• Journal of Electrochemical Science and Technology
• /
• v.10 no.1
• /
• pp.22-28
• /
• 2019

To maximize the oxygen evolution reaction (OER) in the electrolysis of water, nano-grade $IrO_2$ powder with a low specific surface was prepared as a catalyst for a solid polymer electrolyte (SPE) system, and a membrane electrode assembly (MEA) was prepared with a catalyst loading as low as $2mg\;cm^{-2}$ or less. The $IrO_2$ catalyst was composed of heterogeneous particles with particle sizes ranging from 20 to 70 nm, having a specific surface area of $3.8m^2g^{-1}$. The anode catalyst layer of about $5{\mu}m$ thickness was coated on the membrane (Nafion 117) for the MEA by the decal method. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) confirmed strong adhesion at the interface between the membrane and the catalyst electrode. Although the loading of the $IrO_2$ catalyst was as low as $1.1-1.7mg\;cm^{-2}$, the SPE cell delivered a voltage of 1.88-1.93 V at a current density of $1A\;cm^{-2}$ and operating temperature of $80^{\circ}C$. That is, it was observed that the over-potential of the cell for the oxygen evolution reaction (OER) decreased with increasing $IrO_2$ catalyst loading. The electrochemical stability of the MEA was investigated in the electrolysis of water at a current density of $1A\;cm^{-2}$ for a short time. A voltage of ~2.0 V was maintained without any remarkable deterioration of the MEA characteristics.

• Electronics and Telecommunications Trends
• /
• v.38 no.2
• /
• pp.1-11
• /
• 2023

The recent explosion in the number of low earth orbit (LEO) satellites launched to space allows to easily anticipate that the number of satellites in orbit will sustain a dramatic increase. As satellite components are integrated and unified with terrestrial cellular networks, they will play a key role in providing coverage and resilience for future cellular networks. We provide a brief overview of typical scenarios and network architectures for cellular-based LEO satellite communication systems. In addition, we outline 3GPP standardization trends in non-terrestrial networks and satellite access based on 5G/5G Advanced systems and analyze future evolution prospects of cellular-based satellite communication systems.

• Journal of the Korean Electrochemical Society
• /
• v.5 no.3
• /
• pp.131-142
• /
• 2002

The Langmuir adsorption isotherms of the under-potentially deposited hydrogen (UPD H) and the over-potentially deposited hydrogen (OPD H) at the poly-Pt/0.5M $H_2SO_4$ and 0.5 M LiOH aqueous electrolyte interfaces have been studied using cyclic voltammetric and ac impedance techniques. The behavior of the phase shift $(0^{\circ}{\leq}{-\phi}{\leq}90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1{\geq}{\theta}{\geq}0)$ at the interfaces. The phase-shift method, i.e., the phase-shift profile $({-\phi}\;vs.\;E)$ for the optimum intermediate frequency, can be used as a new electrochemical method to determine the Langmuir adsorption isotherms $({\theta}\;vs.\;E)$ of the UPD H and the OPD H for the cathodic $H_2$ evolution reactions at the interfaces. At the poly-Pt/0.5M $H_2SO_4$ aqueous electrolyte interface, the equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the OPD H are $2.1\times10^{-4}$ and 21.0kJ/mol, respectively. At the poly-Pt/0.5M LiOH aqueous electrolyte interface, K transits from 2.7(UPD H) to $6.2\times10^{-6}$ (OPD H) depending on the cathode potential (E) and vice versa. Similarly, ${\Delta}G_{ads}$ transits from -2.5kJ/mol (UPD H) to 29.7kJ/mol (OPD H) depending on I and vice versa. The transition of K and ${\Delta}G_{ads}$ is attributed to the two distinct adsorption sites of the UPD H and the OPD H on the poly-Pt surface. The UPD H and the OPD H on the poly-Pt surface are the independent processes depending on the H adsorption sites themselves rather than the sequential processes for the cathodic $H_2$ evolution reactions. The criterion of the UPD H and the OPD H is the H adsorption sites and processes rather than the $H_2$ evolution reactions and potentials. The poly-Pt wire electrode is more efficient and useful than the Pt(100) disc electrode for the cathodic $H_2$ evolution reactions in the aqueous electrolytes. The phase-shift method is well complementary to the thermodynamic method rather than conflicting.

• Journal of the Institute of Electronics Engineers of Korea TC
• /
• v.46 no.8
• /
• pp.16-21
• /
• 2009

OFDM is a key technology for 4G cellular systems in the future. But when OFDM is used in cellular system environment, it has severe inter-cell interference problems. In this paper, we propose an ICIC scheme that can reduce inter-cell interference for OFDM-based 4G cellular systems. and we analyze the efficiency of the proposed scheme. Simulation is carried out according to the simplified 3GPP LTE system level simulation parameters. We have confirmed the improvement of Geometry efficiency about 4dB at the results.

• The Bulletin of The Korean Astronomical Society
• /
• v.41 no.1
• /
• pp.50.2-50.2
• /
• 2016

Continuous accretion of metal-poor gas can explain the discrepancy between the number of observed G-dwarfs and the number predicted by the "simple model" of galactic evolution. The maximum accretion rate estimated based upon approaching high velocity clouds (HVCs) can be up to ${\sim}0.4M_{\odot}{\cdot}yr^{-1}$ which is comparable with the accretion rate required by many chemical evolution models that is at least ${\sim}0.45M_{\odot}{\cdot}yr^{-1}$. However, it is not clear to what extent the exchange of gas between the disk and the cloud can occur when an HVC collides with the galactic disk. Therefore, we examined a series of HVC-Disk collision simulations using the FLASH 2.5 hydrodynamics simulation code. The outcomes of our simulations show that an HVC will more likely take away substances from the galactic disk rather than adding new material to the disk. We define this as an HVC having a "negative fuel rate". Further results in our study also indicate that the process and amount of fuel rate change can have various forms depending on the density, radius and velocity of an approaching HVC. The simulations in our study covers HVCs with a neutral hydrogen volume density from $1.0{\times}10^{-2}cm^{-3}$ to $41.0cm^{-3}$, radius of 200 pc to 1000 pc and velocity in the range between $40km{\cdot}s^{-1}$ and $100km{\cdot}s^{-1}$.

• Journal of Microbiology and Biotechnology
• /
• v.27 no.3
• /
• pp.507-513
• /
• 2017

Bacillus subtilis spores can be used for protein display to engineer protein properties. This method overcomes viability and protein-folding concerns associated with traditional protein display methods. Spores remain viable under extreme conditions and the genotype/phenotype connection remains intact. In addition, the natural sporulation process eliminates protein-folding concerns that are coupled to the target protein traveling through cell membranes. Furthermore, ATP-dependent chaperones are present to assist in protein folding. CotA was optimized as a whole-cell biocatalyst immobilized in an inert matrix of the spore. In general, proteins that are immobilized have advantages in biocatalysis. For example, the protein can be easily removed from the reaction and it is more stable. The aim is to improve the pH stability using spore display. The maximum activity of CotA is between pH 4 and 5 for the substrate ABTS (ABTS = diammonium 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate). However, the activity dramatically decreases at pH 4. The activity is not significantly altered at pH 5. A library of approximately 3,000 clones was screened. A E498G variant was identified to have a half-life of inactivation ($t_{1/2}$) at pH 4 that was 24.8 times greater compared with wt-CotA. In a previous investigation, a CotA library was screened for organic solvent resistance and a T480A mutant was found. Consequently, T480A/E498G-CotA was constructed and the $t_{1/2}$ was 62.1 times greater than wt-CotA. Finally, E498G-CotA and T480A/E498G-CotA yielded 3.7- and 5.3-fold more product than did wt-CotA after recycling the biocatalyst seven times over 42 h.

• Progress in Superconductivity
• /
• v.3 no.1
• /
• pp.91-94
• /
• 2001

By varying fabricating process, precursor powders with different initial conditions were prepared. Subsequently, Bi-2223/Ag tapes were made through these powders. The effects of precursor powders on the phase evolution and Jr properties of Bi-2223/Ag tapes were studied along with several thermomechanical cycles. Our results showed that the initial conditions of precursor powders could strongly influence the phase formation rate and $J_{c}$ value in final tapes. The factors of precursor powders that influence the phase formation and $J_{c}$ of Bi-2223/Ag tapes must be studied and optimized in combination.ion.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2001.10a
• /
• pp.236-239
• /
• 2001

In thixoforming, the globule size is determined by the hoding time of last reheating stage. In this study, some experiments to investigate the relationship between the mechanical properties and the holding time were performed A357, A390 and A3l9 alloys are used in this study. This paper shows the evolution of the microstructure according to the holding time of last reheating stage. Tensile test was performed for each reheating condition to examine the effect of globule size.

• Electronics and Telecommunications Trends
• /
• v.32 no.6
• /
• pp.66-72
• /
• 2017

The frequency range of a radio wave is from 3kHz to 300GHz, and radio technologies use this range to improve the quality of human lives. Radio technologies have entered a new phase of communication. The core infrastructure used as the basis for technologies leading the fourth industrial evolution, such as artificial intelligence, the Internet of Things, autonomous cars/drones, augmented reality, robots, and remote medical diagnoses, is the 5G network. The 5G network enables transmitting and receiving large amounts of data at very high speed. In particular, application technologies with artificial intelligence have been studied, including radar, wireless charging, electromagnetic devices and their effects on humans, EMI/EMC, and microwave imaging. In this study, we present a future radio technology that is needed to prepare for the upcoming industrial revolution and digital transformation.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.31 no.12B
• /
• pp.1099-1111
• /
• 2006

As W-CDMA R5(HSDPA) service became recently commercialized in Korea, there is increasing demand for new pricing methodology for the 3G mobile interconnection at the earliest possible time. However, it is hard to find any case of systematic study on it. In this paper, a synthetic investigation into the three aspects of new mobile telecommunication service - technology, market, and regulation - is conducted to verify the validity of new interconnection pricing methodology. As the findings of this research indicate, given the several technological limits of 3G, speed of mobile telecommunication industry evolution, the problem of verifying ex-ante regulations' validity, and the cases of some foreign countries, it is suggested that immediate revision of interconnection policy is not sensible and that the revision is more desirable to be postponed until the maturity of the 3G market or the adoption of All-IP network.