• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1360-1363
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• 2006

A borate compound was adopted as new host material for $EU^{3+}$ activator. The $Eu^{3+}-doped\;YCa_3(GaO)_3(BO_3)_4$ (YCGB) phosphors were successfully synthesized. Also, their photoluminescence properties under the excitation of UV ray were measured. In the XRD patterns of the synthesized powders, most peaks were well-matched to a gaudefroyite phase. The emission of $Eu^{3+}$ in YCGB consists of a strong peak centered at 622 nm, which is attributed to $^5D_O-^7F_2$ transition of $Eu^{3+}$ and several weak peaks at near the wavelength. Optimum $Eu^{3+}$ concentration of the red phosphor under the excitation with the wavelength of 395 nm was about 75 mol%. This indicates that the red phosphor has a relatively higher critical concentration than that of the other $Eu^{3+}-doped$ phosphors. The dominant interaction character of $Eu^{3+}$ might be dipole-dipole interaction.

• 한국레이저가공학회지
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• 제17권4호
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• pp.7-13
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• 2014

In this work, the application of laser induced breakdown spectroscopy (LIBS) for the composition analysis of thin $Cu(In,Ga)Se_2$ (CIGS) solar cell films ($1-2{\mu}m$ thickness) is reported. For the ablation of CIGS films, femtosecond (fs) laser (wavelength = 343nm, pulse width = 500fs) and nanosecond (ns) laser (wavelength = 266nm, pulse width = 5ns) were used under atmospheric environment. The emission spectra were detected with an intensified charge coupled device (ICCD) spectrometer and multichannel CCD spectrometer for fs-LIBS and ns-LIBS, respectively. The calibration curves for fs-LIBS and ns-LIBS intensity ratios of Ga/Cu, In/Cu, and Ga/In were generated with respect to the concentration ratios measured by inductively coupled plasma optical emission spectrometry (ICP-OES).

• 반도체디스플레이기술학회지
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• 제19권2호
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• pp.22-25
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• 2020

Deep red EuSi₂O₂N₂ phosphors were synthesized under various sintering gas pressures (1 atm, 2 atm, and 3 atm). They were in good agreement with the standard EuSi₂O₂N₂ ICSD card # 41-6046 (a monoclinic crystal system with space group of P2₁/a). Their photoluminescence intensities were significantly increased with increasing the gas pressures. They showed a broad band emission peaking at 680 nm due to 4f⁶5d¹ - 4f⁷ of Eu²⁺ ion, which can be efficiently excited in the visible range up to 550 nm. The best one at 3 atm was applied for red LED based on blue chip, which showed the strong deep red emission.

• 한국결정성장학회지
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• 제33권1호
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• pp.1-16
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• 2023

LED용 비희토류 기반 strontium-aluminate 계 적색 발광 형광체를 고상반응법으로 합성하였고, 합성온도 및 Mn⁴⁺ 활성제 첨가량이 형광체의 발광특성에 미치는 영향에 대하여 조사하였다. 합성된 SrAl₂O₄:Mn⁴⁺ 형광체는 330 및 460 nm 근처 파장에서 피크가 나타나는 근자외선 및 청색 영역의 광대역 흡광 특성과 644, 658, 및 673 nm 근처의 세 개의 피크로 이루어진 삼중밴드 형태의 deep red 발광 특성을 나타내었다. 합성온도 1600℃, 0.5 mol% Mn⁴⁺ 이온 첨가량에서 합성된 SrAl₂O₄:Mn⁴⁺ 형광체가 가장 우수한 발광 특성을 나타내었고, 0.7 mol% 이상의 첨가량에서는 농도소광이 관찰되었다. FE-SEM 및 DLS 입도크기분포 분석 결과 합성된 SrAl₂O₄:Mn⁴⁺ 형광체 2~6.4 ㎛의 입도 분포 및 불규칙한 구형을 나타내며 약 4 ㎛의 평균 입자 크기를 갖는 것으로 조사되었다.

• Current Optics and Photonics
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• 제5권2호
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• pp.186-190
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• 2021

In this study, a compact, picosecond, mid-infrared 3.8 ㎛ MgO:PPLN optical parametric oscillator (OPO) laser output with high peak power is realized using a master oscillator power amplifier (MOPA) 1 ㎛ solid-state laser seeded by a picosecond fiber laser as the pump source. The pump source was a 50 MHz and 10 ps fiber seed source. After AOM pulse selection and two-stage solid-state amplification, a 1,064 nm laser output with a repetition frequency of 1-2 MHz, pulse width of 9.5 ps, and a maximum average power of 20 W was achieved. Furthermore, a compact short cavity with a unsynchronized pump is adopted through the design of an OPO cavity structure. When the injection pump power was 15 W and the repetition frequency was 1 MHz, the average output power of idler light was 1.19 W, and the corresponding peak power was 119 kW. The optical conversion efficiency was 7.93%. When the repetition frequency was increased to 2 MHz, the average output power of idler light was 1.63 W, the corresponding peak power was 81.5 kW, and the optical conversion efficiency was 10.87%. At the same time, the output wavelength was measured at 3,806 nm, and the beam quality was MX2 = 3.21 and MY2 = 3.34.

• 한국전기전자재료학회논문지
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• 제24권10호
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• pp.839-843
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• 2011

ZnO nanostructures were developed on a Si (100) substrate from powder mixture of ZnO and 5 mol% Pd (ZP-5) as reactants by ${\times}$ sccm oxygen pressures(x= 0, 10, 20, 40). DTA (differential thermal analysis) result shows the Pd(5 mol%)+ZnO mixtured powder(PZ-5) is easily evaporated than pure ZnO powder. The PZ-5 mixtured powder was characterized by DTA to determine the thermal decomposition which was found to be at $800^{\circ}C$, $1,100^{\circ}C$. Weight loss(%) and ICP (inductively coupled plasma) analysis reveal that Zn vaporization is decreased by increased oxygen pressures from the PZ-5 at $1,100^{\circ}C$ for 30 mins. Needle-like ZnO nanostructures array developed from 10 sccm oxygen pressure, was well aligned vertically on the Si substrate at $1,100^{\circ}C$ for 30 mins. The lengths of the Needle-like ZnO nanostructures is about 2 ${\mu}m$ with diameters of about 65 nm. The developed ZnO nanostructures exhibited growth direction along [001] with defect-free high crystallinity. It is considered that Zn vaporization is responsible for the growth of Needle-like ZnO nanostructures by controlling the oxygen pressures. The photoluminescence spectra of ZnO nanostructures exhibited stronger 376.7 nm NBE (near band-edge emission) peak and 529.3 nm DLE (deep level energy) peak.

• 한국대기환경학회지
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• 제29권1호
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• pp.10-26
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• 2013

To understand the traffic emissions with high temporal and spatial resolutions on road, a mobile laboratory was developed. The objective of this study is to characterize on-road air pollution on Naebu express way surrounding the northern area of Seoul, Korea. We measured the number concentration of ultrafine particles larger than 5 nm and particle size distribution using a condensation particle counter and a fast mobility particle sizer, respectively on 3, 7, and 8 December 2009. The average ultrafine particle number concentration on the Naebu express way excluding tunnels was 126,000 particles/$cm^3$ and 4.2 times higher than that on internal road at Korea Institute of Science and Technology in Seoul, and more than twice higher than that measured on and at the arterial roads of Seoul in previous studies. The maximum ultrafine particle number concentration was observed at the tunnel sections. It was 232,000 particles/$cm^3$ and 1.8 times higher than average ultrafine particle number concentration for the other sections on Naebu express way. The ultrafine particle number concentration on the wider roads with higher traffic volume along the Han River was similar to that in the residential section, probably because of enhanced dilution effect in widely open environment. The size distribution of particles on the Naebu express way was highly fluctuated for a short duration. Ultrafine particles measured at the tunnel showed a bimodal size distribution with mode diameters of ~10 nm and ~50 nm. At the Han riverside section, ~10 nm particles appeared significantly compared with size distribution at the tunnel. This on-road measurement approach can be utilized to manage vehicle-related air pollution in urban area.

• Food Science and Biotechnology
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• 제18권4호
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• pp.954-958
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• 2009

Effects of controlled- and uncontrolled-pH operations on phenylalanine ammonia lyase (PAL) production by a recombinant Escherichia coli strain were investigated at uncontrolled-pH ($pH_{UC}$) and controlled-pH ($pH_C$) of 5.5, 6.0, 6.5, 7.0, 7.5, 8.0, and 8.5 in bioreactor systems. The results showed that the recombinant PAL activity was improved significantly by controlled pH strategy. Among the $pH_C$ operations, the highest PAL activities were obtained under $pH_C$ 7.5 strategy where cell mass ($OD_{600\;nm}$) and PAL activity was 1.3 and 1.8 fold higher than those of $pH_{UC}$, respectively. The maximum PAL activity reached 123 U/g. The $pH_C$ 7.5 strategy made recombinant plasmid more stable and therefore allowed easier expression of PAL recombinant plasmid, which increased PAL production. It was indicated that the new approach (controlled-pH strategy) obtained in this work possessed a high potential for the industrial production of PAL, especially in the biosynthesis of L-phenylalanine.

• 분석과학
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• 제12권4호
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• pp.326-331
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• 1999

방향족 탄화수소인 trimethylbenzene (TMB)은 그 사용량이 늘어갈 뿐 아니라 직업적으로 폭로되는 양도 증가하고 있으므로 생물학적 모니터링 및 흡수, 대사, 배설에 관한 연구가 중요시되고 있다. 일반적으로 TMB는 간의 산화효소에 의해 하나의 메틸기가 산화되고 이것이 glycine과 포합되어 배설되는 것으로 알려져 있다. 본 연구에서는 1,2,4-TMB의 대사체를 합성하고, 모세관 전기영동법으로 분석할 수 있는 방법을 개발하였다. 모세관 전기영동법으로 흰쥐의 뇨 중에서 1,2,4-TMB의 대사체인 3,4-, 2,4-, 2,5-dimethylbenzoic acid 및 3,4-, 2,4-, 2,5-dimethylhippuric acid를 분석하기 위하여 내경 $75{\mu}m$, 총길이 36cm (검출기까지 29cm)인 용융실리카 모세관을 $15^{\circ}C$로 유지하면서 양단에 10㎸의 전압을 걸어주고, 전해질로는 15mM ${\beta}-CD$, 3% 2-프로판올을 포함하는 0.1M 인산완충액 (pH 7)을 사용하였으며, 검출신호는 UV 210nm와 254nm에서 동시에 모니터링하였다. 뇨 시료의 분석 결과 배설된 1,2,4-TMB의 대사체의 상대량은 3,4-이성질체가 56.7%, 2,4-이성질체가 30.5%, 2,5-이성질체가 12.8%였다. 이 방법은 노동자의 뇨 분석에도 적용될 수 있을 것으로 생각된다.

• Bulletin of the Korean Chemical Society
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• 제7권2호
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• pp.116-120
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• 1986

Irradiation of 1,4-diphenyl-1,3-butadiyne and 5,5-dimethyl-1-phenyl-1,3-hexadiyne with methanol yields 1:1 polar addition products, [E]- and [Z]-1,4-diphenyl-1-methoxy-1-buten-3-yne and [E]- and [Z]-5,5-dimethyl-1-methoxy-1-phenyl-1-hexen-3-yne, respectively. These geometrical isomers were converted into each other reaching the photostationary state on irradiation with 300 nm UV light. The photoaddition reaction of 1,4-diphenyl-1,3-butadiyne and 5,5-dimethyl-1-phenyl-1,3-hexadiyne with methanol seems to proceed from the zwitterionic lowest excited state.