 using hydrometeorological data provided by the National Water Resources Management Comprehensive Information System. HEC-HMS rainfall-runoff model was used to analyze the runoff characteristics of small mountainous basins, and rainfall-runoff model simulation was performed by reflecting 9 heavy rainfall events and calculated basin characteristic factors. Based on the rainfall-runoff model, parameter optimization was performed for six heavy rain events with large error rates among the simulated events, and the appropriate parameter range for the Danyang 1 Bridge basin, a small mountainous basin, was calculated to be 0.8 to 3.4. The results of this study will be utilized as foundational data for establishing flood forecasting and warning systems in small mountainous basin, and further research will be conducted to derive the range of parameters according to basin characteristics.

Estimation of low flow by grid-based continuous hydrologic modelling (격자기반 분포형 수문모델링을 활용한 하천갈수량 산정)

  • Lee, Yonggwan;Jang, Wonjin;Lee, Jiwan;Han, Daeyoung;Kim, Seongjoon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.34-34
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    • 2021
  • 본 연구에서는 격자기반 분포형 수문모델링을 통해 하천갈수량을 추정하고자 한다. 분포형 수문모형은 단방향흐름 알고리즘에 의한 토양 물수지식을 기반으로 개발되었으며 운동파(kinematic wave) 이론을 적용하여 지표 및 지표하 유출을 모의한다. 또한, 격자별로 수문학적 물수지요소인 차단량, 증발산량, 침투 및 침루량, 지하수충전량 등을 계산하며, 댐·보 방류량을 해당 지점 격자의 물수지에 적용할 수 있도록 개발하였다. 본 모형은 2개의 다목적댐과 3개의 다기능보가 위치한 금강유역(9,645.5 km2)에 적용하였으며, 유역 면적과 하천 유속을 고려하여 1 km × 1 km 격자를 구성하고 10분 간격으로 2013년부터 2020년까지 수문모의를 진행하였다. 모형의 입력자료로 유역 인근의 12개 기상관측소로부터 시단위 기상자료를 구축하였으며, 모형의 검보정은 일단위 관측유량(Q), 플럭스 타워 증발산량, 실측 토양수분 및 지하수위 자료를 구축하여 활용하였다. 댐 및 보 지점에 대해 Q와 1/Q로 검보정을 수행한 결과, 평균 결정계수(R2)는 댐 지점에서 0.53~0.65, 보 지점에서 0.46~0.69의 값을 나타냈으며, Nash-Shtcliffe efficiency(NSE)는 댐 지점에서 0.46~0.55, 보 지점에서 0.31~0.65의 값을 나타냈다. 공간 보정을 위해 증발산량, 토양수분, 지하수위에 대한 검보정을 수행할 예정이며, 유황곡선을 활용하여 하천차수, 토양속성 및 토지이용에 따른 하천갈수량을 분석할 예정이다.

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Oxygen isotope study on the hydrothermal alteration in the Wolf River Batholith, Wisconsin in U.S.A

  • Kim, Sun-Joon
    • The Journal of the Petrological Society of Korea
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    • v.2 no.1
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    • pp.19-31
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    • 1993
  • Oxygen isotope compositions of whole rock and/or mineral separates (quartz and feldspar) have been determined for the granitic and related rocks from the Wolf River Batholith, Wisconsin. Hydrothermal alteration resulting in the decrease of ${\Delta}_{Q-F}$/ values was obaserved locally throughout the batholith. Feldspars of different colors (pink, gray and red) were separated whenever feasible and analyzed. Most red feldspars (An$_{10-30}$/) show the highest and constant ${\delta}^18O$/ values (9.3~10.0 permil) suggesting nearly complete isotope exchange with hydrothermal fluid. Based on ${\delta}^18O$/ values and the alteration temperatures (260~$350^{\circ}C$) estimated from fluid inclusion study, ${\delta}^18O$/ of fluid is calculated to be $5.0{\pm}1.4$ permil. Phanerozoic sedimentary formation water in Wisconsin is most likely the source of the fluid.

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Purification and Properties of Phenylalanine Ammonia-lyase from Chinese Cabbage

  • Lim, Hye-Won;Sa, Jae-Hoon;Kim, Tae-Soo;Park, Eun-Hee;Park, Soo-Sun;Lim, Chang-Jin
    • BMB Reports
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    • v.31 no.1
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    • pp.31-36
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    • 1998
  • Phenylalanine ammonia-lyase (PAL; EC 4.3.1.5), the first enzyme in the phenylpropanoid biosynthesis, catalyzes the elimination reaction of ammonium ion from L-phenylalanine. PAL was purified from the cytosolic fraction of Chinese cabbage (Brassica campestris ssp. napus var. pekinensis) through ammonium sulfate fractionation, DEAE-cellulose chromatography, Sephadex G-200 chromatography, and Q-Sepharose chromatography. It consists of four identical subunits, the molecular mass of which was estimated to be about 38,000 daltons on SDS-PAGE. The optimal pH and temperature of the purified enzyme are 8~9 and $45^{\circ}C$, respectively. Its activity is greatly inhibited by $Zn^{2+}$ ion, and strongly activated by caffeic acid. The purified PAL has some different characteristics compared to those obtained with other PALs.

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