• 한국표면공학회지
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• 제49권2호
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• pp.147-151
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• 2016

The T91 steel (Fe-9%Cr-1%Mo) was corroded at 600 and $700^{\circ}C$ for 5 - 70 h in the $N_2$/(0.5, 2.5)%$H_2$Smixed gas at one atm. It was corroded fast, forming the outer FeS layer and the inner (FeS, $FeCr_2O_4$)-mixed layer. The formation of the outer FeS layer facilitated the oxidation of Cr to $FeCr_2O_4$ in the inner layer. Since the nonprotective FeS scale was present over the whole scale, T91 steel displayed poor corrosion resistance.

• 공업화학
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• 제9권7호
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• pp.1023-1029
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• 1998

5Cr-1Mo steel을 이용하여 나트륨 분위기에서 미량 물 누출 실험을 수행하였다. 시편에서 미량 물 누출로 인한 누출경로의 완전 re-open time은 129분으로 나타났고, 그 크기는 직경 2mm를 나타냈다. 누출경로는 re-open되기 전에 누출부위를 중심으로 halos현상을 형성하였으며, halos의 크기와 실제 re-open크기와는 다르게 나타났다. 나트륨-물 반응으로 인한 재질의 부식은 나트륨부위로부터 시작되었으며, steam 부위에서는 부식이 발생하지 않았다. 시편 누출부위를 AES로 분석한 결과 Cr의 segregation이 가장 많이 나타났으며, SEM과 EPMA 관찰로부터 나트륨화합물들이 누출부위 주변에 대량 침적되어 있는 것이 관찰되어 나트륨 철 크롬혼합물 형태로 부식생성물들이 혼재되어 있는 것으로 예측되었다.

• 대한기계학회논문집A
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• 제35권3호
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• pp.251-257
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• 2011

본 연구는 차세대 원자로의 후보 재료인 수정 9Cr-1Mo 강에 대한 크리프 균열 성장률 법칙, da/dt=B$(C^*)^q$의 파라메터 B와 q에 대한 통계적 성질에 대하여 취급하였다. 본 해석에 이용된 크리프 균열 성장 데이터는 $600^{\circ}C$의 일정 온도에서 5000N의 동일 하중하의 1/2 CT 시험편에 대하여 크리프 균열 성장 실험을 수행하였다. 크리프 균열 성장 거동은 크리프 균열 성장률 da/dt 와 파괴역학 파라메터 $C^*$와의 실험적 관계식으로부터 통계적으로 해석하였다. 각각의 시험편에 대한 파라메터 B와 q는 최소자승법에 의하여 결정하였다. B와 q에 대한 확률분포함수를 정규분포, 대수정규분포 그리고 와이블분포에 대하여 조사하였다. 본 연구에 의하면, B와 q의 확률분포함수는 대수정규분포와 와이블분포에 비교적 잘 따름을 알았다. 또한 이들 사이에는 강한 양의 선형적인 상관이 있음을 알았다.

• 대한기계학회논문집A
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• 제20권9호
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• pp.2819-2832
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• 1996

The estimation of the remaining life for the aged components in power plant as well as chemical and petroleum plants has been recently concerned. The raw materials used in this study are the 1Cr-1Mo-0.25V steel which intensified P and S compositions along with the nominal compositions of ASTM A 470 standard. Five kinds of specimens with the different degradation levels were prepared by isothermal aging heat treatment at 630.deg.C. The mechanical properties and rotated bending fatigue strength of virgin and aged 1Cr-1Mo-0.25V steel have been investigated through the hardness, tensile, fatigue test, SEM fractograph and EDS analysis at 538.deg.C and room temperature, respectively. Thus the data of aged specimens were compared with those of virgin specimen to evaluate the aging effects. The main results obtained in this study are as follows ; The decrease of the yield and tensile strength due to degradation was distinguished until 50, 000hrs simulated service time. And it was confirmed that the considerable amount of P, Mn, Cr and S was precipitated at the grain boundary of aged material through the SEM and EDS analysis. The rotated bendingd fatigue strength at 538.deg.C of virgin, 25, 000, 50, 000, 75, 000 and 100, 000 hrs aged material was decreased 44.6 %, 49.6 %, 51.5 %, 52.4% and 53.8% than that of virgin material at 10$_{7}$cycles of room temperature, respectively. The major cracks of virgin and aged materials mainly initiated at the inclusions including Si, P and Mn compositions which were located at the outer periphery of the specimen.n.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2005년도 창립60주년 기념 추계 학술대회
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• pp.118.1-118.1
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• 2005

• Corrosion Science and Technology
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• 제2권1호
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• pp.12-17
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• 2003

The effects of Cr content and film formation potential on electronic behaviors of the passive film on Fe-Cr alloys were investigated in borate buffer solution. Influence of pH on passive films of both Fe-Cr and Fe-Cr-Mo alloys was also investigated. Mott-Schottky and cyclic voltammetry techniques were used to elucidate electronic behaviors of passive films and their electrochemical characteristics. AES analysis of passive films was carried out. Results showed that doping density decreased as Cr content and film formation potentials increased. The addition of Mo to Fe-Cr alloy had little influence on donor densities in pH 9.2 solution but some effects on the decrease in donor densities in pH 1.6 acidic solution.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집A
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• pp.111-116
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• 2001

Small punch-creep(SP-Creep) test technique has been applied for evaluating the creep characteristics for high temperature materials. However, in order to evaluate the damage and predict the remaining life, it is necessary to establish a quantitative correlation between SP-Creep and uniaxial-creep test results. This paper presents analytical and experimental results of useful correlation between SP-Creep and uniaxial-creep properties for 9Cr1MoVNb steel at $600{\sim}650^{\circ}C$ in terms of stress(load) and activation energy during creep deformation. Especially, the activation energy obtained from SP-Creep test is linearly related to that from uniaxial-creep test at $650^{\circ}C$ as follows: $Q_{sp-p}{\fallingdotseq}1.37\;Q_{TEN},\;Q_{sp-{\sigma}}{\fallingdotseq}1.53\;Q_{TEN}$.

• 대한금속재료학회지
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• 제47권10호
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• pp.621-628
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• 2009

Thermomechanical processes were carried out to evaluate their effects on the mechanical and the microstructural property of a ferritic-martensitic steel. Modified 9Cr-1Mo steels were hot-rolled at a temperature of either $780^{\circ}C$ or $850^{\circ}C$ after normalizing at $1050^{\circ}C$ and then were air-cooled. Continuous annealing at $850^{\circ}C$ for 2 hours immediately after the hot rolling was also performed and they were compared to the specimens without thermomechanical process. The result showed that there were little differences between the hot rolled specimens in terms of the precipitation density and size. However, V content inside the MX precipitates increased in the case of the specimen rolled at $850^{\circ}C$. The application of the continuous annealing induced coarsening of the Nb-rich MX precipitation as well as an increase in the amount of V-rich MX precipitation, which is expected to enhance high temperature mechanical properties of the ferritic-martensitic steel.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.385-386
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• 2006

For attaining optimum fatigue resistance of PM steels, high density levels are necessary. In this work, sintered steels Fe-1.5%Mo-0.6%C and Fe-1.5%Cr-0.2%Mo-0.6%C were produced with density levels of 7.1 to $7.6\;g.cm^{-3}$. Ultrasonic fatigue testing with 20 kHz was performed in push-pull mode up to 10E9 cycles. It was shown that the fatigue endurance strength is strongly improved by higher density levels, but also higher sintering temperatures are beneficial. The Cr-Mo steels proved to be superior to the plain Mo alloyed, due to a more favourable as-sintered matrix microstructure.

• Nuclear Engineering and Technology
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• 제51권1호
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• pp.249-256
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• 2019

The 9Cr-1Mo ferritic-martensitic ODS steel is a promising structural material for the next generation nuclear power plants including fast reactors for application in reactor vessels and nuclear fuel. The ODS steel was cooled down by furnace cooling, air cooling, oil quenching and water quenching, respectively, after normalizing it at $1150^{\circ}C$ for 1 h and then tempering at $780^{\circ}C$ for 1 h. It is found that grain size, a relative portion of ferrite and martensite, martensitic lath configuration, behaviors of carbide precipitates, and hardness of the ODS steel are strongly dependent on a cooling rate. The grain size and martensitic lath width become smaller with the increase in a cooling rate. The carbides were precipitated at the grain boundaries formed between the ferrite and martensite phases and at the martensitic lath interfaces. In addition, the carbide precipitates become smaller and more widely dispersed with the increase in a cooling rate, resulting in that the faster cooling rate generated the higher hardness of the ODS steel.