Comparison of Sampling and Analysis Methods for Volatile Organic Compounds in Ambient Air

대기중 휘발성 유기화합물의 채취 및 분석 방법 비교

  • 나광삼 (한국과학기술연구원 지구환경연구센터) ;
  • 김용표 (국과학기술연구원 지구환경연구센터, 국과학기술연구원 지구환경연구센터, 영남대학교 환경공학과, 영남대학교 환경공학과, 영남대학교 환경공학과, 미국 AtmAA.,Inc., 한국과학기술연구원 특성분석센터, 한국과학기술연구원 특성분석센터)
  • Published : 1998.10.01

Abstract

A field comparison study was carried out to quantify differences among various sampling and analytical methods for volatile organic compounds (VOCs) at a site in Vlsan in June 1997. Air sampling containers (SUMMA canisters) were used by the Korea Institute of Science and Technology (KIST) and adsorption tubes (carbotrap) were used by Yeungnam University (YN Univ.) for sampling ambient air. Duplicate samples obtained by KIST were analyzed by KIST with a GC-MS system for aromatics and halogenated hydrocarbons and by Atm AA with a GC -FID system for C2∼C9 hydrocarbons, respectively. The adsorption tube samples were analyzed by YN Univ. with a GC-FID system for aromatics. VOC levels for the duplicate canister sampls analyzed by KIST and Atm AA were in good agreement. Concentrations of aromatics by the adsroption tube method were generally higher than those by the canister sampling method by factor of 1.5 to 2.0. Differences between the two sampling methods were discussed.

Keywords

References

  1. 한국대기보전학회지 흡착포집 및 열탈착 GC 분석에 의한 공기중의 VOC 측정방법론 평가 백성옥;황승만;박상곤;허규석;전선주;김병주
  2. 대기오염, 소음, 진동 공정시험방법(환경부 고시 제91-73호, 제91-49호) 환경부
  3. Envirorn. Sci. Tec-hnol. v.30 Viability of using SUMMA polished canisters for the collection and storage of parts per billion by volume level volitile organics Brymer, D.;L.D. Ogle;C.J. Johnes;D.L. Lewis
  4. J. Air. Waste Manage Assoc. v.42 Measurements of VOCs from the TAMS Network Evans, G.F.;T.A. Lumpkin;D.L. Smith;M.C. Somervile
  5. Chromatographia v.23 Advances in the determina-tion of volatile organic solvent and other pollutants Fabri, A.;G. Crescentini;F. Mangani;A.R. Mastriogiacomo;F. Bruner
  6. Personal comuication Fung, K.
  7. Anal. Chem. v.62 Eva-luation of aluminum canisters for the collection and store of air toxics Gholson, A.R.;R.K.M. Jayanty;J.F. Storm
  8. Atmos. Environ. v.20 Sampling integrity of trace level volatile organic compounds in ambient air stored in SUMMA polished canis-ters Oliver, K.D.;J.D. Pleil;W.A. McClenny
  9. Atmos. Environ. v.25B Com-parison of Tenax and Carbotrap for sampling and anaylsis of volatile organic compounds in air Rothweiler, H.;P.A. Wager;C. Schlatter
  10. Compendium of Methods for the Deter-mination of Toxic Organic Compounds in Ambient Air US EPA
  11. Identifi-cation and Analysis of Organic Pollutants in Air Analysis of individual hydrocarbon species in ambient atmosphers :Techniques and data validity Westberg H.;W. Lonneman;M. Holdren;Keith L.H.(ed.)
  12. Atmos. Environ. v.30 Volatile organic compounds up to ${C-20}$ emitted from motor vehicles : measure-ment methods Zielinska, B.;J.C. Sagebiel;G. Harshfield;A.W. Gertler;W.R. Pierson