• Journal of the Korean Wood Science and Technology
• /
• v.45 no.5
• /
• pp.580-587
• /
• 2017

Woodfiber insulation board can be considered as a one of the key material for low energy consumption, comfortable and safety construction of residential space because of its eco-friendly and high thermal insulation performance. This study was carried out to investigate the formaldehyde (HCHO) total volatile organic compounds (TVOC) emission properties and combustion shapes by flame test of low density fiberboards (LDFs) prepared with different adhesives. HCHO TVOC emission and combustion properties of LDFs prepared by melamine urea formaldehyde (MUF), phenol formaldehyde (PF), emulsified methylene diphenyl diisocyanate (eMDI) and latex resin adhesives were measured by desiccator method, 20 L chamber method, and flame test, respectively. As results, LDFs manufactured by MUF, eMDI and latex resin adhesives satisfied the Super $E_0$ grade of HCHO emission performance except PF resin. Furthermore, TVOC emission of all LDFs were satisfied the Korean indoor air quality standard (below $400{\mu}g/m^2{\cdot}h$). Especially, LDF with eMDI resin adhesive showed the lowest HCHO and TVOC emissivity, that $0.14mg/{\ell}$, $12{\mu}g/m^2{\cdot}h$, respectively. However, eMDI emitted the small amount ($3{\mu}g/m^2{\cdot}h$) of toluene in VOC components. In the flame test, LDF with MUF resin adhesives showed the most favorable shape after flame test compare to LDFs prepared other adhesives. Based on HCHO and TVOC emission, and combustion shapes, MUF resin adhesive may be recommended to prepare LDF for insulation purpose.

• Journal of Wetlands Research
• /
• v.16 no.2
• /
• pp.281-291
• /
• 2014

In March to August 2013, the emission of gases ($CH_4$, VOC, $CO_2$, $O_2$, and LEL) was measured three times from the intertidal flat sediments at Sogeun-ri, Taean-gun, in the Mid-western seashore of Korea by using chamber method. After analyzing gas emission concentrations inside of flux enclosure chamber by using a GC equipped with Agilent 6890. The gas emission fluxes were calculated from a linear regression of the changes in the concentrations with time. The ranges of gas flux during the experimental period were $+0.06{\sim}+0.60mg/m^2/hr$ for $CH_4$, $+58.45{\sim}+95.58mg/m^2/hr$ for $CO_2$, $-0.02{\sim}-0.20mg/m^2/hr$ for $O_2$, and $-0.60{\sim}+0.65mg/m^2/hr$ for VOC, respectively. The flux measurement results revealed that $CH_4$ fluxes during March in the relatively low sediment temperature ($14.5^{\circ}C$) were significantly higher ($+0.60mg/m^2/hr$) than during June and August ($+0.06{\sim}+0.18mg/m^2/hr$) in high sediment temperature ($32.0{\sim}36.8^{\circ}C$). $CH_4$ flux to mean size of sediments and temperature of inner chamber exhibited strong positive correlation ($R^2=-0.97$ and $R^2=-0.89$, respectively).

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.08a
• /
• pp.395-396
• /
• 2011

본 논문에서는 30% 내외의 평균반사율을 가지는 다결정 실리콘 태양전지의 입사광 손실을 최소화하여 광전변환효율 극대화를 구현하기 위해서 SF6/O2 혼합가스를 이용한 RIE 표면 texturing 공정을 수행하였다. 현재 다결정 실리콘 태양전지는 다양한 방향의 grain을 가지기 때문에 단결정 실리콘에 적용되는 습식 식각 방식이 다결정 실리콘 표면 texturing에 적절하지 않은 것으로 알려져 있다. 이를 개선하기 위해서 이방성 식각 특성을 가지는 다양한 texturing 방법이 시도되고 있다. 대표적으로 기계적인 방식의 V-grooving, 레이저 grooving, 플라즈마 건식식각을 이용한 texturing 및 산 용액을 이용한 texturing 등의 연구가 보고되고 있다. 그 중에서 플라즈마 건식식각 방식의 하나인 RIE를 이용한 표면 texturing 공정이 간단한 공정과 산업계 응용의 용이성 때문에 활발히 연구되어 왔다. 특히 Sandia group과 일본 Kyocera사의 연구 결과에서는 그 가능성을 입증하고 있다. 본 연구에서는 공정의 단순화와 안전한 공정을 위해서 SF6/O2 혼합 가스를 이용하여 마스크 패턴 공정없이 RIE texturing 공정을 수행하였으며, RIE-textured 다결정 실리콘에 대해서 태양전지를 제작하여 표면 texturing이 광전변환효율에 미치는 영향에 대해서 분석하였다. 그 결과 SF6/O2 혼합 가스를 이용한 RIE texturing은 다결정 실리콘 표면에 주로 needle 구조를 형성하는 것을 확인하였다. 각 texturing 조건별 반사율의 차이는 needle 구조의 조밀도와 관련되는 것을 알 수 있었으며, 동일 공정 parameter 상에서 식각 시간 1, 2, 3, 4, 5분 기준 시간에 따른 표면 구조 분석 결과 seed 가 형성되고 그에 따라서 needle 형태로 식각되는 과정을 관찰하였다. 반사율은 분당 약 4%씩 낮아져 5분 식각 후 14.45% 까지 낮아졌으며, 표면 구조에서 폭은 약 30 nm로 모두 일정하며, 길이가 약 20, 30, 50, 80, 100 nm으로 증가되었다. 이 결과로 보아 seed로부터 needle 구조가 심화되어가는 것을 알 수 있었다. 시간에 따른 RIE texturing 후 제작된 태양전지는 효율이 1분 식각 기준 15.92%에서 약 0.35% 씩 낮아져 5분 식각 후 14.4%로 낮아졌다. Voc 는 texturing 시간에 관계없이 일정하며 Isc가 점점 감소되는 것으로 확인되었다. EQE 결과도 이와 동일하게 RIE texturing 시간이 길어질수록 전체 파장 범위에서 일정하게 낮아지는 것이 관찰되었다. Electroluminescence(EL) 이미지 결과 texturing 시간이 길어진 태양전지일수록 점점 어두운 이미지가 나타나 5분 식각의 경우 가장 어두운 결과를 나타내었다. 이런 결과는 한 가지 이유보다는 복합적인 문제로 예상되는데 궁극적으로는 RIE 공정 후 표면에 쌓인 charged particle들이 trap 준위를 형성하여 효율 및 공정상에 영향을 미친 것으로 보이며, 특히 잔류 O기가 불균일한 산화막을 형성하는 것으로 예상된다. 또한 EL 분석 결과를 볼 때 RIE texturing 공정이 길어질수록 불안정한 pn-junction을 형성하는 것을 확인하였으며, emitter 층 형성 후 PSG (phosphorous silica glass) 공정에서 needle의 상부 구조가 무너지면서 면저항이 증가된 결과로 분석된다. PSG 제거 후 측정된 면저항의 경우 3분 texturing 샘플부터 면저항이 약 4${\Omega}/sq$ 정도 증가됨을 확인하였다.

• Journal of the Korean Chemical Society
• /
• v.64 no.6
• /
• pp.327-333
• /
• 2020

Performance of a portable GC that can be utilized for the real time determination of volatile organic compounds in air was evaluated. It employs purified/compressed ambient air as the carrier gas eliminating the need for high pressure gas tanks. The compact system with dimensions of 35 × 26 × 15 ㎤ and weight of 5 kg is powered by either a 24 V DC external adapter or battery pack. Chromatograms of the mixture sample including benzene, toluene, ethylbenzene, and oxylene at concentrations of 1 ppmv and 20 ppmv represent a good reproducibility: 3.79% and 0.48% relative standard deviations (RSDs) for peak area variations; 0.40% and 0.08% RSDs for retention times. The method detection limit was 0.09 ppmv. A 30 m long, 0.28 mm I.D. column operated at an optimal condition yielded a peak capacity of 61 with good resolution for a 10 min isothermal analysis. The relative standard deviations (RSD) of the peak area variations and retention times during consecutive measurements over 27 h were less than 2.4%RSD and 0.5%RSD, respectively. Thus, this instrument makes it suitable for continuous and field analysis of low-concentration VOC mixtures in the indoor/outdoor environment as well as the spillage accident of hazardous chemicals.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.14 no.12
• /
• pp.6610-6617
• /
• 2013

This study examined the current and future Indoor Air Quality (IAQ) control device markets and analyzed the recent studies on indoor air pollutantr emoval to develop a new technology for fine dust control. Currently, the mechanical filter technique occupies the bulk of the IAQ control market but the electronic technique is emerging as an alternative to control fine dust efficiently. Among the gaseous VOCs and fine dust particles contaminating the indoor air quality, fine dust particles are more problematic because they threaten human health by penetrating deep into the body and producing secondary contaminants by chemical reaction with VOCs. The electronic IAQ control device using dielectrophoretic and electrostatic forces is a good option for public spaces where many people pass, and at the same time, it needs to consider temperature, humidity, and the particle properties of specific areas to highlight the control efficiency. Electronic-related technology is expected to be used widely in many public/private spaces wherever a dust-free environment is required.

• Analytical Science and Technology
• /
• v.23 no.2
• /
• pp.109-118
• /
• 2010

Amended at the Law of indoor air quality management open a court according to the test method and excess standard of the fluid building material were changed. It used the paint and the putty in the fluid building material from this research and comparison of amended and original method it led and in about change direction of amended standard with change of the emission rate who is caused by in the amended test method and excess standard it examined. The reduction emission rate about 45% decreases in the change of test period of the paint, there was not an effect of the emission rate whom it follows in change of dry time. Also change of the emission rate whom it follows in change of application quantity the product which above $5\;mg/m^2h$ has the high emission rate the change of the emission rate is big but there was not change of the emission rate from the products of that others. The putty the emission rate about 61% decreases in case in the change of test period, there was not an effect of the emission rate whom it follows at dry time. The emission rate about 164% increased with increase of application quantity. It tried to compare two test methods, it compared in the paint and putty all current test method it was relaxed the possibility of knowing the thing there was a standard.

• Journal of Korean Society of Environmental Engineers
• /
• v.27 no.5
• /
• pp.468-475
• /
• 2005

Biofilters packed with various materials have emerged as a sustainable technology for the treatment of volatile organic compounds (VOCs); however, problems including low performance and clogging are commonly encountered. Recently, a bioactive foam reactor (BFR) using surfactants has been suggested to ensure efficient and stable VOCs removal performance. This study was mainly conducted to investigate the feasibility of BFRs using toluene as a model compound. Prior to bioreactor studies, a series of bottle tests were used to select a suitable surfactant for the BFR application. Experimental results of the batch bottle tests indicated that TritonX-100 was the most appropriate one among the surfactants tested, since it showed a minimal effect on the toluene biodegradation rate while the other surfactants lowered the toluene biodegradation rate significantly. Using the selected surfactant, the BFR performance was determined by changing operating parameters including gas residence time and toluene loading. As the gas residence time increased from 0.5 minutes to 2 minutes, the toluene removal efficiency increased from approximately 50% to 80%. In addition, an increase of the toluene loading from $38\;g/m^3/hr$ to $454\;g/m^3/hr$ resulted in a decrease of toluene removal efficiency from approximately 70% to 20%. The BFR had a maximum elimination capacity of $108\;g/m^3/hr$ for toluene, which was much higher than those generally reported in the literature. The high toluene-elimination performance indicates that the BFR be a potential alternative to the conventional, packed-type biofilters. However, the limitation of toluene solubilization and foam stability at either high or low gas flow rate are still problems to be challenged.

• Journal of Korean Society of Environmental Engineers
• /
• v.32 no.2
• /
• pp.209-218
• /
• 2010

The fifty six components of volatile organic compounds(VOCs) were continuously measured by the hour to see the distributions their of its concentration and the ozone creating contribution of nitric oxides and VOCs in Gamjeon Odor and VOCs Monitoring Network from April to September, 2008. Aromatics occupied 51.3% of VOCs and paraffins, alkanes and olefins came in order. The monthly concentration of VOCs in Gamjeon was high in July and low in September. As for hourly concentration of ozone and nitric oxides, ozone started to increase since 10am having the highest in the daytime, and nitric oxides had the different trend from that of ozone, showing the lowest in the daytime. The photochemical ozone creating potentials(POCPs) of toluene, propane, m/p-xylene, ethylbenzene, and 1,2,4-trimethylbenzene were 30.6%, 10.2%, 9.4%, 7.4% and 5.2% respectively. These five components occupied 62.8% of total POCPs, which means they contributed to the ozone creation mainly. Related with the ozone creating contribution, the ratio of VOCs to NOx was generally under 6 occupied 72.0%, which came under the area coexisting the limit of VOCs. Therefore it is thought that the management of emission source of VOCs is very important for the reduction of ozone.

• Journal of Korean Society of Occupational and Environmental Hygiene
• /
• v.25 no.1
• /
• pp.104-114
• /
• 2015

Objectives: The purpose of this study is to investigate the atmospheric concentration of VOCs and the urinary concentration of t,t-MA, HA, MA in the industrial complex of Yeosu, South Jeolla Province. Methods: In order to study seasonal patterns of air concentration of VOCs, measurements were taken at five sampling sites around Yeosu from June 2013 to June 2014. Urinary metabolite excretionsfrom 671 subjects, exposure and comparison area were analyzed. Results: The average concentration of VOCs in the air was 1.53ppb for benzene, 0.73ppb for toluene, 0.22ppb for ethylbenzene, 0.52ppb for xylene and 0.12ppb for styrene. The concentration of benzene was somewhat higher than the year-average standard ($5{\mu}g/m^3$, about 1.5ppb) of the domestic air-environment criteria newly established in 2010.The metabolic concentration of VOCs in the urine of the entire sample was analyzed at $47.76{\mu}g/g\;cr.$, 213.07mg/g cr., and $290.09{\mu}g/g\;cr.$ for t,t-MA, HA, and MA, respectively. Compared with the average values for Korea as presented in the first basic survey of national environmental conservation ( $49.8{\mu}g/g\;cr.$ for t,t-MA, 0.17g/g cr. for HA, and 0.26mg/g cr. for MA), the metabolic concentrations of HA and MA in urine were higher than the average values. Conclusions: The concentration of VOCs in the air and urinary metabolites of the exposed and control areas showed that the concentrations of all substances were higher in the exposed area than in the control area.

• Economic and Environmental Geology
• /
• v.37 no.6 s.169
• /
• pp.613-629
• /
• 2004

Contamination of groundwater by volatile organic compounds (VOCs) was investigated for 168 groundwater wells in Ulsan area to study the natural attenuation of organic compounds in the aquifers. As groundwater contamination by VOCs is closely related to land use, 168 groundwater samples were classified into 4 different groups; agricultural, forestry, industrial, and residential & business. From analysis 65 out of 168 groundwater samples contained more than one VOC. Analysis of samples were performed fir 36 halogenated aliphatic hydrocarbons and 25 petroleum hydrocarbons set up by NAWQA of US geological survey. Twelve petroleum hydrocarbons were detected in 26 groundwater wells, but their concentrations were less than 1.5 g/L except for MTBE. Twenty three chlorinated aliphatic hydrocarbons, composed of 11 methanes, 6 ethanes and 6 ethenes, were detected in 63 groundwater samples. The range of methanes concentration was $ND\~330\;/gL,\;ethanes\;ND\~84\;gL$, and PCE and their derivatives $ND\~62\;g/L$. As the study area was comprised of the aerobic/denitrification zones and $Fe^{+3}$ redox condition, most of petroleum hydrocarbons were degraded well, while halogenated hydrocarbons were slowly biodegradation.