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Corrosion of Fe-9%Cr-1%Mo Steel at 600 and 700℃ in N2/(0.5, 2.5)%H2S-mixed Gas

  • Lee, Dong Bok (School of Advanced Materials Science and Engineering, Sungkyunkwan University) ;
  • Abro, Muhammad Ali (School of Advanced Materials Science and Engineering, Sungkyunkwan University) ;
  • Yadav, Poonam (School of Advanced Materials Science and Engineering, Sungkyunkwan University) ;
  • Bak, Sang Hwan (School of Advanced Materials Science and Engineering, Sungkyunkwan University) ;
  • Shi, Yuke (School of Advanced Materials Science and Engineering, Sungkyunkwan University) ;
  • Kim, Min Jung (School of Advanced Materials Science and Engineering, Sungkyunkwan University)
  • Received : 2016.03.29
  • Accepted : 2016.04.12
  • Published : 2016.04.30

Abstract

The T91 steel (Fe-9%Cr-1%Mo) was corroded at 600 and $700^{\circ}C$ for 5 - 70 h in the $N_2$/(0.5, 2.5)%$H_2$Smixed gas at one atm. It was corroded fast, forming the outer FeS layer and the inner (FeS, $FeCr_2O_4$)-mixed layer. The formation of the outer FeS layer facilitated the oxidation of Cr to $FeCr_2O_4$ in the inner layer. Since the nonprotective FeS scale was present over the whole scale, T91 steel displayed poor corrosion resistance.

Keywords

References

  1. G. Y. Lai, High-Temperature Corrosion and Materials Applications, ASM International, USA (1990) 201-234.
  2. N. J Simms, J. F Norton, T. M. Lowe, Alloy corrosion in a coal gasification system, J. Phys. IV, 3 (1993) 807-816.
  3. R. John, Shreir's Corrosion, vol. 1, 4th ed., (eds. R. A. Cottis, M. J. Graham, R. Lindsay, S. B. Lyon, J. A. Richardson, J. D. Scantlebury, and F. H. Stott), Elsevier, UK (2010) 240-271.
  4. N. Birks, G. H. Meier, F. S. Pettit, Introduction to the High Temperature Oxidation of Metals, 2nd ed., Cambridge University Press, USA (2006) 163-168.
  5. D. J. Young, High Temperature Oxidation and Corrosion of Metals, T. Burstein, 1st ed., Elsevier, UK (2008) 361-396.
  6. S. Mrowec, K. Przybylski, Transport properties of sulfide scales and sulfidation of metals and alloys, Oxid. Met, 23 (1985) 107-139. https://doi.org/10.1007/BF00659899
  7. S. Mrowec, T. Walec, T. Werber, High-temperature sulfur corrosion of iron-chromium alloys, Oxid. Met., 1 (1969) 93-120. https://doi.org/10.1007/BF00609926
  8. A. S. Khanna, P. Rodriguez, J. B. Gnanamoorthy, Oxidation kinetics, breakaway oxidation, and inversion phenomenon in 9Cr-1Mo steels, Oxid. Met., 26 (1986) 171-200. https://doi.org/10.1007/BF00659183
  9. A. P. Greeff, C. W. Louw, H. C. Swart, The oxidation of industrial FeCrMo steel, Corros. Sci., 42 (2000) 1725-1740. https://doi.org/10.1016/S0010-938X(00)00026-3
  10. D. Laverde, T. Gomez-Acebo, F. Castro, Continuous and cyclic oxidation of T91 ferritic steel under steam, Corros. Sci., 46 (2004) 613-631. https://doi.org/10.1016/S0010-938X(03)00173-2
  11. F. Gesmundo, F. Viani, W. Znamirowski, K. Godlewski, F. Bregani, The Corrosion of iron and of three commercial steels in $H_2-H_2S$ and in $H_2-H_2S-CO_2$ gas mixtures at $400-700^{\circ}C$, Mater. Corros., 43 (1992) 83-95. https://doi.org/10.1002/maco.19920430302
  12. M. A. Abro, D. B. Lee, Aluminizing and corrosion of carbon steels in $N_2$-0.5%$H_2S$ gas at $650-850^{\circ}C$, J. Kor. Inst. Surf. Eng., 48 (2015) 110-114. https://doi.org/10.5695/JKISE.2015.48.3.110
  13. M. Danielewski, S. Mrowec, A. Stolosa, Sulfidation of iron at high temperatures and diffusion kinetics in ferrous sulfide, Oxid. Met., 17 (1982) 77-97. https://doi.org/10.1007/BF00606194
  14. I. Barin, Thermochemical Data of Pure Substances, VCH, Germany (1989).
  15. L. B. Pankratz, A. D. Mah, S. W. Watson, Thermodynamic properties of sulfides, U.S. Bur. Min. Bull., 689 (1987) 472.
  16. M. J. Kim, D. B. Lee, Corrosion of Fe-(4.8, 9.2, 14.3) wt% Al alloys at 700 and $800^{\circ}C$ in $N_2/H_2O/H_2S$ gases, Met. Mater. Int., 19 (2013) 975-982. https://doi.org/10.1007/s12540-013-5009-z
  17. A. S. Khanna, Introduction to High Temperature Oxidation and Corrosion, ASM International, USA (2002) 204.
  18. Gmelin Institute for Inorganic Chemistry, Gmelin Handbook of Inorganic Chemistry, Vol. A7, 8th ed., Springer, Germany (1987).
  19. E. McCafferty, Introduction to Corrosion Science, Springer, USA (2010) 236.