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Influence of Thermal Annealing on the Microstructural Properties of Indium Tin Oxide Nanoparticles

  • Kim, Sung-Nam;Kim, Seung-Bin;Choi, Hyun-Chul
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.194-198
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    • 2012
  • In this work, we studied the microstructural changes of ITO during the annealing process. ITO nanoparticles were prepared by the sol-gel method using indium tin hydroxide as the precursor. The prepared sample was investigated using TEM, powder XRD, XPS, DRIFT, and 2D correlation analysis. The O 1s XPS spectra suggested that the microstructural changes during the annealing process are closely correlated with the oxygen sites of the ITO nanoparticles. The temperature-dependent in situ DRIFT spectra suggested that In-OH in the terminal sites is firstly decomposed and, then, Sn-O-Sn is produced in the ITO nanoparticles during the thermal annealing process. Based on the 2D correlation analysis, we deduced the following sequence of events: 1483 (due to In-OH bending mode) ${\rightarrow}$ 2268, 2164 (due to In-OH stretching mode) ${\rightarrow}$ 1546 (due to overtones of Sn-O-Sn modes) ${\rightarrow}$ 1412 (due to overtones of Sn-O-Sn modes) $cm^{-1}$.

Measurements of Thermal Characteristics for a Micro-Fabricated Thermal Mass Air Flow Sensor With Real-Time Controller (실시간 제어기를 이용한 마이크로 열식 질량공기 유량센서의 열특성 측정)

  • Park, Byung-Kyu;Lee, Joon-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.8
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    • pp.573-579
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    • 2009
  • A thermal mass air flow sensor, which consists of a micro-heater and thermal sensors on the silicon-nitride thin membrane structure, is micro-fabricated by MEMS processes. Three thermo-resistive sensors, one for the measurement of microheater temperature, the others for the measurement of membrane temperature upstream and downstream of the micro-heater respectively, are used. The micro-heater is operated under the constant temperature difference mode via a real time controller, based on inlet air temperature. Two design models for microfabricated flow sensor are compared with experimental results and confirmed their applicabilities and limitations. The thermal characteristics are measured to find the best flow indicator. It is found that two normalized temperature indicators can be adopted with some advantages in practice. The flow sensor with this control mode can be adopted for wide capability of high speed and sensitivity in the very low and medium velocity ranges.

Adsorption of O Atom on Cr (100), (110), (111), and (211) Surfaces: An 5-Parameter Morse Potential Method Study

  • Han, Ling-Li;Liu, Tao
    • Bulletin of the Korean Chemical Society
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    • v.33 no.6
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    • pp.1867-1872
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    • 2012
  • The 5-parameter Morse potential (5-MP) method for the interaction between O atom and Cr surfaces is constructed in the present work. The adsorption of O on Cr (100), (110), (111), and (211) surfaces are studied with 5-MP in detail. The fourfold hollow site of the Cr (100) surface is favored for O atom. On Cr (110), quasithreefold site is favored with the parallel frequencies (the frequencies of O atom paralleling the metal surface) of 342 and 538 $cm^{-1}$, and perpendicular frequency (the frequency of O atom perpendicular to the metal surface) at 526 $cm^{-1}$. On Cr (111), the most favored mode for O atom is found to be the quasi-threefold site with the perpendicular frequency at 553 $cm^{-1}$ and the parallel frequencies at 253 and 399 $cm^{-1}$. According to our calculation results, we speculate the most preferred mode for O adsorption on Cr (211) surface is the quasithreefold site with the perpendicular frequency at 583 $cm^{-1}$ and the parallel frequencies at 449 and 185 $cm^{-1}$.

Study on Analysis of Vibration Characteristics and Modal Test for a Quad-Rotor Drone (쿼드로터형 드론의 진동특성 분석 및 실험에 관한 연구)

  • Kim, Minsong;Kim, Jaenam;Byun, Youngseop;Kim, Jeong;Kang, Beomsoo
    • Journal of the Korean Society for Precision Engineering
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    • v.33 no.9
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    • pp.707-714
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    • 2016
  • This paper describes analysis results of vibration characteristics and modal test for a small-scale quad-rotor drone. The rotor arm has a slender body with a propeller and motor at its tip. Rotor system generates excitation for an unbalanced mass. Therefore, the drone platform is involved in the possibility of resonance. For advance identification of the possibility of resonance, confirmation of eigen-mode being closest to the propeller operation range is necessary. Material properties of CFRP tubes used for the rotor arm were acquired by finding the natural frequency based on Rayleigh method. A simplified quad-rotor FE model consisting of rotor arm assembly with tip mass was built to perform numerical analysis, and a free-free boundary condition was applied to provide flight status. Modal tests for the actual platform with impact hammer instrument were performed to verify analysis results. Separation margin from hazardous eigen-mode was checked on the propeller operation range.

Vibration Analysis of Stiffened Corrugated Composite Plates (보강된 적층 복합재료 주름판의 진동해석)

  • Park, Kyung-Jo;Kim, Young-Wann
    • Composites Research
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    • v.33 no.6
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    • pp.377-382
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    • 2020
  • The free vibration characteristics of corrugated laminated composite plates with axial stiffeners is investigated using the Rayleigh-Ritz method. The plate is stiffened by beams with open cross-section area. The equivalent homogenization model is used for the corrugated laminated composite plates. This homogenization model is treated a corrugated plate as an orthotropic plate that has different material properties in two perpendicular directions. The motion of equivalent plate is represented on the basis of the first order shear deformation theory (FSDT) to account for the effect of rotary inertia and transverse shear deformation. Stiffeners are considered as discrete elements to predict the local vibration mode to be generated by the presence of stiffeners. To validate the proposed analytical approach, natural frequencies and vibration mode shapes from the analytical method are compared with those from the FEA by ANSYS.

Analysis of Seismic Response by the Movement of the Plane Rotation Axis and the Core of Atypical Structures (비정형 구조물의 평면 회전축과 코어의 이동에 따른 지진응답분석)

  • Lee, Da-Hye;Kim, Hyun-Su;Kang, Joo-Won
    • Journal of Korean Association for Spatial Structures
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    • v.22 no.1
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    • pp.33-40
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    • 2022
  • When the center of stiffness and the center of mass of the structure differ under the seismic load, torsion is caused by eccentricity. In this study, an analysis model was modeled in which the positions of the core and the plane rotation axis of a 60-story torsional atypical structure with a plane rotation angle of 1 degree per floor were different. The structural behavior of the analysis model was analyzed, and the earthquake response behavior of the structure was analyzed based on the time history analysis results. As a result, as the eccentricity of the structure increased, the eccentricity response was amplified in the high-rise part, and the bending and torsional behavior responses were complex in the low-order vibration mode. As a result of the analysis, the maximum displacement and story drift ratio increased due to the torsional behavior. The maximum story shear force and the story absolute maximum acceleration showed similarities for each analysis model according to the shape of the vibration mode of the analysis model.

Image-based characterization of internal erosion around pipe in earth dam

  • Dong-Ju Kim;Samuel OIamide Aregbesola;Jong-Sub Lee;Hunhee Cho;Yong-Hoon Byun
    • Computers and Concrete
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    • v.33 no.5
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    • pp.481-496
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    • 2024
  • Internal erosion around pipes can lead to the failure of earth dams through various mechanisms. This study investigates the displacement patterns in earth dam models under three different failure modes due to internal erosion, using digital image correlation (DIC) methods. Three failure modes—erosion along a pipe (FM1), pipe leakage leading to soil erosion (FM2), and erosion in a pipe due to defects (FM3)—are analyzed using two- and three-dimensional image- processing techniques. The internal displacement of the cross-sectional area and the surface displacement of the downstream slope in the dam models are monitored using an image acquisition system. Physical model tests reveal that FM1 exhibits significant displacement on the upper surface of the downstream slope, FM2 shows focused displacement around the pipe defect, and FM3 demonstrates increased displacement on the upstream slope. The variations in internal and surface displacements with time depend on the segmented area and failure mode. Analyzing the relationships between internal and surface displacements using Pearson correlation coefficients reveals various displacement patterns for the segmented areas and failure modes. Therefore, the image-based characterization methods presented in this study may be useful for analyzing the displacement distribution and behavior of earth dams around pipes, and further, for understanding and predicting their failure mechanisms.

Effectiveness of multi-mode surface wave inversion in shallow engineering site investigations (토목관련 천부층 조사에서 다중 모드 표면파 역산의 효과)

  • Feng Shaokong;Sugiyama Takeshi;Yamanaka Hiroaki
    • Geophysics and Geophysical Exploration
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    • v.8 no.1
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    • pp.26-33
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    • 2005
  • Inversion of multi-mode surface-wave phase velocity for shallow engineering site investigation has received much attention in recent years. A sensitivity analysis and inversion of both synthetic and field data demonstrates the greater effectiveness of this method over employing the fundamental mode alone. Perturbation of thickness and shear-wave velocity parameters in multi-modal Rayleigh wave phase velocities revealed that the sensitivities of higher modes: (a) concentrate in different frequency bands, and (b) are greater than the fundamental mode for deeper parameters. These observations suggest that multi-mode phase velocity inversion can provide better parameter discrimination and imaging of deep structure, especially with a velocity reversal, than can inversion of fundamental mode data alone. An inversion of the theoretical phase velocities in a model with a low velocity layer at 20 m depth can only image the soft layer when the first higher mode is incorporated. This is especially important when the lowest measurable frequency is only 6 Hz. Field tests were conducted at sites surveyed by borehole and PS logging. At the first site, an array microtremor survey, often used for deep geological surveying in Japan, was used to survey the soil down to 35 m depth. At the second site, linear multichannel spreads with a sledgehammer source were recorded, for an investigation down to 12 m depth. The f-k power spectrum method was applied for dispersion analysis, and velocities up to the second higher mode were observed in each test. The multi-mode inversion results agree well with PS logs, but models estimated from the fundamental mode alone show f large underestimation of the depth to shallow soft layers below artificial fill.

Fast Inter Block Mode Decision Using Image Complexity in H.264/AVC (H.264/AVC에서 영상 복잡도를 이용한 고속 인터 블록 모드 결정)

  • Kim, Seong-Hee;Oh, Jeong-Su
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.33 no.11C
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    • pp.925-931
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    • 2008
  • In video coding standard H.264/AVC, variable block size mode algorithm improves compression efficiency but has need of a large amount of computation for various block modes and mode decision. Meanwhile, decided inter block modes depend on the complexity of a block image, and then the more complex a macroblock is, the smaller its block size is. This paper proposes fast inter block mode decision algorithm. It limits valid block modes to the block modes with a great chance for decision using the image complexity and carries out motion estimation rate-distortion optimization with only the valid block modes. In addition to that, it applies fast motion estimation PDE to the valid block modes with only the $16{\times}16$ block mode. The reference software JM 9.5 was executed to estimate the proposed algorithm's performance. The simulation results showed that the proposed algorithm could save about 24.12% of the averaged motion estimation time while keeping the image quality and the bit rate to be -0.02dB and -0.12% on the average, respectively.

Effects of GMA Welding Conditions on the Bead Shape of Hardfacing Overlay Welding (하드페이싱 오버레이용접 비드형상에 미치는 GMA 용접조건의 영향)

  • Han, Kyu-Ho;Kim, Jun-Ki;Kim, Cheol-Hee;Kim, Jeong-Han;Nam, See-Hwan;Jeon, Chi-Jung
    • Journal of Welding and Joining
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    • v.25 no.5
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    • pp.58-63
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    • 2007
  • The relationship between GMA welding conditions and the bead shape of overlay weld was studied by using ${\Phi}1.6mm$ hypo-eutectic metal-cored wire designed for hardfacing against the severe metal-to-metal wear. As the welding voltage increased, the dilution also increased but the sudden drop of dilution was observed at $30{\sim}33V$. It was considered to be due to the decrease of penetration resulting from the change of transfer mode, from short circuit to spray. It was also found that the behavior of penetration with welding current was dependant on the transfer mode. The short circuit mode exerted the penetration to decrease while the spray mode did it to increase with increase of welding current. The former was considered to be responsible for the remarkable decrease in dilution at low welding voltage region. The change of transfer mode also had an effect on the behavior of bead width with welding current but it did not on the bead spreadability defined as W/H ratio. It was considered that the optimal welding conditions for multi-pass overlay welding could be obtained from the bead spreadability suitable for bead lapping and the dilution as low as possible in the spray transfer mode.