• Title/Summary/Keyword: 6W2H

Search Result 2,820, Processing Time 0.033 seconds

Crystal Structure of Pentapotassium Disodium Hexatungstoantimonate(V) Dodecahydrate, $K_5Na_2[SbW_6O_{24}]\cdot12H_2O$

  • Lee, Uk;Sasaki, Yukiyoshi
    • Bulletin of the Korean Chemical Society
    • /
    • v.8 no.1
    • /
    • pp.1-3
    • /
    • 1987
  • The crystal structure of $K_5Na_2[SbW_6O_{24}]{\cdot}12H_2O$ has been determined. Final R = 0.081 for 890 observed independent reflections collected by diffractometry. Crystal data as follows; trigonal, space group R3m, a = 9.794(1) ${\AA},\;{\alpha}$ = 84.72$(1)^{\circ}$, Z = 1. The heteropolyanion has a structure with point symmetry $D_{3d}$ (3m), of the ideal Anderson-type heteropolyanion. The Sb-W and W-W distances are 3.259(2) and 3.259(3) ${\AA}$. Three types of W-O ($W-O_t,\;W-O_b\;and\;W-O_c$) distances are 1.73(2), 1.95(4) and 2.20(3) ${\AA}$. The Sb-O distance is 1.97(3) ${\AA}$.

A Study on Development of the Secondary Reverse Vortex in Building Canyon (건물협곡에서의 2차 역회전 소용돌이 형성에 관한 연구)

  • Son, Minu;Kim, Do-Yong
    • Journal of the Korean Society for Environmental Technology
    • /
    • v.19 no.6
    • /
    • pp.528-535
    • /
    • 2018
  • In this study, the effect of obstacle aspect ratio on vortex in building canyon was numerically investigated using a computational fluid dynamics(CFD) model. The sensitivity experiments were performed in the cases of increasing building length(L) and height(H) by the width(W) of building canyon. The wind vector fields and secondary reverse vortex in building canyon were discussed in this study. For the horizontal vortex, the vortex zone increased as the building length increases, but the vectors at the middle of building canyon began to change in the case of L/W=2.5. In the case of L/W=3.0, the smaller primary vortex was presented with the secondary reverse vortex. For the vertical vortex, the vortex zone increased as the building height increases, but the direction of vectors at the bottom of building canyon began to change in the case of H/W=2.5. In the case of H/W=3.5, the smaller primary vortex was presented with the secondary reverse vortex.

Purification of Cellulase Produced from Cellulomonas sp. YE-5 (Cellulomonas sp. YE-5가 생산하는 Cellulase의 정제)

  • 최동철;허남윤;오두환;유주현
    • Microbiology and Biotechnology Letters
    • /
    • v.18 no.4
    • /
    • pp.376-382
    • /
    • 1990
  • An extracellular cellulase producing bacterium YE-5 was isolated from soil, and identified as a Cellulomonas sp. by its taxonomical characteristics. The maximal activities of avicelase (0.35 units/ml), CMCase (3.18 units/ml), FPase (0.315 units/ml) and $\beta$-glucosidase (0.882 units/ml) were obtained when this strain was cultured for 48 hrs at $30^{\circ}C$ in a medium containing 0.8% (w/v) Solka floc, 0.06010 (wlv) urea, 0.1% (w/v) $K_2HP0_4$, 0.1% (w/v) $MgS0_4.7H2_0$, 0.2% (w/v) bacto peptone, 0.2% (w/v) yeast extract and pH 6.5. The cellulase was purified by ammonium sulfate fractionation, DEAE-Sepharose column chromatography and Sephadex 6-100 column chromatography from culture filtrate of Cellulomonus sp. YE-5. The molecular weights of purified avieelase, CMCase I, and CMCase II were estimated to be about 95,000 ~ 105,000, 46,000 ~ 47,000 and 120,000 ~ 125,000, respectively.

  • PDF

1H NMR Study of Aziridine Derivatives Coordinated to the Paramagnetic Undecatungstocobalto(II)silicate and -nickelo(II)silicate Anions

  • 박석민;서현수
    • Bulletin of the Korean Chemical Society
    • /
    • v.18 no.9
    • /
    • pp.1002-1006
    • /
    • 1997
  • 1H NMR spectra of D2O solutions containing 2,2-dimethylaziridine (1) or 2-methylaziridine (2) and [SiW11COⅡO39]6- (SiW11Co) or [SiW11NiⅡO39]6- (SiW11Ni) exhibit separate signals for the free ligand and the complex, indicating that the ligand exchange is slow on the NMR time scale. Identified are two linkage isomers with the methyl group of 2 at trans or cis position with respect to the metal. The isotropic shifts of 1 and 2 coordinated to SiW11Ni originate mainly from the contact shifts, and they agree reasonably with the relative values reported for similar ligands coordinated to bis(2,4-pentanedionato)nickel(Ⅱ). The isotropic shifts for the SiW11Co complexes were separated into contact and pseudocontact contributions. The pseudocontact shifts show that (χ∥-χ⊥) is positive, while that for the SiW11Co complexes of pyridine derivatives is negative. This result indicates that the ordering of dxy and dxz, dyz orbitals in SiW11Co complexes can be reversed by ligands.

A New Single Nucleotide Polymorphism in the IGF-I Gene and Its Association with Growth Traits in the Nanjiang Huang Goat

  • Zhang, Chunxiang;Zhang, Wei;Luo, Hailing;Yue, Wenbin;Gao, Mingyu;Jia, Zhihai
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.21 no.8
    • /
    • pp.1073-1079
    • /
    • 2008
  • The objectives of this study were to identify polymorphisms of insulin-like growth factor I (IGF-I) gene and to investigate their association with growth traits in Nanjiang Huang goats. Five hundred and ninety-two animals were used to detect the polymorphisms in the complete coding sequence, part of introns and the 5'-regulatory region of the IGF-I gene by means of PCR-SSCP. A new single nucleotide polymorphism (G to C transversion) was identified at intron 4 of the IGF-I gene in the goats. Two alleles and three genotypes were observed in this group. The frequency of G and C alleles was 54.6 and 45.4%, respectively. The statistical analysis showed that polymorphism of the IGF-I gene had a significant association (p<0.05) with birth weight (BW), body weight at 6 months (W6) and at 12 months (W12), heart girth at 2 months (G2), body length at 6 months (L6), wither height at 6 months (H6) and at 12 months (H12) and heart girth at 12 months (G12). The goats with genotype CC had significantly higher BW, W6, W12, G2, L6, H6, H12 and G12 than those with genotype GC and had significantly higher W12, H6, H12 and G12 than those with genotype GG. Therefore, genotype CC may be the most advantageous for growth traits in the Nanjiang Huang goat. However, no significant association between SNP genotypes and other growth traits was observed. These results indicated that the SNP marker of the IGF-I gene may be a potential molecular marker for growth traits in Nanjiang Huang goats.

An extension of new laser pulse atom-probe construction and time-of-flight mass spectrum of $H_2$ and He gas (A new laser pulse atom-probe 제작 및 $H_2$ 가스와 He 가스의 time-of-flight mass spectrum)

  • 송순달;홍남관
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.7 no.3
    • /
    • pp.465-472
    • /
    • 1997
  • An extension of new test methods for surfaces with an apparatus based on photon-induced desorption and ionisation in the electric field, is constructed and tested, It also investigates how to show the efficiency of the arrangement adsorbates $H_2$ and He on W(110). The field emitter temperature was 80 K. The wavelength of light used was 193 nm with field strengths between 10 and 50 V/nm. Many ion fragments($CO^+, He^+, H_2^^+, H_2O^+, W^{3+}\; and\; W^{2+}$) were produced by an electronic stimulation of the adsorbate with the help of a photon energy of 6.4 eV at He and $H_2$/W(110). A transient recorder enables the registration of the entire mass spectrum.

  • PDF

Antioxidant Properties and Protective Effects of Inula britannica var. chinensis Regel on Oxidative Stress-induced Neuronal Cell Damage (금불초 추출물의 항산화 효과 및 산화 스트레스에 대한 신경세포 보호작용)

  • Lee, Na-Hyun;Hong, Jung-Il;Kim, Jin-Yung;Chiang, Mae-Hee
    • Korean Journal of Food Science and Technology
    • /
    • v.41 no.1
    • /
    • pp.87-92
    • /
    • 2009
  • The antioxidant properties and protective effects of Inula britannica on ${H_2}{O_2}$-induced SH-SY5Y neuroblastoma cell damage were investigated. A series of solvent fractions, including hexane(Fr.H), petroleum ether, chloroform, ethyl acetate(Fr.EA), and water fraction(Fr.W), were prepared from the 70% methanol extracts of Inula britannica. Fr.W had the highest total contents of phenolics and flavonoids, followed by Fr.EA. The antioxidant properties of the fractions were also evaluated by analyzing their scavenging activities on 1,1-diphenyl-2-picrylhydrazyl(DPPH) radicals, 2,2'-azinobis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) radicals, and nitric oxide. Fr.W showed the strongest activities in all assays. The concentrations of Fr.W that resulted in 50% reductions of the DPPH and ABTS radicals were 20.7 ${\mu}g$/mL and 39.4 ${\mu}g$/mL, respectively. Fr.W showed the weakest cytotoxic activities on the SH-SY5Y cells, whereas it effectively protected ${H_2}{O_2}$-induced cell death, increasing cell survival by 35.0-77.0% at a concentration range of 62.5-250 ${\mu}g$/mL. In this range, Fr.W also significantly decreased intracellular ROS levels by 34-39%. Overall, the antioxidant properties of Inula britannica can contribute to rescuring neuronal cells from oxidative stress-induced cell injury.

A Study of Service Decision Method in Context Awareness System (상황인식 시스템에서의 서비스 결정 방법에 관한 연구)

  • Heo, Kyeong-Wook;Ha, Kyeong-Jae
    • Journal of Digital Convergence
    • /
    • v.10 no.6
    • /
    • pp.253-258
    • /
    • 2012
  • In this thesis, I categorize expression of context data required for context data inference according to five Ws and one H(5W1H) in Ubiquitous computing environment and infer superordinate context by combining context data of 4W1H with inferred context of why. This thesis suggests that we categorize specific context and service according to 6W2H added Whom(specific data or service) and How much (accuracy), and determine proper services for specific contexts by introducing the concept of rough set for expression and inference of categorized contexts and inaccurate knowledge. Since there is an limitation of the set of 0 and 1 when concerned with accuracy of services, I introduce the concept of fuzzy set. To provide users with the most appropriate service by ridding of unnecessary properties through the process of reduction, I also use the concept of rough set.

Technical Development of Hot Sauce with Red Pepper (생홍고추를 이용한 핫소스 제조 기술)

  • Kwon, Dong-Jin;Kim, Yoo-Jin;Lee, Sung;Yoo, Jin-Yong
    • Korean Journal of Food Science and Technology
    • /
    • v.30 no.2
    • /
    • pp.391-396
    • /
    • 1998
  • To inhibit the import of hot sauce, the manufacturing process of the Korean type hot sauce was developed. Chemical analysis of the imported hot sauce showed as follows; moisture 95.66% (w/w), salt 2.79% (w/w), titratable acidity 3.62% (w/w), crude fiber 0.42% (w/w), reducing sugar 0.03% (w/w), capsanthin 0.89% (w/w), capsaicin 4.28 mg% and pH 3.26. Korean type hot sauce prepared with red pepper, salt and vinegar was aged in oak barrel for 12 months at $10^{\circ}C$. Chemical analysis of the Korean type hot sauce showed as follows; moisture 92.05% (w/w), salt 8.82% (w/w), titratable acidity 3.88% (w/w), crude fiber 3.14% (w/w), reducing sugar 1.78% (w/w), capsanthin 0.13% (w/w), capsaicin 2.32 mg% and pH 3.29. Among chemical components, the contents of reducing sugar, salt and crude fiber except capsaicin and capsanthin were more than those of imported one. Chemical components of the Korean type hot sauce were changed slightly during aging for 12 months. The cell counts of yeast were increased from $3.2{\times}10^2\;to\;5.2{\times}10^6$ till the second month and those of lactic acid bacteria were increased from $3.{\times}10^1\;to\;1.5{\times}10^7$ till the third month, those of yeast and lactic acid bacteria decreased from the eighth month showed $6.6{\times}10^4$ and not detectable on the twelfth month, respectively. As the results of sensory evaluation on the Korean type hot sauce were evaluated to be superior to the imported to be superior to the imported one.

  • PDF

A numerical study for near building effects on concentration fields of the skimming flow in an urban street canyon (도시 협곡내 skimming flow 내의 농도장에 주변 건물이 미치는 영향에 관한 수치 해석적 연구)

  • 정상진
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2000.11a
    • /
    • pp.203-204
    • /
    • 2000
  • 도시협곡 내에서 형성되는 전형적인 유동장은 협곡내부에서 형성되는 회전류(vortex)이다(Berkowicz, 1998). Oke(1988)에 따르면 단면비가 큰 경우 (W/H>2.5), 도시 협곡내 유동장은 isolated roughness flow, 단면비가 중간인 경우(1.538

  • PDF