• Computers and Concrete
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• v.33 no.6
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• pp.659-670
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• 2024

The mechanical behaviour of layered concrete samples containing an internal crack was numerically studied by modelling the geo-mechanical specimens in the particle flow code in two dimensions (PFC2D). The numerical modelling software was calibrated with the experimental results of the Brazilian tensile strengths gained from the laboratory disc-type specimens. Then, the samples with the bedding layers and internal notch were numerically simulated with PFC2D under uniaxial compressive loading. In each specimen, the layers' thickness was 10 mm but the layer's inclination angle was changed to 0°, 30°, 60°, 90°, 120° and 150°. Of course, the layers'interfaces are considered to have very low strengths. The internal notch was kept at 3 cm in length however, its inclination angle was changed to 0°, 40°, 60° and 90°. Therefore, a total, of 24 numerical models were made to study the failure mechanism of the layered concrete samples. Considering these results, it has been concluded that the inclination angles of both internal crack and bedding layers affect the failure mechanism and uniaxial compressive strength of the concrete.

• Journal of Environmental Science International
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• v.14 no.7
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• pp.711-717
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• 2005

A magenta azomethine dye(D) was synthesized from the reaction of 3-methyl-1-phenyl-2-pyrazoline-5-one with N,N-diethyl-1,4-phenylenediamine. The magenta azomethine dye was identified on the basis of elemental analysis, $^{13}C-NMR$, infrared, and GC/MS studies. The magenta azomethine dye was decomposed in a basic solution. Rate constants of the fading reaction of magenta azomethine dye in ethanol-water solvent were measured spectrophoto­metrically at 540 nm. Reaction rate was increased with the increase of $[OH\^{-}]\;and\;[H\_{2}O]$ in the region of $[H_{2}O]=11\~40\;M$. The reaction was governed by the following rate law. -d[D]/dt = $\{k_o\;+\;k_{OH}[OH^-][H_{2O}]\}[D]$ A possible mechanism consistent with the empirical rate law has been proposed.

• The Korean Journal of Ceramics
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• v.5 no.1
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• pp.40-43
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• 1999

In order to investigate Sn substitution sites and interstitial O atoms in tin-doped indium oxide, molecular dynamics (MD) simulations were carried out. There are two kinds of cation sites in $In_2O_3$, namely b-site and d-site. NTP-MD simulations under the condition of 300 K and 0 GPa were performed with two kinds of cells substituted by Sn atoms at each site. The excess oxygen atom accompanied with Sn doping was also taken into consideration. According to the calculations of Sn potential energies in each site, it was revealed that Sn atoms were substituted for b-sites rather than for d-sites. It was also revealed that the interstitial excess oxygen atoms tend to be connected with the Sn atoms substituted for the d-sites Sn rather than for the b-site. There MD simulation results well agreed with the experimental results.

• Journal of KIISE:Information Networking
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• v.36 no.3
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• pp.256-262
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• 2009

In this paper, we propose a mechanism for increasing the handover performance of the IEEE 802.11 link layer. The mechanism reduces the number of scanning channels by referencing an AP map based on GPS. Also, by monitoring the SNRs of the mobile node and neighbor APs, it enables the handover to maintain a higher SNR than a given threshold. The experimental results establish that it has a disconnection ratio of 6.7% and an average SNR of 16.8 dB. It is 4.1% lower disconnection ratio and 26% higher SNR than the mechanism used by MadWifi.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2000.11a
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• pp.551-554
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• 2000

Alignment system is a system to locate an object to it's accurate position in multi-d.o.f space. According to process of application, it is need to align an object in 3 or 6 d.o.f. space. And alignment system is used in various environments. Especially in PDP application, alignment process is carried out in vaccume environment. In this paper, we developed 3 d.o.f. alignment system for vaccume environment, performed kinematic analysis and improved it's positional accuracy.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.6
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• pp.1690-1695
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• 2008

The 3D virtual reality digital recovery technique is a new type in protecting and displaying remains and cultural relics through which the information of cultural relics can easily be known anytime and any where. The dissertation focuses on the study of the contradiction between quality and loading speed.

• Journal of Korea Foundry Society
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• v.8 no.3
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• pp.287-295
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• 1988

The experiment was carried out for the purpose of studying the carburization of pure iron ingot and sintered iron powder by solid carbon in the atmosphere of CO gas. The volocity of carburization was estimaed by the diffusion coefficient D calculated by carburization equation. The results obtained were as follow: 1. The higher the carburization temperature, carburization depth and carbon concentration were increased, and the melting zone which had $2.8{\sim}3.4%C$ at the $3{\sim}4mm$ from interface of carburization was formed at $1300^{\circ}C$. 2. The main carburization mechanism of pure iron ingot and the sintered iron powder were proceeded by CO gas up to $1100^{\circ}C$, solid carbon over than $1300^{\circ}C$, respectively. 3. The main carburization mechanism of pure iron ingot at $1200^{\circ}C$ was proceeded by solid carbon, and sintered iron powder was proceeded bs CO gas, however, in case the reaction time, the carburization was proceeded by solid carbon over than 5hrs. 4. The diffusion coefficient D of carbon were $0.559{\times}10^{-6}cm^2.sec^{-1}$ at $1100^{\circ}C$, $0.237{\times}10^{-6}cm^2.sec^{-1}$ at $1200^{\circ}C$, $0.087{\times}10^{-6}cm^2.sec^{-1}$ at $1300^{\circ}C$, in case of pure iron ingot carburized. 5. The diffusion coefficient D of carbon were $0.124\;cm^2.sec^{-1}$ at $1100^{\circ}C$, $0.102\;cm^2.sec^{-1}$ at $1200^{\circ}C$, $0.480\;{\times}10^{-6}cm^2.sec^{-1}$ at $1300^{\circ}C$, in the case of sintered iron carburized at the pressuring $4ton\;/\;cm^2$.

• Bulletin of the Korean Chemical Society
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• v.33 no.3
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• pp.843-847
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• 2012

The nucleophilic substitution reactions of dibutyl chlorothiophosphate (4S) with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at $55.0^{\circ}C$. The obtained deuterium kinetic isotope effects (DKIEs;$k_H/k_D$) are primary normal ($k_H/k_D$ = 1.10-1.35). A concerted mechanism involving predominant frontside nucleophilic attack is proposed on the basis of the primary normal DKIEs and selectivity parameters. Hydrogen bonded, four-center-type transition state is proposed. The steric effects of the two ligands on the anilinolysis rates of the chlorothiophosphates are discussed. The anilinolyses of P=S systems are compared with those of their P=O counterparts on the basis of the reactivities, thio effects, selectivity parameters, and DKIEs.

• Bulletin of the Korean Chemical Society
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• v.32 no.9
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• pp.3245-3250
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• 2011

The nucleophilic substitution reactions of diisopropyl chlorophosphate (3) with substituted anilines ($XC_6H_4NH_2$) and deuterated anilines ($XC_6H_4ND_2$) are investigated kinetically in acetonitrile at $55.0^{\circ}C$. The anilinolysis rate of 3 is rather slow to be rationalized by the conventional stereoelectronic effects. The obtained deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are secondary inverse ($k_H/k_D$ = 0.71-0.95) with maximum magnitude at X = H.A concerted mechanism involving predominant backside nucleophilic attack is proposed on the basis of the secondary inverse DKIEs.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.26 no.7
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• pp.84-91
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• 2012

In this paper, design by magnetic analysis software and proportional control of solenoid for pressure valve for electric pressure cooker is described. The validation of design was proved by 3D finite element analysis results. Also the efficiency of an air ventilation mechanism was considered when pressure was happened by fluid analysis results. The linear proportional control system by AVR was manufactured and its validation was proved by pressure control of solenoid.