• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3771-3776
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• 2010

The dynamics of the $CN^-$-ligated ferric cytochrome c (CytcCN) in $D_2O$ at 283 K following Q-band photoexcitation at 575 nm was observed using femtosecond time-resolved vibrational spectroscopy. The equilibrium vibrational spectrum of the CN stretching mode of CytcCN shows two overlapping bands: one main band (82%) at $2122\;cm^{-1}$ with $23\;cm^{-1}$ full width at half maximum (fwhm) and the other band (18%) at $2116\;cm^{-1}$ with $7\;cm^{-1}$ fwhm. The time-resolved spectra show bleaching of the CN fundamental mode of CytcCN and two absorption features at lower energies. The bleach signal and both absorption features are all formed within the time resolution of the experiment (< 200 fs) and decay with a life time of 1.9 ps. One transient absorption feature, appearing immediately red to the bleach signal, results from the thermal excitation of low-frequency modes of the heme that anharmonically couple to the CN fundamental mode, thereby shifting the CN mode to lower energies. The shift of the CN mode decays with a lifetime of 2 ps, equivalent to the time scale for vibrational cooling of the low-frequency heme modes. The other transient absorption feature, which is 3.3 times weaker than the bleach signal and shifted $27\;cm^{-1}$ toward lower energies, is attributed to the CN mode in an electronically excited state where the CN bond is weakened with a lowered extinction coefficient. These observations suggest that photoexcited CytcCN mainly undergoes ultrafast radiationless relaxation, causing photo-deligation of $CN^-$ from CytcCN highly inefficient. As also observed in $CN^-$-ligated myoglobin, inefficient ligand photodissociation might be a general property of $CN^-$-ligated ferric hemes.

• 소성∙가공
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• 제31권1호
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• pp.29-38
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• 2022

Recently, the composite material market is gradually growing. Various composite forming processes have been developed in order to reduce the production cost of the composite material. Unlike the conventional forming process, the microwave composite forming process has the advantage of reducing the processing time because the composite material is heated directly or indirectly at the same time. Due to this advantage, in this study, a double cantilever beam test was conducted with specimens manufactured by the microwave composite forming process. The purpose of this study was to compare mode-I energy release rate for specimens manufactured by prepreg compression forming and microwave composite forming processes. First, a microwave oven was proposed to conduct the microwave composite forming process. Double cantilever beam specimens were manufactured. After that, the double cantilever beam test was conducted to obtain the mode-I energy release rate. Mode-I energy release rates of specimens manufactured by the microwave composite forming and prepreg compression forming processes were then compared. As a result, mode-I energy release rates of specimens fabricated by the microwave composite forming process were similar to those fabricated with the prepreg compression forming process with a relatively reduced process time.

• Ocean Systems Engineering
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• 제2권1호
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• pp.17-31
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• 2012

This study investigated the behavior of a non-isothermal $CO_2$ bubble formed through a leak process from a high-pressure source in a deep sea. Isenthalpic interpretation was employed to predict the state of the bubble just after the leak. Three modes of mass loss from the rising bubble were demonstrated: dissolution induced by mass transfer, condensation by heat transfer and phase separation by pressure decrease. A graphical interpretation of the last mode was provided in the pressure-enthalpy diagram. A threshold pressure (17.12 bar) was identified below which the last mode was no longer present. The second mode was as effective as the first for a bubble formed in deep water, leading to faster mass loss. To the contrary, only the first mode was active for a bubble formed in a shallow region. The third mode was insignificant for all cases.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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• pp.223-224
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• 2006

This paper present a new disk-type piezoelectric transformer. The input side of the transformer has a crescent-shaped electrode and the output side has a focused poling direction. This transformer has multi-layered structure. The piezoelectric transformers operated m each transformer's resonance vibration mode. The electrodes and poling directions on commercialy available piezoelectric ceramic disks were designed so that the planar or shear mode coupling factor ($k_p,\;k_{15}$) becomes effective rather than the transverse mode coupling factor ($k_{31}$). The Resonance frequency is 65.22[kHz] and maximum voltage step-up ratio is 149. Multi-layered transformer has better efficiency and step-up ratio than the single-layered transformer.

• International Journal of Aeronautical and Space Sciences
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• 제8권1호
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• pp.21-31
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• 2007

Relaxed Static Stability (RSS) concept has been applied to improve aerodynamic performance of modern version supersonic jet fighter aircraft. The T-50 advanced supersonic trainer employs the RSS concept in order to improve the aerodynamic performance. And the flight control system stabilizes the unstable aircraft and provides adequate handling qualities. The T-50 longitudinal control laws employ a proportional-plus-integral type controller based on a dynamic inversion method. The longitudinal dynamic modes consist of short period with high frequency and phugoid mode with low frequency. The design goal of longitudinal control law is optimization of short period damping ratio and frequency using Lower Order Equivalent System (LOES) complying the requirement of MIL-F-8785C. This paper addresses phugoid mode characteristics such as damping ratio and natural frequency that is affected by the nonlinear control laws such as angle of attack limiter, auto pitch attitude command system and autopilot of pitch attitude hold.

• JSTS:Journal of Semiconductor Technology and Science
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• 제3권4호
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• pp.188-193
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• 2003

This paper describes a novel burst-mode clock and data recovery (CDR) circuit which can be used for 622Mbps burst mode applications. The CDR circuit is basically a phase locked loop (PLL) having two phase detectors (PDs), one for the reference clock and the other for the NRZ data, whose operations are controlled by an external control signal. This CDR was fabricated in a 1-poly 5-metal $0.25{\;}\mu\textrm{m}$ CMOS technology. Jitter generation, burst/continuous mode data receptions were tested. Operational frequency range is 320Mhz~720Mhz and BER is less than 1e-12 for PRBS31 at 622Mhz. For the same data sequence, the extracted clock jitter is less than 8ps rms. Power consumption of 100mW was measured without I/O circuits.

• 한국전기전자재료학회논문지
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• 제13권4호
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• pp.332-336
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• 2000

We have developed a novel vertical-alignment(VA) -$\pi$ cell mode that provides a wide viewing angle and fast response times for nematic liquid crystal(NLC) with negative dielectric anisotropy on a homeotropic polymide(PI) surfaces. Good voltage-transmittance curves and low driving voltages were achieved with the new VA-$\pi$ cell mode without a negative compensation film. Iso-viewing angle characteristics using the new VA-$\pi$ cell mode without a negative compensation film was also successfully observed. As well a fast response time of 31.7 ms for a new VA-$\pi$ mode was measured. Consequently the iso-viewing angel fast response time and low driving voltage characteristics using a VA-$\pi$ cell can be achieved.

• 전자공학회논문지B
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• 제31B권8호
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• pp.109-118
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• 1994

We proposed new field/frame mode selection quantization and buffer control strategy for interlaced digital HDTV image coding system. The field/frame mode selection is performed based on the mean square error and number of generated bits for each superblock. The quantization factor for each superblock is determined by the characteristics of human visual system and buffer status. The statistical characteristics of the number of generated bits for basis block and the prediction of buffer status are used for buffer control. Simulation results show that the proposed field/frame mode selection and rate buffer control. Simulation results show that the proposed field/frame mode selection and rate buffer control strategy have good subjective image quality and have stable buffer status.

• 천문학회보
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• 제31권1호
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• pp.34.1-34.1
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• 2006

• 한국통신학회논문지
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• 제31권8A호
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• pp.790-797
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• 2006

IEEE 802.16e 표준은 sleep 모드와 idle 모드의 두 저전력 모드를(power saving mode: PSM) 정의하고 있다. 이들은 모드 천이시 단말과 망간 상태 정보 유지 여부에 따라 소모 전력 측면에서 성능이 달라진다. 따라서 802.16e 단말의 전력 소모 최적화를 위해서는 각 기법의 성능에 영향을 주는 요소들을 모두 고려한 상세한 성능분석이 필요하다. 본 논문에서는 단말의 이동성과 호 사용 빈도를 고려하여 소모 전력 측면에서 두 PSM의 성능분석 모델을 제안하고, idle 모드가 전력 소모 측면에서 sleep 모드보다 우수하다는 것을 보인다. 또한 분석 결과와 모의실험과의 비교를 통해 제안한 분석 모델의 타당성을 검증하였다.