• Title/Summary/Keyword: 4Cs

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석탄회 세슘포집재의 고온안정성 분석

  • 박장진;전관식;신진명;조영현;박현수
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.596-602
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    • 1996
  • 석탄화력발전소 폐기물인 석탄회로 포집한 세슘의 고온안정성 분석을 위하여 Cs/Al의 몰비를 0.1에서 1.5까지 변화시켜 제조한 시료를 TGA, XRD, SEM등으로 분석하였다. 몰비가 0.75이상에서부터 pollucite 상 이외에 CsAlSiO$_4$상이 나타나기 시작하였으며 몰비가 증가할수록 CsAlSiO$_4$상이 증가하였다. 몰비가 0.5까지 세슘의 휘발로 인한 무게감량은 없었고 0.75부터는 몰비가 증가할수록 무게감량이 증가하였다. 이는 몰비가 증가할수록 세슘 증기압이 큰 CsAlSiO$_4$상이 증가하기 때문인 것으로 사료된다.

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'Hillslope Erosion Assessment using 137Cs radionuclide in Granite and Sedimentary rock basins in South Korea'

  • Orkhonselenge, A.;Tanaka, Y.;Kim, Song-Hyun;Kim, Yong-Kyun
    • Proceedings of the Korean Quaternary Association Conference
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    • 2005.06a
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    • pp.7-11
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    • 2005
  • The soil erosion processes have estimated using spatial distribution of 137Cs radionuclide in Granite and Sedimentary Hillslopes in South Korea. The local variability of 137Cs inventory indicates that was related positively to organic matter content, clay content and water content and negatively to hydraulic permeability and slope gradient for bulk samples in different landforms within Granite and Sedimentary rock basins. The vertical variability of 137Cs inventory shows that most of 137Cs concentration and organic matter were accumulated between 0 and 2cms and gradually decrease with soil depth in incremental samples in both basins. The vertical variability of 137Cs inventories shows that 137Csinventories increase as we go to toward downslope in both basins. Finally, the soil loss values indicate that hillslope erosion processes are more intensive in Granite rock basin than those in Sedimentary rock basin.

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Synthesis and Crystal Structure of $CsTiP_2O_7$ ($CsTiP_2O_7$의 합성과 결정구조)

  • 김대영;동용관;이건수;윤호섭
    • Korean Journal of Crystallography
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    • v.10 no.1
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    • pp.51-55
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    • 1999
  • Cesium titanium(III) pyrophosphate 화합물인 CsTiP2O7을 합성하고 X절 회절법을 이용하여 그 결정구조를 해석하였다. 이물질은 단사정계의 P21/a 공간군으로 결정화되었고 a=8.369(2) , b=10.208(2) , c=7.752(1) , β=104.77(2)o, V=640.4(2) 3, and Z=4이다. 이 물질의 구조는 모서리를 공유하고 있는 TiO6 팔면체와 P2O7 pyrophosphate group들로 구성된 framework로 구성되어 있으며 그 결과로 형성된 tunnel 안에는 Cs+이온이 존재한다. CsTiP2O7은 ATiP2O7(A=K, Rb)와 KAIP2O7 그리고 AMoP2O7(A=K, Rb, Cs)등 다른 +3금속 pyrophosphate들로 유사한 구조를 가지고 있다. 이 물질은 [Cs+][Ti3+][P2O74-]의 식으로 표현할 수 있다.

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Compressive Sensing Reconstruction Based on the Quantization Constraint Sets (양자화 제한 집합에 기초한 컴프레시브 센싱 복구)

  • Kim, Dong-Sik
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.46 no.5
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    • pp.8-14
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    • 2009
  • In this paper, a convex optimization technique, which is based on the generalized quantization constraint (GQC), is proposed in the compressive sensing reconstruction using quantized measures. The set size of the proposed GQC can be controlled, and through extensive numerical simulations based on the uniform scalar quantizers, the CS reconstruction errors are improved by 3.4-3.6dB compared to the traditional QC method for the CS problems of m/klogn > 2.

Recovery of cesium ions from seawater using a porous silica-based ionic liquid impregnated adsorbent

  • Wu, Hao;Kudo, Tatsuya;Kim, Seong-Yun;Miwa, Misako;Matsuyama, Shigeo
    • Nuclear Engineering and Technology
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    • v.54 no.5
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    • pp.1597-1605
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    • 2022
  • A porous silica-based adsorbent was prepared by impregnating the pores of a silica support with the extractant 1,3-[(2,4-diethylheptylethoxy)oxy]-2,4-crown-6-calix[4]arene (Calix[4]arene-R14) and an additive agent 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (C2mim + NTf-2) as the materials to remove cesium(I) (Cs+) ions from seawater. The as-prepared adsorbent showed excellent adsorption performance toward Cs+ ions, with adsorption equilibrium reached within 2 h and an adsorption amount of 0.196 mmol/g observed. The solution pH, temperature, and the presence of coexisting metal ions were found to have almost no effect on Cs+ adsorption. The adsorption mechanism was considered to proceed via ion exchange between Cs+ and C2mim+. In addition, the particle-induced X-ray emission analysis results further clarified that the adsorbed Cs+ ion species on the adsorbent was in the form of both CsCl and CsBr.

Proton-Conducting Electrolyte $CsH_2PO_4$ for Intermediate-Temperature Fuel Cell

  • Park, Chi-Yeong;Lee, Su-Yeon;Jeon, Min-Hyeon;Lee, Gwang-Se;Kim, Jae-Hyeong;Kim, Jeong-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.218-218
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    • 2007
  • 고체 전해질로서 $CsH_2PO_4$결정은 $230^{\circ}C$ 이상에서 전기전도도가 $10^{-2}\;{\Omega}^{-1}cm^{-1}$의 값에 도달하는 초양성자(Superprotonic) 상태로 상전이를 한다. 이러한 이유로 $CsH_2PO_4$ 결정은 $230^{\circ}C$ 부근에서 사용할 수 있는 연료전지로 개발되어왔다. 실용적인 면에서 단결정의 경우보다 다결정의 물성 및 응용 연구가 많았는데, 입자 크기에 따른 체계적인 연구는 잘 이루어지지 않았다. 본 발표에서는 $CsH_2PO_4$ 다결정을 합성하여 SEM 및 micro Raman spectra를 조사하였다. SEM의 결과 입자들의 평균 크기는 100 nm 이었으며, micro Raman spectra는 Bulk $CsH_2PO_4$의 spectra 와 큰 차이를 보이지 않았다. $PO_4$의 내부진동은 거의 같은 주파수대를 보여주나, $300\;cm^{-1}$이하의 저주파 수 영역에서는 광학적 포논의 픽이 잘 보이지 않았다. 그 원인이 micro Raman 장치의 측정 특성인지, 물리적 변화인지는 확실치 않다.

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Effect of Cassiae semen extract on ovalbumin-induced allergic asthma in mice (결명자 추출물의 난알부민 감작으로 천식이 유발된 마우스에서의 개선 효과)

  • Seo, Beom-Su;Park, Yong-Ki
    • The Korea Journal of Herbology
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    • v.30 no.1
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    • pp.25-32
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    • 2015
  • Objectives : In this study, we investigated the effect of Cassia obtusifolia Linne (Cassiae Semen; CS) extract on ovalbumin (OVA)-induced allergic asthma in mice. Methods : CR was extracted with 70% ethanol. For in vitro study, HMC-1, human mast cells were treated with CS extract at 0.2 and $0.5mg/m{\ell}$ for 1 h, and then stimulated with compound (C) 48/80 for 30 min. Primary spleenocytes were isolated from the spleen of mice, treated with CS extract for 1 h, and then stimulated with ConA for 24 h. For in vivo study, mice were sensitized at day 0, 7 and 14 with 0.2% OVA and then airway challenged using neublizer at day 21, 23, 25, and 27 to induced allergic asthma. CS extract at doses of 100 and 300 mg/kg body weight was orally administered during OVA challenge once per a day. The levels of allergic mediators such as histamine, OVA-specific IgE, IL-4, and $IFN-{\gamma}$ were measured in the sera of mice or culture supernatants by EIA and ELISA, respectively. The expression of IL-4 and $IFN-{\gamma}$ gene was determined by RT-PCR. The histopathological change of lung tissues was observed with hematoxylin and eosin (H&E) and Periodic acid Schiff (PAS) staining. Results : The treatment of CS extract in HMC-1 cells significantly inhibited C48/80-induced degranulation, and histamine release. The treatment of CS extract in spleenocytes suppressed the expression of IL-4 and $IFN-{\gamma}$ mRNA. The administration of CS extract in OVA-induced asthmatic mice significantly decreased the levels of OVA-specific IgE, and IL-4 in a dose-dependent manner with OVA-control group. In addition, CS extract inhibited the infiltration of inflammatory cells and bronchiolar damage with epithelial thickening in lung tissues of OVA-induced asthma mice, and also mucin accumulation. Conclusions : These results indicate that CS extract prevents asthmatic damage through regulating the allergic immune response.

Biases in the Assessment of Left Ventricular Function by Compressed Sensing Cardiovascular Cine MRI

  • Yoon, Jong-Hyun;Kim, Pan-ki;Yang, Young-Joong;Park, Jinho;Choi, Byoung Wook;Ahn, Chang-Beom
    • Investigative Magnetic Resonance Imaging
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    • v.23 no.2
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    • pp.114-124
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    • 2019
  • Purpose: We investigate biases in the assessments of left ventricular function (LVF), by compressed sensing (CS)-cine magnetic resonance imaging (MRI). Materials and Methods: Cardiovascular cine images with short axis view, were obtained for 8 volunteers without CS. LVFs were assessed with subsampled data, with compression factors (CF) of 2, 3, 4, and 8. A semi-automatic segmentation program was used, for the assessment. The assessments by 3 CS methods (ITSC, FOCUSS, and view sharing (VS)), were compared to those without CS. Bland-Altman analysis and paired t-test were used, for comparison. In addition, real-time CS-cine imaging was also performed, with CF of 2, 3, 4, and 8 for the same volunteers. Assessments of LVF were similarly made, for CS data. A fixed compensation technique is suggested, to reduce the bias. Results: The assessment of LVF by CS-cine, includes bias and random noise. Bias appeared much larger than random noise. Median of end-diastolic volume (EDV) with CS-cine (ITSC or FOCUSS) appeared -1.4% to -7.1% smaller, compared to that of standard cine, depending on CF from (2 to 8). End-systolic volume (ESV) appeared +1.6% to +14.3% larger, stroke volume (SV), -2.4% to -16.4% smaller, and ejection fraction (EF), -1.1% to -9.2% smaller, with P < 0.05. Bias was reduced from -5.6% to -1.8% for EF, by compensation applied to real-time CS-cine (CF = 8). Conclusion: Loss of temporal resolution by adopting missing data from nearby cardiac frames, causes an underestimation for EDV, and an overestimation for ESV, resulting in underestimations for SV and EF. The bias is not random. Thus it should be removed or reduced for better diagnosis. A fixed compensation is suggested, to reduce bias in the assessment of LVF.

Development of environmentally friendly inorganic fluorescent pigments, A3V5O14 (A = K and Rb) and Cs2V4O11: Crystal structure, optical and color properties (친환경 무기 형광 안료 A3V5O14 (A = K and Rb) and Cs2V4O11 개발: 결정구조, 광학적 특성 및 착색 특성)

  • Jeong, Gyu Jin;Kim, Jin Ho;Lee, Younki;Hwang, Jonghee;Toda, Kenji;Bae, Byoungseo;Kim, Sun Woog
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.47-54
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    • 2020
  • To develop the bright-vivid red- and yellow-inorganic fluorescent pigments with high luminescence properties, A3V5O14 (A = K and Rb) and Cs2V4O11 inorganic pigments were synthesized by a water assisted solid state reaction (WASSR) method and a conventional solid state reaction method. Although impurity peaks corresponding to the AVO3 and AV3O8 (A = K, Rb, and Cs) were observed in all samples prepared, the trigonal structure A3V5O14 (A = K and Rb) and orthorhombic structure Cs2V4O11 were successfully obtained as a main phase. These inorganic pigments showed the broad absorption band (under 550 nm) originated from CT transitions of VO4 polyhedron, and the strong broad red- and green-emission bands due to 3T21A1 and 3T11A1 transitions of the [VO4]3- group. The A3V5O14 (A = K and Rb) and Cs2V4O11 pigments showed a bright-vivid red- and yellow-body color, where the a* values of the A3V5O14 (A = K and Rb) were +35.5 and +45.9, respectively, and b* value of Cs2V4O11 pigments was +50.3. The L* values of the A3V5O14 (A = K and Rb) and Cs2V4O11 inorganic pigments were over +45. These results indicate that the A3V5O14 (A = K and Rb) and Cs2V4O11 inorganic pigments could be an attractive candidate as a bright-vivid red- and yellow inorganic pigments.

Differential Toxicity of the Water and Ethanol Extracts of Chung-Sang, an Experimental Herbal Formula

  • Won, Ran;Choi, Jun-Yong;Han, Chang Woo;Jeong, Han-Sol;Shin, Sang Woo;Jung, Hee Jae;Joo, Myungsoo
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.32 no.4
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    • pp.255-260
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    • 2018
  • Chung-Sang (CS) is an experimental herbal remedy that is formulated to treat respiratory diseases implicated by inflammation. The herbs comprised of CS are frequently prescribed for treating various inflammatory symptoms: Menthae haplocalycis Herba, Magnoliae Flosis, Xanthii Fructus, Herba Asari, and Caryphylli Flos. Here, we prepared the extract of CS with boiling water (wCS) or with 50 % ethanol (eCS) and examined whether the two different extracts of CS exhibit a toxicity to cultured cells and mice. RAW 264.7 cells were treated with wCS or eCS, and the cytotoxicity of these extracts to RAW 264.7 cells was determined by an MTT assay. Although the production of intracellular reactive oxygen species that are detrimental to the cells was not increased by the extracts, the cytotoxicity to the cells was evident from 10 mg/ml of wCS and 100 mg/ml of eCS, suggesting that eCS is less cytotoxic. When mice (n = 10/group) received a single intratracheal wCS or eCS daily for 14 days, wCS yielded 40 % mortality, whereas eCS showed none. Both wCS and eCS did not significantly affect the weight of the body and of vital organs, except the lung. Biochemical analyses of mice blood indicated no damage to liver or kidney. However, unlike eCS, wCS significantly increased the level of IgE in serum. Collectively, our results show that eCS was less toxic than wCS, suggesting that CS prepared with 50 % ethanol is preferential over the conventional way of preparing CS.