• Title/Summary/Keyword: 3.5 % NaCl solution

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Phytochemical-based Tannic Acid Derivatives as Draw Solutes for Forward Osmosis Process (정삼투 공정의 유도용질로서의 식물 화학물질 기반의 탄닌산 유도체)

  • Kim, Taehyung;Ju, Changha;Kang, Hyo
    • Membrane Journal
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    • v.28 no.3
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    • pp.157-168
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    • 2018
  • Potassium tannate (TA-K), which is prepared by base treatment of the bio-renewable tannic acid (TA), was evaluated for its potential application as a draw solute for water purification by forward osmosis. The forward osmosis and recovery properties of TA-K were systematically investigated. In the application of forward osmosis through the active layer facing feed solution (AL-FS) method, the water flux of TA-K draw solution was significantly higher than that of the TA draw solution, while that of the latter was not identified. At a low concentration of 100 mM, the osmotic pressure (1,135 mOsmol/kg) of the TA-K draw solution was approximately 6.5 times that (173 mOsmol/kg) of the NaCl draw solution. Furthermore, the water flux and specific salt flux (6.14 LMH, 1.26 g/L) of the TA-K draw solution at 100 mM were approximately 2.5 and 0.5 times those of the NaCl draw solution (2.46 LMH, 2.63 g/L) at the same concentration, respectively. For reuse, TA-K was precipitated by using a metal ion and recovered through membrane filtration. This study demonstrates the applicability of a phytochemical material as a draw solute for forward osmosis.

Effect of Hydrodynamic Condition on the Electrochemical Behavior of Various Metals in 3.5 wt% NaCl Solution

  • Pan, Szu-Jung;Hadinata, Samuel-Sudibyo;Kao, Ruey-Chy;Tsai, Wen-Ta
    • Corrosion Science and Technology
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    • v.14 no.5
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    • pp.218-225
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    • 2015
  • The electrochemical behaviors of various metals with and without diamond-like-carbon (DLC) coating in 3.5 wt% NaCl solution were investigated. The effect of hydrodynamic conditions was focused by employing a rotating disc electrode (RDE). The experimental results showed that each bare metal had a more positive corrosion potential and a higher corrosion rate due to enhanced oxygen transport at the higher rotating speed of the RDE. DLC coating caused a substantial increase in the corrosion resistance of all metals studied. However, localized corrosion was still found in the DLC-coated metal at sites where deposition defects existed. Surface morphology examination was performed after the electrochemical test to confirm the roles of hydrodynamic conditions and DLC coating.

Effects of Salinity and Temperature on the Survival of Vibrio vulnificus (염도와 수온의 변화가 Vibrio vulnificus의 생존에 미치는 영향)

  • KIM Young-Man;KWON Ji-Young
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.3
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    • pp.367-376
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    • 1997
  • Vibrio vulnificus is a gram-negative, halophilic, oxidase-positive, lactose-positive, motile, rod shaped bacterium that has been associated with primary septicemia and wound infection. Elucidating the growth and survival of V. vulnificus in ecological conditions is of great importance to develop sanitary measure against this microorganism. Thus we simulated the ecological conditions and evaluated the effect. About $10^5\;CFU/ml$ of V. vulnificus was inoculated to fresh water, brackish water $(1\%\;NaCl)$, sea water $(3\%\;NaCl)$, and bottom deposit solution. The same concentration of V. vulnificus was also inoculated to distilled water, $1\%\;NaCl$ solution and $3\%\;NaCl$ solution as controls. These were stored at 4, 15 and $25^{\circ}C$, respectively and were used to assess the effects of temperature and salinity on the survival of V. vulnificus. In fresh water V. vulnificus could not survive regardless of storage temperature. In case of brackish water and sea water survival time of V. vulnificus was the longest at $25^{\circ}C$, and the number of V. vulnificus was decreased most rapidly at $4^{\circ}C$. V. vulnificus survived longer in brackish water than in any other conditions. In bottom deposit solution containing brackish water, the survival time of V. vulnificus was longer and the rate of decline was slower than that in brackish water. These results indicate that both biological and physicochemical factors such as temperature and salinity could affect survival of V. vulnificus. V. vulnificus, damaged in normal fresh water, did not grow on TCBS agar of selective plating medium but grew on BHI agar plate; However, V. vulnificus was recovered by addition of salt and nutrient materials.

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Development of Combined Method for Extraction of Sea Tangle (다시마의 효과적 추출을 위한 종합적인 추출방법의 개발)

  • Kim, Woo-Jung;Lee, Jung-Kun;Chang, Young-Sang
    • Korean Journal of Food Science and Technology
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    • v.26 no.1
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    • pp.51-56
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    • 1994
  • Development for extraction method of sea tangle was investigated with addition of sucrose, NaCl, EDTA-2Na, SHMP, and hydrolysis with commercial polysaccharide hydrolyzing enzymes. The total solids and protein yields were significantly increased by enzymatic hydrolysis or addition of NaCl and EDTA-2Na during boiling. The extract prepared by enzymatic hydrolysis followed by 2 hrs of boiling in 1.5% NaCl solution was significantly improved in solids and protein yield from 24.1% and 13.9% of 2 hrs of water boiling to 44.6% and 32.2%, respectively. The combined method increased the amino-nitrogen content but reduced the turbidity and viscosity. Extracts with a high intensity of total and seaweed-like taste as revealed by sensory evalution were obtained by combined method.

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The Influence of the Changing of Cyclic Frequency on the Corrosion Fatigue Fracture Behavior of the Dual Phase Steel in 3% NaCl Solution (3% NaCl 수용액중에서 복합조직강의 부식피로 파괴거동에 미치는 주파수변화의 영향)

  • O, Se-Uk;Sin, Gyu-Dong;Kim, Ung-Jip
    • Journal of Ocean Engineering and Technology
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    • v.9 no.2
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    • pp.141-148
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    • 1995
  • Fatigue tests were carried out by a rotary bending testing machine of cantilever type. M.E.F.(ferrite encapsulated islands of martensite) materials were made by a series of heat treatment from a low carbon steel(SM 20 C). The fatigue tests were conducted at stress levels of 302 MPa and with frequencies of 25Hz, 2.5 Hz and 0.5 Hz in 3% NaCl solution. The fatigue strength increased with frequency got higher. The microcracks and corrosion pits were generated at the boundary between the matrix and the 2nd phase. The cracks generated by the corrosion pits were coalesced with the pits around the notch and became the initial crack. The $N_i/N_f$ ratio increased as the frequency and stress level decreased. The interference phenomenon increased with stress level and frequency gots higher. The crack propagation rate was delayed as the stress level lowers and the frequency gets higher, however, the range of the stress intensity factor depended only on a stress level.

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Short-term Preservation of Sperm in the Tiger Puffer, Takifugu rubripes (자주복(Takifugu rrbripes) 정자의 액상보존)

  • 장영진;장윤정;임한규
    • Journal of Aquaculture
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    • v.10 no.3
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    • pp.273-279
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    • 1997
  • Condition for fresh storage of tiger puffer in the liquid state were investigated in several experiments. When marine fish ringer solution and 1% NaCl were used as the diluent for the short-term preservation method, spermatozoa activity index (SAI) and survival rate showed the best result among the various diluents tested. The dilution rate for the shortterm preservation of spermatozoa was suitable between 3 and 5 times with the 1% NaCi diluent. The appropriate range of temperature for the short-term preservation showed between 0 and $5^{\circ}C$. In order to keep high SAI and survival rate of spermatozoa, antibiotic addition (800 ppm neomycin) could be suggested. These results indicated that the short-term preservation method could be employed in tiger puffer spermatozoa.

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Effect of microwave heating and salts addition on pH and acidity of Kakdugi during fermentation (깍뚜기 발효중 순간 가열과 염첨가가 pH변화에 미치는 영향)

  • Yun, Jung-Won;Kim, Jong-Koon;Lee, Jung-Kun;Kim, Woo-Jung
    • Applied Biological Chemistry
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    • v.34 no.3
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    • pp.213-218
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    • 1991
  • Addition of salts or their mixtures and microwave heating were studies for their effects on Kakdugi fermentation. The Kakdugi, a Korean fermented Chinese radish, were prepared by salting in 15% NaCl solution and fermented at $25^{\circ}C$. From the results, a first order reaction relationship was found between salt permeated into the radish and time during brining in $5{\sim}10%$ NaCl solution. Addition of 0.05M KCl into 15% NaCl brining solution or microwave heating of salted radish for 3 minutes showed a little decreasing effect on Kakdugi fermentation rate while beating for 1 or 2 minuted resulted a rather increase. When three different salt mixtures in the concentration range of $0.001{\sim}0.01\;M$ were added into half fermented Kakdugi(appr. pH 4.4), the fermentation was greatly controlled based on pH change. Among the salt mixtures, mixture III$(Na_2HPO_4,\;Na_2PO_4,\;NaNO_2,\;Ca\;EDTA,\;Sod.\;citrate)$ showed a most significant effect where the time required to reach pH 4.0 after addition was extended by more than 6 folds when it was compared to the control method.

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Effect of Salt on the Formation of $\alpha$-Calcium Sulfate Hemihydrate from by-Product Gypsum of Phosphoric Acid Process in Aqueous Salt Solution at Atmospheric Pressure (상압수용액중에서 인산석고로부터 $\alpha$형 반수석고의 생성에 미치는 염류의 영향)

  • 이구종;최상흘
    • Journal of the Korean Ceramic Society
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    • v.25 no.1
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    • pp.66-72
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    • 1988
  • The effect of salts on the formation of ${\alpha}$-hemihydrated gypsum at boiling temperature under atmospheric pressure was studied by the solubility measurement method, and the formation of ${\alpha}$-hemihydrated gypsum from by-product gypsum of phosphoric acid process in the salts solution were investigated. The order of catalytic effect of salt on the formation of ${\alpha}$-hemihydrated gypsum are as follows: NH4Cl>NaCl>NaNO3. In the salts solution of sodium nitrate, sodium chloride, and ammonium chloride, prismatic ${\alpha}$-hemihydrated gypsum was obtained and the crystal form was converted to needle form in complex solution with sulfuric acid. The P2O5 content in gypsum was largely decreased in this atmosphoric solution process.

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Gas Sensing Characteristics and Preparation of SnO2 Nano Powders (SnO2 나노 분말의 합성 및 가스 감응 특성)

  • Lee, Ji-Young;Yu, Yoon-Sic;Yu, Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.7
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    • pp.589-593
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    • 2011
  • [ $SnO_2$ ]nano powders were prepared by solution reduction method using tin chloride($SnCl_2{\cdot}2H_2O$), hydrazine($N_2H_4$) and NaOH. The $SnO_2$ thick films for gas sensors were fabricated by screen printing method on alumina substrates and annealed at $300^{\circ}C$ in air, respectively. XRD patterns of the $SnO_2$ nano powders showed the tetragonal structure with (110) dominant orientation. The particle size of $SnO_2$ nano powders at the ratio of $SnCl_2:N_2H_4$+NaOH= 1:6 was about 60 nm. The sensing characteristics were investigated by measuring the electrical resistance of each sensor in a test box. Sensitivity of $SnO_2$ gas sensor to 5 ppm $CH_4$gas and 5 ppm $CH_3CH_2CH_3$ gas was investigated for various $SnCl_2:N_2H_4$+NaOH proportion. The highest sensitivity to $CH_4$ gas and $CH_3CH_2CH_3$ gas of $SnO_2$ sensors was observed at the $SnCl_2:N_2H_4$+NaOH= 1:8 and $SnCl_2:N_2H_4$+NaOH= 1:6, respectively. Response and recovery times of $SnO_2$ gas sensors prepared by $SnCl_2:N_2H_4$+NaOH= 1:6 was about 40 s and 30 s, respectively.

Corrosive Characterisics of 12Cr Alloy Steel and Fatigue Characteristics of the Artificially Degraded 12Cr Alloy Steel (고온의 인공해수 중 12Cr강의 부식피로특성에 관한 연구)

  • Jo, Seon-Yeong;Kim, Cheol-Han;Bae, Dong-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.5
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    • pp.772-778
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    • 2001
  • In this study, corrosion fatigue characteristics of 12Cr alloy steel were investigated in 3.5wt.% NaCl solution of 150$^{\circ}C$ and 4.5bar. Behavior of corrosion fatigue cracks was measured by the indirect compliance method and compared with the results in distilled water and in air. 1) 12Cr alloy steel was susceptible to temperature. Its susceptibility was increased as the temperature was increased. 2) The crack growth characteristics of 12Cr alloy steel in distilled water were similar to 3.5wt.% NaCl solution. 3) The temperature of solution affects to the crack growth characteristics of 12Cr alloy steel. In corrosion solutions of 4.5bar, 150$^{\circ}C$, fracture surfaces of corrosion fatigue crack growth at a/W=0.3 was showed the trans-granular fracture suface. As the crack grew up, it was changed to inter-granular type. In condition of high temperature, The crack growth behaviors of 12Cr alloy steel were remarkable.