• Title/Summary/Keyword: 6LiF

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Experimental Study on the Determination of Absorbed dose Index (흡수선량지수결정(吸收線量指數決定)에 관한 실험적(實驗的) 연구(硏究))

  • Jun, Jae-Shik;Rho, Chae-Shik;Ro, Seung-Gy;Ha, Chung-Woo;Yoo, Young-Soo;Lee, Hyun-Duk
    • Journal of Radiation Protection and Research
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    • v.7 no.1
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    • pp.34-48
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    • 1982
  • The prime purpose of this study is to realize an index quantity, absorbed dose index, defined by the ICRU for the characterization of ambient radiation level at any location for the purpose of radiation protection. The experiment has been designed to be carried out in two phases, namely, preliminary and main experiment. In the primary study a 30cm diameter sphere of polyethylene was used, while in the main experiment that of tissue equivalent material was fabricated and used. Both experiments were performed in the gamma-ray fields of $^{137}Cs\;and\;^{60}Co$, and in a neutron beam of thermal column of the TRIGA MARK-II research reactor. In the measurement of gamma-ray absorbed dose TLD-700 $(^{7}LiF)$ chips were used, and for the neutron dose both Au activation foils and TLD chips (TLD-600 $(^{6}LiF)$ and TLD-700 for the discrimination of gamma-ray contribution) were used. Theoretical assessment of the absorbed dose in the sphere phantom has been carried out in accordance with the Ehrlich's idea that deduced on the basis of Burlin's cavity theory in the case of gamma-ray irradiation. For the analysis of neutron dose fluence-KERMA rate conversion method was used. The explanation on the dose assessment is given in detail. Results obtained were numerically and statistically analyzed and the depth dose distributions are presented in the graphic forms with normalized values. In the concluding remarks, the possibility and difficulty of realizing the index quantity, including questions and problems to be solved are mentioned.

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A prototype of the SiPM readout scintillator neutron detector for the engineering material diffractometer of CSNS

  • Yu, Qian;Tang, Bin;Huang, Chang;Wei, Yadong;Chen, Shaojia;Qiu, Lin;Wang, Xiuku;Xu, Hong;Sun, Zhijia;Wei, Guangyou;Tang, Mengjiao
    • Nuclear Engineering and Technology
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    • v.54 no.3
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    • pp.1030-1036
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    • 2022
  • A high detection efficiency thermal neutron detector based on the 6LiF/ZnS(Ag) scintillation screens, wavelength-shifting fibers (WLSF) and Silicon photomultiplier (SiPM) readout is under development at China Spallation Neutron Source (CSNS) for the Engineering Material Diffractometer (EMD).A prototype with a sensitive volume of 180mm×192mm has been built. Signals from SiPMs are processed by the self-design Application Specific Integrated Circuit (ASIC). The performances of this detector prototype are as follows: neutron detection efficiency could reach 50.5% at 1 Å, position resolution of 3, the dark count rate <0.1Hz, the maximum count rate >200KHz. Such detector prototype could be an elementary unit for applications in the EMD detector arrays.

Polymer-Ceramic Composite Gel Polymer Electrolyte for High-Electrochemical-Performance Lithium-Ion Batteries (고성능 리튬 이온전지를 위한 폴리머-세라믹 복합 겔 고분자 전해질)

  • Jang, So-Hyun;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.19 no.4
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    • pp.123-128
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    • 2016
  • In this study, poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP)-based gel polymer electrolyte incorporating nano-size $Al_2O_3$ ceramic particle was prepared by electrospinning. The gel polymer electrolyte (GPE) incorporated with $Al_2O_3$ ceramic particle showed higher ionic conductivity of $9.5{\times}10^{-2}Scm^{-1}$ than pure PVdF-HFP GPE without ceramic particle and improved the electrochemical stability up to 5.2 V. The GPEs were assembled with $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ (NMC) cathode for electrochemical test. The GPE batteries at 0.1 C-rate delivered $168.2mAh\;g^{-1}$ for pure GPE and $189.6mAh\;g^{-1}$ for hybrid GPE, respectively. Therefore, the incorporation of high dielectric constant ceramic particle will be good strategy to enhance the stability and electrochemical properties of lithium ion gel polymer batteries.

Low Temperature Sintering and Microwave Dielectric Properties of Ca[Ti1-x(Ni1/3Nb2/3)x]O3 Ceramics (Ca[Ti1-x(Ni1/3Nb2/3)x]O3 세라믹스의 저온소결 및 마이크로파 유전특성)

  • Lee, Young-Gyu;Kim, Hyo-Tae;Nam, Joong-Hee;Kim, Jong-hee;Paik, Ungyu
    • Journal of the Korean Ceramic Society
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    • v.43 no.1 s.284
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    • pp.55-61
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    • 2006
  • The microwave dielectric properties and low temperature sintering of $Ca[Ti_{1-x}(Ni_{1/3}Nb_{2/3})_x]O_3$ system were investigated at the sintering temperature $1,200\~1,350^{\circ}C$. The density and quality factors $(Q{\times}f)$ increased while dielectric constants slightly decreased with the decrease of Ti. The dielectric constant, quality factor, and temperature coefficient of resonance frequency $(\tau_f)$ were 64, 17,000 GHz, and $-9.1\;ppm/^{\circ}C$ respectively, when $CaTi_{1/2}(Ni_{1/3}Nb_{2/3})_{1/2}O_3$ ceramics were sintered at $1,300^{\circ}C$ for 4 h. $2Li_2O-B_2O_3$ was added to $CaTi_{1/2}(Ni_{1/3}Nb_{2/3})_{1/2}O_3$ to decrease the sintering temperature for LTCC application. The microwave dielectric properties of the samples sintered at $925^{\circ}C$ for 2 h with the addition of $6\;wt\%\;2Li_2O-B_2O_3$ were $\varepsilon_r=48.7,\;Q{\times}f=8,460\;GHz$, and $\tau_f=+5.6ppm/^{\circ}C$. Compatibility test of the composition with silver electrode shows no reaction with silver electrode, implying the feasibility as a high-K LTCC material.

Diagnostic Value of 18F-FDG PET/CT in Comparison to Bone Scintigraphy, CT and 18F-FDG PET for the Detection of Bone Metastasis

  • Liu, Ning-Bo;Zhu, Lei;Li, Ming-Huan;Sun, Xiao-Rong;Hu, Man;Huo, Zong-Wei;Xu, Wen-Gui;Yu, Jin-Ming
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.6
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    • pp.3647-3652
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    • 2013
  • Purpose: To evaluate the diagnostic value of $^{18}F$-FDG PET/CT for detection of bone metastasis in comparison with the efficacies of $^{18}F$-FDG PET/CT, CT, $^{18}F$-FDG PET and conventional planar bone scintigraphy in a series of cancer patients. Methods: Five hundred and thirty patients who underwent both $^{18}F$-FDG PET/CT and bone scintigraphy within 1 month were retrospectively analyzed. The skeletal system was classified into 10 anatomic segments and interpreted blindly and separately. For each modality, the sensitivity, specificity, accuracy, PPV and NPV were calculated and the results were statistically analyzed. Results: Bone metastases were confirmed in 117 patients with 459 positive segments. On patient-based analysis, the sensitivity, specificity, accuracy, PPV and NPV of $^{18}F$-FDG PET/CT were significantly higher than bone scintigraphy, CT and $^{18}F$-FDG PET (P<0.05). On segment-based analysis, the sensitivity of CT, bone scintigraphy, $^{18}F$-FDG PET and $^{18}F$-FDG PET/CT were 70.4%, 89.5%, 89.1% and 97.8%, respectively (P<0.05, compared with $^{18}F$-FDG PET/CT). The overall specificity and accuracy of the four modalities were 89.1%, 91.8%, 90.3%, 98.2% and 90.3%, 90.9%, 89.8%, 98.0%, respectively (P<0.05, compared with $^{18}F$-FDG PET/CT). The PPV and NPV were 89.8%, 87.6%, 85.6%, 97.2% and 85.6%, 93.2%, 92.8%, 98.6%, respectively. Three hundred and twelve lesions or segments were presented as lytic or sclerotic changes on CT images at the corresponding sites of increased $^{18}F$-FDG uptake. In lytic or mixed lesions, the sensitivity of $^{18}F$-FDG PET/CT and $^{18}F$-FDG PET were better than bone scintigraphy, while in osteoblastic lesions bone scintigraphy had a similar performance with $^{18}F$-FDG PET/CT but better than $^{18}F$-FDG PET alone. Conclusion: Our data allow the conclusion that $^{18}F$-FDG PET/CT is superior to planar bone scintigraphy, CT or $^{18}F$-FDG PET in detecting bone metastasis. $^{18}F$-FDG PET/CT may enhance our diagnosis of tumor bone metastasis and provide more information for cancer treatment.

F4-TCNQ를 이용한 유기 발광 소자의 전기적 특성 변화

  • Na, Su-Hwan;Kim, Tae-Wan;Jang, Gyeong-Uk;Han, Won-Geun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.166-167
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    • 2009
  • 본 연구에서는 2,3,5,6-fluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ)를 이용한 유기 발광 소자의 전기적 특성에 대하여 연구하였다. F4-TCNQ 는 높은 전자 친화도를 가지고 있어서 전하 수송층이나 전하 주입층에 많이 사용되고 있다. 또한 TCNQ 유도체들은 물질의 전도도를 조절하는 용도로 많이 이용된다. TCNQ 유도체를 유기 발광 소자의 전하 수송층이나 전하 주입층에 이용할 경우, 소자의 구동 전압이나 효율과 같은 특성들이 향상된다고 알려져 있다. 우리는 소자 특성에 있어서 F4-TCNQ의 영향을 알아보기 위해서 ITO(170nm)/TPD(40nm)/$Alq_3$(60nm)/LiF(0.5nm)/Al(100nm)의 구조로 기본 소자를 제작하였다. 그리고 TPD층에 F4-TCNQ를 도핑하여 소자를 제작하였다. 도핑 농도는 5와 10%로 하였다. 또한 ITO와 TPD층 사이에 F4-TCNQ층을 1, 2, 그리고 5nm의 두께로 하여 소자를 제작하였다. F4-TCNQ를 5와 10% 도핑한 소자의 구동 전압은 도핑하지 않은 소자에 비해 감소하였다. 그리고, ITO와 유기물층 사이에 F4-TCNQ층을 삽입한 소자의 특성은 삽입하지 않은 소자에 비해 향상되었다.

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Microwave Dielectric Properties of (1-X) ${Na}_{1/2}{Sm}_{1/2}TiO_3-X\;{Li}_{1/2}{Nd}_{1/2}TiO_3$ Ceramics ((1-X) ${Na}_{1/2}{Sm}_{1/2}TiO_3-X\;{Li}_{1/2}{Nd}_{1/2}TiO_3$ 세라믹스의 고주파 유전특성)

  • Yun, Jung-Rag;Hong, Suk-Kyung;Kim, Kyung-Yong
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1103-1105
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    • 1993
  • Microwave characteristics of the system (1-X) ${Na}_{1/2}{Sm}_{1/2}TiO_3$[NST]-X ${Li}_{1/2}{Nd}_{1/2}TiO_3$[LNT] were investigated. The dielectric constant and unloaded Q were 86,1950 respectively for NST at 3GHz and 80,500 for LNT. 0.4 NST - 0.6 LNT system has the dielectric constant ${\varepsilon}r$=86.2, Q=930(3GHz), temperature coefficient of the resonant frequency ${\tau}f$ = 8 ppm/$^{\circ}C$ when sintered at $1450^{\circ}C$ for 2h.

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Effect of Vinyl Ethylene Carbonate on Electrochemical Characteristics for Activated Carbon/Li4Ti5O12 Capacitors (활성탄/리튬티탄산화물 커패시터의 전기화학적 특성에 미치는 비닐에틸렌카보네이트의 영향)

  • Kwon, Yong-Kab;Choi, Ho-Suk;Lee, Joong-Kee
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.190-197
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    • 2012
  • We employed the vinyl ethylene carbonate (VEC) as an electrolyte additive and investigated the effect of the electrolyte additive on the electrochemical performance in hybrid capacitor. The activated carbon was adopted as cathode material, and the $Li_4Ti_5O_{12}$ oxide was used as anode material. The electrolyte was prepared with the $LiPF_6$ salt in the mixed solvent of ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate(EMC). We evaluated the electrochemical performance of the hybrid capacitor with increasing the amount of the VEC electrolyte additive, which is known as the remover of oxygen functional group and the stabilizer of the electrode by reducing the surface of electrode, and obtained the superior performance data especially at the addition of the VEC electrolyte additive of around 0.7 vol%. On the contrary, the addition of the VEC more than 0.7 vol% in the electrolyte leads to the degradation in electrochemical performance of hybrid capacitor, suggesting the increase of the side reaction from the excessive VEC additive. X-ray photoelectron spectroscopy (XPS) revealed that the addition of the VEC suppressed the formation of LiF component, which is known as the insulator, on the surface of electrode. The optimized addition of VEC exhibited the improved capacity retention around 82.7% whereas the bare capacitors without VEC additive showed the 43.2% of capacity retention after 2500 cycling test.

Recoverty of Lithium Carbonate and Nickel from Cathode Active Material LNO(Li2NiO2) of Precursor Process Byproducts (전구체 공정부산물 LNO(Li2NiO2)계 양극활물질로부터 탄산리튬 및 니켈 회수연구)

  • Pyo, Je-Jung;Wang, Jei-Pil
    • Resources Recycling
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    • v.28 no.4
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    • pp.30-36
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    • 2019
  • In this study, Li powder was recovered from the by-product of LNO ($Li_2NiO_2$) process, which is the positive electrode active material of waste lithium ion battery, through the $CO_2$ thermal reaction process. In the process of recovering Li powder, the $CO_2$ injection amount is 300 cc/min. The $Li_2NiO_2$ award was phase-separated into the $Li_2CO_3$ phase and the NiO phase by holding at $600^{\circ}C$ for 1 min. After this, the collected sample:distilled water = 1:50 weight ratio, and after leaching, the solution was subjected to vacuum filtration to recover $Li_2CO_3$ from the solution, and the NiO powder was recovered. In order to increase the purity of Ni, it was maintained in $H_2$ atmosphere for 3 hours to reduce NiO to Ni. Through the above-mentioned steps, the purity of Li was 2290 ppm and the recovery was 92.74% from the solution, and Ni was finally produced 90.1% purity, 92.6% recovery.

EFFECT OF $SiF_4$ADDITION ON THE STRUCTURES OF SILICON FILMS DEPOSITED AT LOW TEMPERATURE BY REMOTE PLASMA ENHANCED CHEMICAL VAPOR DEPOSITION

  • Xiaodong Li;Park, Young-Bae;Kim, Dong-Hwan;Rhee, Shi-Woo
    • Journal of the Korean Vacuum Society
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    • v.4 no.S2
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    • pp.64-68
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    • 1995
  • Silicon films were deposited at $430^{\circ}C$ by remote plasma chemical vapor deposition(RPECVD) with a gas mixture of $Si_2H_6/SiF_4/H_2$. The silicon films deposited without and with $SiF_4$ were characterized using atomic force microscopy(AFM), transmission electron microscopy(TEM) and X-ray diffraction(XRD). Both silicon films have the same rugged surface morphology, but, the silicon film deposited with $SiF_4$ exhibits more rugged. The silicon film deposited without $SiF_4$ is amorphous, whereas the silicon film deposited with $SiF_4$ is polycrystalline with very small needle-like grains which are perpendicular to the substrate and uniformly distributed in the thickness of the film. The silicon film deposited with $SiF_4$ was found to have a preferred orientation along the growth direction with the<110> of the film parallel to the <111> of the substrate. The effect of $SiF_4$ during RPECVD was discussed.

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