• Title/Summary/Keyword: 5VOC

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Development of Environmental-friendly Nontoxic Flame Retardant Paint (친환경 무독성 난연도료 개발연구)

  • Do, Young-Woong;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.9 no.5
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    • pp.1354-1358
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    • 2008
  • Environmental-friendly nontocxic flame retardant paint which can overcomes the restriction of harmful materials for human body and environments such as Pb, Hg, Cd, $C^{+6}$, PBB/PBDE by EU and domestic Ministry of Environment was developed. Developed paint is the water-soluble organic inorganic hybrid material that VOC(volatility organic compound) discharge is low, and that human riskiness and environmental pollution is minimized not using the kinds of halogen materials. $Mg(OH)_2$, $Sb_{2}O_{3}$, and Zinc borate were used as flame retardant materials, 2% Micell and water were used as binder and solvent, respectively. Results showed the optimum activity was obtained when the ratio of those frame retardant agents($Mg(OH)_2$, $Sb_{2}O_{3}$, Zinc borate made by 1: 2: 2), binder(2% Micell) and water was 1: 0.5: 0.5.

A Study on Toluene Removal of VOC and Characteristics of Material Using Biofilter (Bio필터를 이용한 VOC 가스 중 Toluene 제거율과 필터특성 연구)

  • 강신묵;하상안
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.88-94
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    • 1998
  • This study was investigated the application of biofiltration using cometabolic process to remediate gaseous toluene that are highly recalcitrant to adsorption, absorption and biodegradation. The investigation was conducted using specially built steel columns packed with granular activated carbon for removal of toluene and G.A.C was also coated with Pseudomonas putida microorganisms by addition of KH$_{2}$PO$_{4}$. The biofilter unit was operated in the condition of dry and 27.5% moisture content at gas loading rate of 12.5 l/min. Gaseous toluene taken from tedlar bag was analyzed by the use of G.C. equipped with F.I.D. detector. The removal efficiency of gaseous toluene was 85% at average inlet concentration of 970 ppm during dry operating condition. For gaseous toluene, 91% removal efficient was obtained at the filter material with moisture content and 97% removal efficiency was obtained with Pseudomonas putida microorganisms at gas loading rate of 12.5 l/min.

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VOCs impact factor analysis of unit components in Part assembly by ISO 12219-5 method (ISO 12219-5 (Static chamber법)를 이용한 모듈내 구성부품별 VOCs 영향도 분석)

  • Lee, Shinjong;Jang, Heyjin;Gwak, Donghwan;Kim, Man-Goo
    • Analytical Science and Technology
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    • v.27 no.6
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    • pp.284-291
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    • 2014
  • The handling process of car indoor air quality is composed of 2 steps of testing. First, assambly part is tested to find a source of car indoor VOCs. Second, cut sample of unit component is tested to find a source material of VOCs emission. If the source material of VOCs emission is found, it can reduce car and assembly part of VOCs by improving material. As cut sample testing has problem of emission from cut surface to find the source of VOCs, it needs to apply unit components testing method. The aim of study is to evaluate VOCs impact factor of unit components in assembly parts. ISO 12219-5 test method reflects not only material effect but also surface area effect by testing unit component without cutting. The unit components of doortrim and console, were tested by ISO12219-5. And it could figure what unit component is main source of VOCs in assembly. And quantity conversion Factor which gets by testing assembly and unit components can be used to make guideline of ISO 12219-5.

Characteristics of Environment-friendly Waterborne Coating Agent Applied to Inorganic Adsorbent (무기흡착제가 적용된 친환경 수성 코팅제의 특성 연구)

  • Shin, Jong-Sub;Lee, Jung-Hee;Kwak, Eun-Mi;Yun, Jong-Kuk;Kim, Hyun-Bum
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.622-627
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    • 2012
  • This study focuses on mechanical property enhancement and volatile organic compounds (VOCs) reduction characteristic of environmentally-friendly waterborne coatings. We synthesized a series of organic-inorganic hybrid waterborne polyurethanes by using poly(tetramethylene glycol) 2000, polycarbonate diol 2000, isophorone diisocyanate, dimethylolpropionic acid and titanium dioxide. The study on the effects of the R ratio([NCO]/[OH]) and inorganic contents on environmentally-friendly waterborne coatings showed that the R ratio with more than 1.5 is appropriate due to arrangement of hardsegments. The applied $TiO_2$ on films reduced volatile organic compounds (VOCs).

Analysis of Photochemical Ozone Formation Regime in Busan - Comparative Study on Busan vs. Seoul Metropolitan Area(Ⅳ) (부산지역 광화학 오존 생성 regime 분석 - 수도권과 비교연구 (Ⅳ))

  • Seung-Hee Baek;Hyo-Jung Lee;Cheol-Hee Kim
    • Journal of Environmental Science International
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    • v.32 no.5
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    • pp.285-301
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    • 2023
  • This study analyzed characteristics of ozone (O3) formation regimes in Busan over a period of recent five years (2015~2019) and compared the findings with those obtained in Seoul. We employed four observed variations: early morning commuting-hour (i.e., 06:00-09:00 LST) nitrogen dioxide (NO2), peak-hour (i.e., 12:00-16:00 LST) O3, 8-hour average O3 (MDA8 O3), and △O3 (=O3_max- O3_min) in Busan and Seoul. In addition, the NO2-O3 relation was assessed to interpret which of NOx-limited or volatile organic compound (VOC)-limited was dominant. In Busan, the annual mean O3 concentration was relatively higher than in Seoul, whereas there were fewer high-concentration days. The Pearson correlation coefficients (R) between Early morning-hour NO2 and the Peak-hour O3 was positive (but close to zero) in Busan and negative in Seoul. Likewise, the R between the Early morning-hour NO2 and the △O3 showed a relatively considerable positive correlation (R=+0.4~0.5)(R=+0.4~0.5) in Busan, while a weak positive correlation (R=+0.1~0.2) in Seoul. From this result, it can be inferred that the O3 formation regime in Busan was intrepreted to be nearly neutral or relatively closer to the NOx-limited regime than Seoul, while Seoul to the VOC-limited regime. The study findings imply that O3 control strategies should be applied differently in Busan and Seoul. The results here were inferred from surface NO2 and O3 observations, and the varification studies based on in-situ VOCs measurements would be needed.

Estimation of Chemical Speciation and Temporal Allocation Factor of VOC and PM2.5 for the Weather-Air Quality Modeling in the Seoul Metropolitan Area (수도권 지역에서 기상-대기질 모델링을 위한 VOC와 PM2.5의 화학종 분류 및 시간분배계수 산정)

  • Moon, Yun Seob
    • Journal of the Korean earth science society
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    • v.36 no.1
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    • pp.36-50
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    • 2015
  • The purpose of this study is to assign emission source profiles of volatile organic compounds (VOCs) and particulate matters (PMs) for chemical speciation, and to correct the temporal allocation factor and the chemical speciation of source profiles according to the source classification code within the sparse matrix operator kernel emission system (SMOKE) in the Seoul metropolitan area. The chemical speciation from the source profiles of VOCs such as gasoline, diesel vapor, coating, dry cleaning and LPG include 12 and 34 species for the carbon bond IV (CBIV) chemical mechanism and the statewide air pollution research center 99 (SAPRC99) chemical mechanism, respectively. Also, the chemical speciation of PM2.5 such as soil, road dust, gasoline and diesel vehicles, industrial source, municipal incinerator, coal fired, power plant, biomass burning and marine was allocated to 5 species of fine PM, organic carbon, elementary carbon, $NO_3{^-}$, and $SO_4{^2-}$. In addition, temporal profiles for point and line sources were obtained by using the stack telemetry system (TMS) and hourly traffic flows in the Seoul metropolitan area for 2007. In particular, the temporal allocation factor for the ozone modeling at point sources was estimated based on $NO_X$ emission inventories of the stack TMS data.

Comparison of Sampling and Analysis Methods for Volatile Organic Compounds in Ambient Air (대기중 휘발성 유기화합물의 채취 및 분석 방법 비교)

  • 나광삼;김용표
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.5
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    • pp.507-518
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    • 1998
  • A field comparison study was carried out to quantify differences among various sampling and analytical methods for volatile organic compounds (VOCs) at a site in Vlsan in June 1997. Air sampling containers (SUMMA canisters) were used by the Korea Institute of Science and Technology (KIST) and adsorption tubes (carbotrap) were used by Yeungnam University (YN Univ.) for sampling ambient air. Duplicate samples obtained by KIST were analyzed by KIST with a GC-MS system for aromatics and halogenated hydrocarbons and by Atm AA with a GC -FID system for C2∼C9 hydrocarbons, respectively. The adsorption tube samples were analyzed by YN Univ. with a GC-FID system for aromatics. VOC levels for the duplicate canister sampls analyzed by KIST and Atm AA were in good agreement. Concentrations of aromatics by the adsroption tube method were generally higher than those by the canister sampling method by factor of 1.5 to 2.0. Differences between the two sampling methods were discussed.

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박막태양전지 TCO/P 버퍼층 활성화를 위한 P-layer 최적화 Simulation

  • Jang, Ju-Yeon;Baek, Seung-Sin;Kim, Hyeon-Yeop;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.91-91
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    • 2011
  • 박막태양전지의 높은 효율개선을 위해 TCO층과 p-layer 사이에 buffer layer를 넣어 Voc와 FF를 개선하는 연구가 진행되고 있다. 이에 buffer layer의 활성화 정도를 높이기 위해 p-layer을 최적화 시키고자한다. 이 실험에서 a-Si:B에 N2O를 도핑시켜 Bandgap Energy 2.0 eV, Activation Energy 0.4 eV인 a-SiOx:B 막을 제작하여 buffer layer로 사용하였고 이 buffer layer에 의한 cell의 효율 향상을 최적화 하기위해 ASA simulation을 이용해 p-layer의 Bandgap Energy와 Activation Energy를 가변 하여 보았다. 실험결과 p-layer의 Bandgap Energy 1.95 eV에서 buffer layer와 p-layer사이에서의 barrier가 최소가 됨을 확인 할 수 있었고 Actication Energy 0.5 eV에서 가장 높은 Voc를 가짐을 알 수 있었다. 본 연구를 통해 p-layer의 Bandgap Energy 1.95 eV, Activation Energy 0.5 eV에서 buffer layer를 활성화시키기 위한 p-layer의 최적화 조건을 구현해 볼 수 있었다.

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