• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.412-415
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• 2017

In this study, the decomposition performance of ammonia dinitramide (ADN) based liquid monopropellant was evaluated by using metal supported alumina bead catalyst. Alumina bead was calcined at $1200^{\circ}C$, and Pt and Cu were impregnated on alumina bead by excess water impregnation using a rotary evaporator. The decomposition temperature ($T_{dec}$) of ADN-based liquid monopropellant was measured in a home-made batch reactor. The decomposition temperature of Cu/$Al_2O_3$ catalyst was lower than that of Pt/$Al_2O_3$ catalyst, and $T_{dec}$ was about $130^{\circ}C$.

• Polymer(Korea)
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• v.32 no.5
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• pp.446-457
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• 2008

Three kinds of hydroxypropyl cellulose (HPC) derivatives: 6- (cholesteryloxycarbonyl) pentoxypropyl celluloses(CHPCs) with degree of esterification(DE) ranging from 0.6 to 3, 6-[4-{4'-(nitrophenylazo)phenoxycarbonyl}] pentoxypropyl celluloses (NHPCs) with DE ranging from 0.4 to 3, and fully 6-(cholesteryloxycarbonyl) pentanoated NHPCs (CNHPCs) were synthesized, and their thermotropic liquid crystalline properties were investigated. All the CHPCs and NHPCs with $DE{\leq}1.7$ formed enantiotropic cholesteric phases, whereas CNHPCs with 6-(cholesteryloxycarbonyl) pentanoyl DE(DEC) more than 1.6 exhibited monotropic cholesteric phases. On the other hand, NHPCs with $DE{\geq}2.4$ and CNHPCs with $DEC{\leq}1.3$ showed monotropic nematic phases. NHPCs with $DE{\leq}l$, as well as HPC, formed right-handed helices whose optical pitches (${{\lambda}_m}'s$) increase with temperature, while all the CHPCs formed left-handed helices whose ${{\lambda}_m}'s$ decrease with temperature. In contrast with these derivatives, NHPCs with $1.4{\leq}DE{\leq}1.7$ and CNHPCs with $DEC{\geq}1.6$ did not display reflection colors over the full cholesteric range, suggesting that the helical twisting power of the cellulose chain and the cholesteryl group highly depends on the chemical structure and DE of mesogenic group.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.33 no.4
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• pp.455-463
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• 2023

Objectives: The aim of this study was to develop an air sampling and analytical method for estimating worker exposure to linear carbonate solvents and to evaluate the method. Methods: The target substances were three linear carbonates: DMC, DEC, EMC. GC/FID was used for sample analysis. Laboratory experiments were conducted to determine desorption solvents and sample capacity, and to evaluate storage stability, accuracy, and precision. Results: Coconut Shell Charcoal (CSC, 100/50 mg) was used as the air sampling media, and a desorption solvent of 5% methanol/95% dichloromethane was selected. Recommended sampling capacities were 1~11 ℓ for DMC, 1~18 ℓ for DEC, and 1~24 ℓ for EMC. The stability of three linear carbonates was demonstrated over 30 days in a refrigerator (4℃). Detection limits were determined as follows: DMC 0.26 ㎍/sample, DEC 0.24 ㎍/sample, and EMC 0.25 ㎍/sample. The total coefficient of variation was calculated as DMC 0.064, DEC 0.079, and EMC 0.07. Conclusions: This sampling and analysis method is suitable for estimating personal exposure to linear carbonates in the workplace.

• Nuclear Engineering and Technology
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• v.50 no.2
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• pp.259-267
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• 2018

Focused ion beam-scanning electron microscope and electron backscattered diffraction examinations were conducted in the center of a $73\;GWd/t_U\;UO_2$ fuel. They showed the formation of subdomains within the initial grains. The local crystal orientations in these domains were close to that of the original grain. Most of the fission gas bubbles were located on the boundaries. Their shapes were far from spherical and far from lenticular. No interlinked bubble network was found. These observations shed light on previous unexplained observations. They plead for a revision of the classical description of fission gas release mechanisms for the center of high burn-up $UO_2$. Yet, complementary detailed observations are needed to better understand the mechanisms involved.

• Journal of the Korean Society of Safety
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• v.38 no.5
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• pp.8-14
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• 2023

Lithium ions can induce the thermal runaway phenomenon and lead to reignition due to electrical, mechanical, and environmental factors such as high temperature, smoke generation, explosions, or flames, which is extremely likely to create safety concerns. Therefore, one of the ways to improve the flame retardancy of the electrolyte is to use a flame-retardant additive. Comparing the associated characteristic value of existing substances with the required experimental value, it was found that these values were either considerably different or were not documented. It is vital to know a substance's combustion characteristic values, flash point, explosion limit, and autoignition temperature (AIT) as well as its combustion characteristics before using it. In this research, the flash point and AIT of materials were measured by mixing a highly volatile and flammable substance, diethyl carbonate (DEC), with flame-retardant dimethyl methylphosphonate (DMMP). The flash point of DEC, which is a pure substance, was 29℃, and that for DMMP was 65℃. Further, the lower explosion limit calculated using the measured flash point of DEC was 1.79 Vol.%, while that for DMMP was 0.79 Vol.%. The AIT was 410℃ and 390℃ for DEC and DMMP, respectively. In particular, since the AIT of DMMP has not been discussed in any previous study, it is necessary to ensure safety through experimental values. In this study, the experimental and regression analysis revealed that the average absolute deviation (ADD) for the flash point of the DEC+DMMP DEC+DMMP system is 0.58 sec and that the flash point tends to increase according to changes in the composition employed. It also revealed that the AAD for the AIT of the mixture was 3.17 sec and that the AIT tended to decrease and then increase based on changes in the composition.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.545-549
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• 2001

We have produced electrolyte solution out of 1.15M $LiPF_6$ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M $LiPF_6$ DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M $LiPF_6$ EC/DEC(1/2 by vol%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC,DMC and EMC brought the de-decomposition peak of salt anion of $PF_6$ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. $Li/Li^+$). In addition, a kinetics current peak, in which intercalation of Lt is proceeded at 750mV, 450mV(vs. $Li/Li^+$), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance($R_{ct}$) according to the electric potential of $Li^+$ intercalation at 750mV(vs. $Li/Li^+$), which was the same as the resistance ($R_f$) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance($R_p$) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.545-549
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• 2001

We have produced electrolyte solution out of 1.15M LiPF$\sub$6/ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M LiPF$\sub$6/DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M LiPF$\sub$6/ EC/DEC(1/2 by vo%%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC, DMC and EMC brought the de-decomposition peak of salt anion of PF$\sub$6/$\^$-/ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. Li/Li$\^$+/\`). In addition, a kinetics current peak, in which intercalation of Li$\^$+/ is proceeded at 750mv, 450mv(vs. Li/Li$\^$+/), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance(R$\sub$ct/) according to the electric potential of Li$\^$+/ intercalation at 750mv(vs. Li/Li$\^$+/), which was the same as the resistance (R$\sub$f/) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance(R$\sub$p/) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

• Tribology and Lubricants
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• v.37 no.3
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• pp.99-105
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• 2021

In this study, for a high-pressure turbine (HPT) of 800 MW class supercritical thermal-power plant, considering aerodynamic cross-coupling, we performed a rotordynamic logarithmic decrement (LogDec) stability analysis with various tilting pad journal bearing (TPJB) designs, which several steam turbine OEMs (original equipment manufacturers) currently apply in their supercritical and ultra-supercritical HPTs. We considered the following TPJB designs: 6-Pad load on pad (LOP)/load between pad (LBP), 5-Pad LOP/LBP, Hybrid 3-Pad LOP (lower 3-Pad tilting and upper 1-Pad fixed), and 5-Pad LBPs with the design variables of offset and preload. We used the API Level-I method for a LogDec stability analysis. Following results are summarized only in a standpoint of LogDec stability. The Hybrid 3-Pad LOP TPJBs most excellently outperform all the other TPJBs over nearly a full range of cross-coupled stiffness. In a high range of cross-coupled stiffness, both the 6-Pad LOP and 5-Pad LOP TPJBs may be recommended as a practical conservative bearing design approach for enhancing a rotordynamic stability of the HPT. As expected, in a high range of cross-coupled stiffness, the 6-Pad LBP TPJBs exhibit a better performance than the 5-Pad LBP TPJBs. However, contrary to one's expectation, notably, the 5-Pad LOP TPJBs exhibit a slightly better performance than the 6-Pad LOP TPJBs. Furthermore, we do not recommend any TPJB design efforts of either increasing a pad offset from 0.5 or a pad preload from 0 for the HPT in a standpoint of stability.

• The Journal of Engineering Geology
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• v.32 no.3
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• pp.351-361
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• 2022

Numerical analysis performed to predict the behavior of Ipseok-dae columnar joints in Mudeungsan National Park to understand their stability and movement. The numerical analysis technique, 3DEC, is based on the discrete element method that can analysis discontinuities. The analysis used data for material properties derived from laboratory tests, which found that average density was 2.68 kN/m³, average normal stiffness was 3.15 GPa/m, average shear stiffness was 1.00 GPa/m, average cohesion was 0.51 MPa, and the average friction angle was 33°. The Ipseok-dae columnar joints were modeled on the basis of the field survey data for 15 joints located between the observation platform and the hiking trail. The numerical analysis assessed the behavior of each columnar joint by interpreting the displacement of the edges of its upper and lower surfaces. The greatest maximum displacement was found in columnar joint No. 6, and the greatest minimum displacement was found in joint No. 11. Analyzing the movements of five discontinuities in joint No. 11 indicated that the maximum displacement occurred at the 2nd level. The other levels were ordered 5th, 4th, 1st, and 3rd in terms of subsequent greatest displacements. Considering the total displacement in the 15 studied joints, the Ipseok-dae columnar joints are judged to be stable. However, considering the cultural and historical value of Mudeungsan National Park, it is regarded that the currents slope stability should be maintained by monitoring the individual rock blocks of the joints.

• Nuclear Engineering and Technology
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• v.56 no.3
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• pp.866-872
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• 2024

Design Extension Conditions (DEC)-A assessments of the operating nuclear power plants are generally considered for the purpose of getting additional safety demonstrations of their capability to undergo conditions that are generally more severe than DBAs by features implemented in the design and accident management measures. The pursued methodology is generally based upon Best Estimate approaches aiming at verifying that the safety limits in terms of integrity of the barriers against eventual large or early releases of radioactive material are fulfilled. These aspects are nowadays being experimentally and analytically addressed within the OECD/NEA experimental projects like the ATLAS and PKL series where a set of DEC-A experiments are considered. In this paper, experiments related to SBLOCA at the vessel upper head of the pressurized vessel of ATLAS and PKL are analytically assessed using the CATHARE code. These experiments includes issues related to common cause failure of the safety injection system and operator actions for preventing core excessive overheating. It is shown that, on the one hand, the safety features embedded in the design together with the operator actions are capable to prevent the progression towards a severe accident state and on the other hand, the code prediction capabilities for such scenario are generally good but still to be enhanced.