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Adsorption Characteristics of Pb(II) and Cr(III) onto C-Methylcalix[4]resorcinarene (C-Metylcalix[4]resorcinarene에서 Pb(II)와 Cr(III)의 흡착 특징)

  • Jumina, Jumina;Sarjono, Ratnaningsih Eko;Siswanta, Dwi;Santosa, Sri Juari;Ohto, Keisuke
    • Journal of the Korean Chemical Society
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    • v.55 no.3
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    • pp.454-462
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    • 2011
  • A study on the adsorption characteristics of Pb(II) and Cr(III) cations onto C-methylcalix[4]resorcinarene (CMCR) has been conducted. CMCR was produced by one step synthesis from resorcinol, acetaldehyde, and HCl. Most parameters in batch system confirm that CMCR is a good adsorbent for Pb(II) and Cr(III). Cr(III) uptake was bigger than that of Pb(II), but Cr(III) adsorption rate was slower than Pb(II). The adsorption kinetic of Pb(II) and Cr(III) adsorptions in batch followed pseudo $2^{nd}$ order kinetics model, but the kinetic of Pb(II) adsorption in fixed bed column system followed first order model. Desorption studies to recover the adsorbed Pb(II) was performed sequentially with distilled water and HCl, and the results showed that the adsorption was dominated by chemisorption.

Electrical Properties of (Ba,Ca)(Ti,Zr)O3 Ceramics for Bimorph-type Piezoelectric Actuator

  • Shin, Sang-Hoon;Yoo, Ju-Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.4
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    • pp.226-229
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    • 2014
  • In this study, lead-free $(Ba_{0.85}Ca_{0.15})(Ti_{1-x}Zr_x)O_3$ ceramics and a bimorph-type piezoelectric actuator were fabricated using the normal oxide-mixed sintering method, and their dielectric properties, microstructure, and displacement properties were investigated. From the results of X-ray diffraction, the pattern of the specimen has a pure perovskite structure. In addition, no secondary impurity phases were found. The excellent piezoelectric coefficient of $d_{33}=454pC/N$, the electromechanical coupling factor $k_p=0.51$, the dielectric constant ${\varepsilon}_r=3,657$, the mechanical quality factor $Q_m=239$, and $T_c$(Tetragonal-Cubic) =$90^{\circ}C$ were shown at x= 0.085. ${\Delta}k_p/k_p20^{\circ}C$ and ${\Delta}f_r/f_r20^{\circ}C$ showed the maximum value of -0.255 and 0.111 at $-20^{\circ}C$ and $80^{\circ}C$, respectively. The maximum total-displacement was $60{\mu}m$ under the input voltage of 50 V. As a result, it is considered that lead-free $(Ba_{0.85}Ca_{0.15})(Ti_{1-x}Zr_x)O_3$ ceramics is a promising candidate for piezoelectric actuator application for x= 0.085.

포항지역 지열수의 수리지구화학적 특성

  • 고동찬;염병우;하규철;송윤호
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.453-454
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    • 2004
  • Hydrogeochemical and isotopic characteristics were investigated for groundwater of Tertiary basin in southeastern part of Korea where deep drilling is in progress for geothermal investigation. According to geology, aquifer was distinguished as alluvial, tertiary sedimentary bedrock (bedrock groundwater), and fractured volcanic rock (deep groundwater). Groundwater of each aquifer is distinctively separated in Eh-pH conditions and concentrations of Cl, F, B and HCO$_3$. Deep groundwater has very low level 3H and 14C whereas alluvial groundwater has those of recent precipitation level. However one of deep groundwater show mixed characteristics in terms of hydrochemistry which indicates effect of pumping. Deep groundwater have temperature of 38 to 43$^{\circ}C$ whereas bedrock and alluvial groundwater have temperature less than 2$0^{\circ}C$. Fractured basement rock aquifer has different hydrogeologicalsetting from bedrock and alluvial aquifer considering hydrogeochemical and isotopic characteristics, and temperature.

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The Effect of $WO_3$ Addition on Microwave Dielectric Properties in $BaTiO_3-3{(1-x)TiO_2-xWO_3}$ System ($WO_3$ 첨가량 변화에 따른 $BaTiO_3-3{(1-x)TiO_2-xWO_3}$ 계의 고주파 유전특성)

  • 박찬식;변재동;김왕섭;김경용
    • Journal of the Korean Ceramic Society
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    • v.32 no.4
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    • pp.448-454
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    • 1995
  • The effect of WO3 addition on microwave dielectric properties of BaTiO3-3{(1-x)TiO2-xWO3} system was studied. Addition of WO3 to this system resulted in the formation of BaWO4 and Ba2Ti9O20 phases. Both the dielectric constant (K) and the temperature coefficientof resonant frequency (Tf) were decreased with the amount of WO3 addition. The value of Q$\times$f0 was increased as the amount of WO3 was increased up to x=0.0275, and then decreased when x exceeded 0.03. At x=0.0275, this ceramic showed excellent microwave proprties of K=34-35, Q$\times$f0=50,000-53,000, and near zero ppm/$^{\circ}C$ of Tf.

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Intestinal Permeability of Oyster Shell Calcium with Different Particle Sizes (패각 칼슘 입자 크기에 따른 흡수율)

  • Han, JeungHi;Choi, Hyeon-Son;Ra, Kyung Soo;Chung, Seungsik;Suh, Hyung Joo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.43 no.3
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    • pp.454-458
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    • 2014
  • In this study, we examined the ionization rate and permeability of nanocalcium prepared from oyster shells with various particle sizes. Four particle sizes of the calcium samples were prepared by centrifugation according to their density disparity in alcoholic solution: NC (normal calcium), C-1 (supernatant of 1,000 rpm), C-2 (supernatant of 2,000 rpm), and C-3 (supernatant of 3,000 rpm). Particle sizes of NC, C-1, C-2, and C-3 were $2,280.3{\pm}64.3nm$, $521.3{\pm}83.3nm$, $313.9{\pm}29.5nm$, and $280.0{\pm}3.4nm$, respectively. C-3 showed a slight increase in ionization rate compared with the other calcium samples, but their differences were not significant. Dialysis membrane-employed analysis showed that nanocalcium permeability increased as its particle size smaller; 32% of C-3 nanocalcium was transported to the outside of the membrane, whereas C-1 showed a 25% transport rate. We determined the permeability of the nanocalciums by using rat intestinal sacs, in order to provide different intestinal environments depending on pH level. Nanocalcium generally showed a higher permeability at pH 7, which represents an ileum environments compared to the duodenum and jejunum environments at pH 4.2 and pH 6.2, respectively. However, C-3 calcium showed the highest permeability, followed by C-2, C-1 and NS calciums. This result shows that the size of calcium positively affected its permeability in the intestinal sac. Taken together, nano-sized calcium derived from discarded oyster shell shows improved permeability in intestinal environments.

Gas sensing characteristics of $LaCoO_3$ thick-films ($LaCoO_3$ 후막의 가스 감지 특성)

  • Shin, Jeong-Ho;Jang, Jae-Young;Ma, Tae-Young;Park, Ki-Cheol;Kim, Jeong-Gyoo
    • Journal of Sensor Science and Technology
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    • v.8 no.6
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    • pp.454-460
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    • 1999
  • $LaCoO_3$ thick-films for gas sensing layers were prepared on alumina substrate by screen printing method. The sensitivities to $C_4H_{10}$, $NH_3$, NO and CO gases were investigated for different heat treatment temperatures of the films. Their structural properties were examined by X-Ray Diffraction measurements and SEM photographs. The sensitivity of $LaCoO_3$ thick-film to CO gas was much higher than those of $C_4H_{10}$, $NH_3$, and NO gases. The optimal heat treatment and operating temperatures were $800^{\circ}C$ and $150^{\circ}C$, respectively. The sensitivities of $LaCoO_3$ thick-films to 500ppm and 1250ppm CO gas were 72% and 95%, respectively.

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THE NUMBER OF LINEAR SYSTEMS COMPUTING THE GONALITY

  • Coppens, Marc
    • Journal of the Korean Mathematical Society
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    • v.37 no.3
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    • pp.437-454
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    • 2000
  • Let C be a smooth k-gonal curve of genus g. We study the number of pencils of degree k on C. In case $g\geqk(k-a)/2$ we state a conjecture based on a discussion on plane models for C. From previous work it is known that if C possesses a large number of pencils then C has a special plane model. From this observation the conjectures are split up in two cases : the existence of some types of plane curves should imply the existence of curves C with a given number of pencils; the non-existence of plane curves should imply the non-existence of curves C with some given large number of pencils. The non-existence part only occurs in the range $k(k-1)/2\leqg\leqk(k-1)/2] if k\geq7$. In this range we prove the existence part of the conjecture and we also prove some non-existence statements. Those result imply the conjecture in that range for $k\leq10$. The cases $k\leq6$ are handled separately.

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Effect of Pb Doping on the Thermoelectric Properties of Bi0.48Sb1.52Te3 (Bi0.48Sb1.52Te3의 열전특성에 대한 Pb 도핑 영향)

  • Moon, Seung Pil;Kim, Tae Wan;Kim, Sung Wng;Jeon, Woo Min;Kim, Jin Heon;Lee, Kyu Hyoung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.7
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    • pp.454-458
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    • 2017
  • $Bi_2Te_3$-based alloys have been intensively investigated as active materials for thermoelectric power generation devices from low-temperature (< $250^{\circ}C$) waste heat. In the present study, we fabricated Pb-doped, p-type $Bi_{0.48}Sb_{1.52}Te_3$ polycrystalline bulks by using meltsolidification and spark plasma sintering techniques, and evaluated their thermoelectric transport properties in an effort to develop optimized composition for low-temperature power generation applications. The electronic and thermal transport properties of $Bi_{0.48}Sb_{1.52}Te_3$ could be manipulated by Pb doping. As a result, the temperature for a peak thermoelectric performance (zT) gradually shifted toward higher temperatures with Pb content, suggesting that thermoelectric power generation efficiency can be enhanced by controlled Pb doping.

Effect of Annealing Conditions on Microstructures and Mechanical Properties of a 5083 Al Alloy deformed at Cryogenic Temperature (어닐링 조건이 극저온 압연 5083 Al Alloy의 미세조직 및 기계적성질에 미치는 영향)

  • 이영범;남원종
    • Transactions of Materials Processing
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    • v.13 no.5
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    • pp.449-454
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    • 2004
  • The annealing behavior of a 5083 Al alloy deformed at cryogenic temperature was investigated, focusing on the evolution of microstructures and mechanical properties. Especially, the effects of annealing temperature, $150~300^{\circ}C$, and time, 3∼60min., on microstructures and mechanical properties of the sheets received 85% reduction at cryogenic temperature were investigated. The optimization of the annealing conditions resulted in a mixture of equiaxed grains and elongated subgrains, exhibiting a good combination of uniform elongation and high strength.