• Title/Summary/Keyword: 3R4F

Search Result 2,350, Processing Time 0.032 seconds

Fabrication and Oxygen Permeation Properties of ${La_{1-x}Sr_{x}B_{1-{\gamma}}Fe_{\gamma}O_{3-{\delta}}$(B=Co, Ga) Perovskite-Type Ceramic Membranes (${La_{1-x}Sr_{x}B_{1-{\gamma}}Fe_{\gamma}O_{3-{\delta}}$(B=Co, Ga) 페롭스카이트 세라믹 분리막의 제조 및 산소투과특성)

  • 임경태;조통래;이기성;한인섭;서두원
    • Membrane Journal
    • /
    • v.11 no.4
    • /
    • pp.143-151
    • /
    • 2001
  • We have fabricated mixed-ionic conducting membranes, L $a_{0.6}$S $r_{0.4}$ $Co_{0.2}$F $e_{0.8}$ $O_{3-}$$\delta$/ and L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ by the solid state method. Ceramic membranes consisted of perovskite-type structures and exhibited high relative density, >95%. Especially, dense L $a_{0.6}$S $r_{0.4}$Co $O_{3-}$$\delta$/ layer was coated on the L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes by using screen printing technique in order to improve oxygen ion flux. We measured oxygen ion flux on uncoated L $a_{0.6}$S $r_{0.4}$ $Co_{0.2}$F $e_{0.8}$ $O_{3-}$$\delta$/, uncoated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/, and coated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes. The L $a_{0.6}$S $r_{0.4}$ $Co_{0.2}$F $e_{0.8}$ $O_{3-}$$\delta$/ membranes showed the highest flux, 0.26 mL/min.$\textrm{cm}^2$ at 90$0^{\circ}C$, after steady state had been reached. The oxygen flux of coated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes showed higher value, 0.19 mL/min.$\textrm{cm}^2$ at 95$0^{\circ}C$. This flux was as much as 2 or 3 times higher than those of uncoated L $a_{0.7}$S $r_{0.3}$G $a_{0.6}$F $e_{0.4}$ $O_{3-}$$\delta$/ membranes. 3-$\delta$/ membranes.X> 3-$\delta$/ membranes.membranes.

  • PDF

On the growth of entire functions satisfying second order linear differential equations

  • Kwon, Ki-Ho
    • Bulletin of the Korean Mathematical Society
    • /
    • v.33 no.3
    • /
    • pp.487-496
    • /
    • 1996
  • Let f(z) be an entire function. Then the order $\rho(f)$ of f is defined by $$ \rho(f) = \overline{lim}_r\to\infty \frac{log r}{log^+ T(r,f)} = \overline{lim}_r\to\infty \frac{log r}{log^+ log^+ M(r,f)}, $$ where T(r,f) is the Nevanlinna characteristic of f (see [4]), $M(r,f) = max_{$\mid$z$\mid$=r} $\mid$f(z)$\mid$$ and $log^+ t = max(log t, 0)$.

  • PDF

A Study of Convergence Social Voluntary Service Activity and Sense of Profession Values, Self-Esteem, Sociality in Nursing Students (간호대학생의 융·복합 사회봉사활동과 직업가치관, 자아존중감, 사회성에 관한 연구)

  • Yoon, Mi-Sun;Yim, So-youn
    • The Journal of the Korea Contents Association
    • /
    • v.18 no.11
    • /
    • pp.562-570
    • /
    • 2018
  • This study is a descriptive research to understand the degree and relevance of profession value, self - esteem, and sociality of nursing college students according to voluntary service activities. The results showed that the formation of profession values according to the general characteristics was related to religion (F = 4.79, p = .003) and major (F = 3.75, p = .011) and self esteem was related to grade (F = 4.84, p = .002). The profession values according to the characteristics of voluntary service activities showed a significant difference in volunteer time (F=18.70, p<.001), volunteer duration (F=18.87, p<.001), volunteer organization(F=3.41, p=.001), volunteer motivation(F=8.08, p<.001), participation path(F=3.63, p=.002), participation field(F = 2.13, p = .031). The profession value was positively correlated with self-esteem(r = .327, p <.01) and sociality(r= .248, p <.01). Self-esteem showed a statistically significant positive correlation with sociality(r= .327, p <.01).

GENERALIZED CUBIC MAPPINGS OF r-TYPE IN SEVERAL VARIABLES

  • Kang, Dong Seung
    • Journal of the Chungcheong Mathematical Society
    • /
    • v.20 no.1
    • /
    • pp.37-45
    • /
    • 2007
  • Let X, Y be vector spaces. In this paper, we investigate the generalized Hyers-Ulam-Rassias stability problem for a cubic function $f:X{\rightarrow}Y$ satisfies $$r^3f(\frac{\Sigma_{j=1}^{n-1}x_j+2x_n}{r})+r^3f(\frac{\Sigma_{j=1}^{n-1}x_j-2x_n}{r})+8\sum_{j=1}^{n-1}f(x_j)=2f{\sum_{j=1}^{n-1}}x_j)+4{\sum_{j=1}^{n-1}}(f(x_j+x_n)+f(x_j-x_n))$$ for all $x_1,{\cdots},x_n{\in}X$.

  • PDF

Flux Melting Route to 2-and 3-dimensional Fibrous Potassium Titanates, K$_2Ti_{2n}O_{4n+1}$ (n = 2 and 3) (Flux 용융법에 의한 2차원 및 3 차원 구조의 티탄산칼륨 섬유의 합성)

  • Jin-Ho Choy;Yang Su Han;Seung Wan Song
    • Journal of the Korean Chemical Society
    • /
    • v.37 no.8
    • /
    • pp.765-772
    • /
    • 1993
  • Two-dimensional potassium tetratitanate ($K_2Ti_4O_9$) and three-dimensional potassium hexatitanate ($K_2Ti_6O_{13}$) fibers have been prepared by the combined method consisting of the flux melting (1150$^{\circ}C$)-slow cooling (cooling rate = 5$^{\circ}C$/h) process from the starting raw materials of $K_2CO_3$, and $TiO_2$ with the flux of $K_2MoO_4$. It was found that the fiber growth reaction is strongly dependent upon the mole ratio of flux (F) to raw material (R), which is 7 : 3 (F : R) as for the optimum growth condition. Relatively long fibers (average length ${\thickapprox}$ 4 mm) with a mixture of $K_2Ti_4O_9$ (major) and $K_2Ti_6O_{13}$ (minor) could be obtained when the reaction was carried out for the $K_2MoO_4-$K_2O{\cdot}4TiO_2$ (F : R = 7 : 3) system, but for the $K_2$MoO_4$-$K_2O{\cdot}6TiO_2$ (F : R = 7: 3) one, only the short fibers with ${\thickapprox}$ 2 mm long could be grown as the mixed phase of $K_2Ti_6O_{13}$ and $K_2Ti_4O_9$.

  • PDF

Grignard Coupling Reaction of Bis(chloromethyl)diorganosilanes with Dichloro(diorgano)silanes: Syntheses of 1,3-Disilacyclobutanes

  • 조연석;유복렬;안삼영;정일남
    • Bulletin of the Korean Chemical Society
    • /
    • v.20 no.4
    • /
    • pp.427-430
    • /
    • 1999
  • The Grignard coupling reaction of bis(chloromethyl)diorganosilanes [(ClCH2)2SiR1R2: R1 = R2 = Me, la; R1 = Me, R2 = Ph, lb; R1 = R2 = Ph, lc] with diorganodichlorosilanes [(Cl2SiR3R4: R3 = R4 = Me, 2a; R3 = Me, R4 = Ph, 2b; R3 = R4 = Ph, 2c] at THE reflux temperature gave the intermolecular C-Si coupling product of 1,1,3,3-tetraorgano-1,3-disilacyclobutanes 3a-f in poor to moderate yields ranging from 7% to 50% along with polydiorganosilapropanes. The cyclization reaction of la-c with methyl-substituted dichlorosilanes 2a, b gave 1,3-disilacyclobutanes 3a-c, e, d in moderate yields (42-50%), while the same reaction with dichlorodiphenylsilane (2c) to 1,3-disilacyclobutanes 3d, f resulted in low yield (7-18%) probably due to the steric hindrance of two-phenyl groups on the silicon of 2c.

Preparation and Structure of $Re(NC_6F_5)(PPh_3)_2Cl_3 $ ($Re(NC_6F_5)(PPh_3)_2Cl_3 $화합물의 합성 및 구조)

  • 박병규;김영웅
    • Korean Journal of Crystallography
    • /
    • v.7 no.2
    • /
    • pp.113-119
    • /
    • 1996
  • Reaction of Re(O)(PPh3)2Cl3,I, with 2,3,4,5,6-pentafluoroaniline (C6F5NH2), produced Re(NC6F5)(PPh3)2Cl3, II. The product has been characterized by 1H-NMR, elemental analysis, and X-ray diffraction. II crystallizes in the orthorhombic system, space group Pna21 with cell parameters a=18.763Å, b=14.737(2)Å, c=16.707(3)Å, Z=4. Least-square refinement of the structure led to an R(wR2)factor of 0.0455(0.1148) for 3319 unique reflections of I > 2σ(I) and for 174 variables.

  • PDF

Regioselective Lithiation of $\alpha$-Methylpyridine Analogue and Its Trapping Reactions with $Me_2RSiCl(R = Me, tBuCH_2(Me_3Si)CH)$ ($\alpha$-Methylpyridine유도체의 국지 선택적 리튬화 반응과 $Me_2RSiCl(R = Me, tBuCH_2(Me_3Si)CH)$을 이용한 반응생성물의 확인반응)

  • Kim, Jeong Gyun;Park, Eun Mi;Son, Byeong Yeong
    • Journal of the Korean Chemical Society
    • /
    • v.38 no.8
    • /
    • pp.570-575
    • /
    • 1994
  • The metallation of $\alpha$-methylpyridine 1(a∼f) with n-BuLi produced $\alpha-methylenylpyridinium$ salt 3(a∼f) by elimination of butane. The trapping reactions of 3(a∼f) with $Me_3SiCl\;and\;Me_2SiClCH(SiMe_3)CH_2tBu$ produced only 4(a∼f) and 5(a∼f). The $\alpha$-hydrogen atom of silylated methylene group in 4(a∼f) is more reactive than unreacted $CH_3$ of 4(a∼f) itself and 1(a∼f) toward n-BuLi at low temperature in pentane medium.

  • PDF

ON THE PRIME SPECTRUM OF A RING (환의 PRIME SPECTRUM에 관하여)

  • Kim Eung Tai
    • The Mathematical Education
    • /
    • v.12 no.2
    • /
    • pp.5-12
    • /
    • 1974
  • 단위원을 가지는 하환환에 있어서의 Prime Spectrum에 관하여 다음 세가지 사실을 증명하였다. 1. X를 환 R의 prime spectrum, C(X)를 X에서 정의되는 실연적함수의 환, X를 C(X)의 maximal spectrum이라 하면 X는 C(X)의 prime spectrum의 부분공간으로서의 한 T-space로 된다. N을 환 R의 nilradical이라 하면, R/N이 regula 이면 X와 X는 위상동형이다. 2. f: R$\longrightarrow$R'을 ring homomorphism, P를 R의 한 Prime ideal, $R_{p}$, R'$_{p}$를 각각 S=R-P 및 f(S)에 관한 분수환(ring of fraction)이라 하고, k(P)를 local ring $R_{p}$의 residue' field라 할 때, R'의 prime spectrum의 부분공간인 $f^{*-1}$(P)는 k(P)(equation omitted)$_{R}$R'의 prime spectrum과 위상동형이다. 단 f*는 f*(Q)=$f^{-1}$(Q)로서 정의되는 함수 s*:Spec(R')$\longrightarrow$Spec(R)이다. 3. X를 환 S의 prime spectrum, N을 R의 nilradical이라 할 때, 다음 네가지 사실은 동치이다. (1) R/N 은 regular 이다. (2) X는 Zarski topology에 관하여 Hausdorff 공간이다. (3) X에서의 Zarski topology와 constructible topology와는 일치한다. (4) R의 임의의 원소 f에 대하여 f를 포함하지 않는 R의 prime ideal 전체의 집합 $X_{f}$는 Zarski topology에 관하여 개집합인 동시에 폐집합이다.폐집합이다....

  • PDF

Effects of CuO and ${B_2}{O_3}$Additions on Microwave Dielectric Properties of $PbWO_4$-$TiO_2$Ceramic (CuO ${B_2}{O_3}$첨가에 따른 $PbWO_4$-$TiO_2$세라믹스의 마이크로파 유전특성)

  • 최병훈;이경호
    • Journal of the Korean Ceramic Society
    • /
    • v.38 no.11
    • /
    • pp.1046-1054
    • /
    • 2001
  • Effects of B$_2$O$_3$and CuO addition on the microwave dielectric properties of the PbWO$_4$-TiO$_2$ceramics were investigated in order to use this material as an LTCC material for fabrication of a multilayered RF passive components module. We found that PbWO$_4$could be used as an LTCC material because of its low sintering temperature (8$50^{\circ}C$) and fairy good microwave dielectric properties($\varepsilon$$_{r}$=21.5, Q$\times$f$_{0}$=37200 GHz and $\tau$$_{f}$ =-31 ppm/$^{\circ}C$). In order to stabilize $\tau$$_{f}$ of PbWO$_4$, TiO$_2$was added to the PbWO$_4$and the mixture was sintered at 8$50^{\circ}C$. A near zero $\tau$$_{f}$ value (+0.2 ppm/$^{\circ}C$) was obtained with 8.7 mol% TiO$_2$addition. $\varepsilon$r and Q$\times$f$_{0}$ values were 22.3 and 21400 GHz, respectively. It was believed that the decrement of Q$\times$f$_{0}$ value with TiO$_2$addition was resulted from increasing grain boundary. In order to improve Q$\times$f$_{0}$, various amounts of B$_2$O$_3$and CuO were added to the 0.913PbWO$_4$-0.087TiO$_2$mixture. The optimum amount of CuO was 0.05 wt%. At this addition, the 0.913PbWO$_4$-0.087TiO$_2$ceramic showed $\varepsilon$$_{r}$=23.5, $\tau$$_{f}$ =-2.2ppm/$^{\circ}C$, and Q$\times$f$_{0}$=32900 GHz after sintered at 8$50^{\circ}C$. In case of B$_2$O$_3$addition, the optimum amount range was 1.0~2.5 wt% at which we could obtain following results; $\varepsilon$$_{r}$=20.3~22.1, Q$\times$f$_{0}$=48700~54700 GHz, and $\tau$$_{f}$ =+2.4~+8.2ppm/$^{\circ}C$.

  • PDF