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http://dx.doi.org/10.5012/jkcs.2011.55.3.454

Adsorption Characteristics of Pb(II) and Cr(III) onto C-Methylcalix[4]resorcinarene  

Jumina, Jumina (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University)
Sarjono, Ratnaningsih Eko (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Indonesia Educational University)
Siswanta, Dwi (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University)
Santosa, Sri Juari (Department of Chemistry, Faculty of Mathematics and Natural Sciences, Gadjah Mada University)
Ohto, Keisuke (Department of Chemistry and Applied Chemistry, Faculty of Science and Engineering, Saga University)
Publication Information
Journal of the Korean Chemical Society / v.55, no.3, 2011 , pp. 454-462 More about this Journal
Abstract
A study on the adsorption characteristics of Pb(II) and Cr(III) cations onto C-methylcalix[4]resorcinarene (CMCR) has been conducted. CMCR was produced by one step synthesis from resorcinol, acetaldehyde, and HCl. Most parameters in batch system confirm that CMCR is a good adsorbent for Pb(II) and Cr(III). Cr(III) uptake was bigger than that of Pb(II), but Cr(III) adsorption rate was slower than Pb(II). The adsorption kinetic of Pb(II) and Cr(III) adsorptions in batch followed pseudo $2^{nd}$ order kinetics model, but the kinetic of Pb(II) adsorption in fixed bed column system followed first order model. Desorption studies to recover the adsorbed Pb(II) was performed sequentially with distilled water and HCl, and the results showed that the adsorption was dominated by chemisorption.
Keywords
adsorption; Pb(II); Cr(III); C-methylcalix[4]resorcinarene; batch system; fixed bed column;
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