• Title/Summary/Keyword: 3 electrode-type

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Deposition of Uranium Ions with Modified Pyrrole Polymer Film Electrode (우라늄이온 포집을 위한 수식된 피를 고분자 피막전극)

  • Cha Seong-Keuck;Lee Sang Bong
    • Journal of the Korean Electrochemical Society
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    • v.3 no.3
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    • pp.141-145
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    • 2000
  • Anodically Polymerized conducting Polypyrrole film electrode was employed to Pick up uranyl ion with the type of Gr/ppy, xylenol orange modified electrode. To have Porous and oriented ppy film, NBR was applied as precoating agent. The rate constant of polymerization was $3.22\times10^{-3}s^{-1}$ which was 1.6 times smaller value than bare graphite surface. The deposited amount of uranyl iou on $1.70Ccm^{-2}$ of ppy was $1.55\times10^{-4}g$. The matrix effect in artificial seawater was $6.8\%$. The polymer film electrode has a diffusion controlled process in conduction, but the modified Gr/ppy, $X.O^{4-}UO^+$ type was influenced on the ion doping and electronic conduction of film itself owing to increasing of impedance. The capacitance of electrical double layer was respectively enhanced to 56 and 130 times in Gr/ppy, $X.O.^{4-}$ and Gr/ppy, $X.O^{4-}UO^+$ than Grippy type electrode.

Comparison of Dye Removal Performance of Direct and Indirect Oxidation Electrode (직접 산화와 간접 산화용 전극의 Dye 제거 성능 비교)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Korean Society on Water Environment
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    • v.26 no.6
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    • pp.963-968
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    • 2010
  • This study has carried out to evaluate the performance of direct and indirect oxidation electrode for the purpose of decolorization of Rhodamine B (RhB) in water. Four kinds of electrodes were used for comparison: Pt and JP202 (indirect oxidation electrode), Pb and boron doping diamond (BDD, direct oxidation electrode). The effect of applied current (0.5 ~ 2.5 A), electrolyte type (NaCl, KCl, HCl, $Na_2SO_4$ and $H_2SO_4$) and electrolyte concentration (0.5 ~ 2.5 g/L), solution pH (3 ~ 11) and initial RhB concentration (25 ~ 125 mg/L) were evaluated. Experimental results showed that RhB removal efficiency were increased with increase of current, NaCl dosage and decrease of the pH. However, the effect of operating parameter on the RhB removal were different with the electrode type. JP202 electrode was the best electrode from the point of view of performance and energy consumption. The order of removed RhB concentration per energy lie in: JP202>Pt>Pb>BDD.

A Study on the Preparation of the Dimensionally Stable Anode(DSA) with High Generation Rate of Oxidants(II) (산화제 생성율이 높은 촉매성 산화물 전극(DSA)의 개발에 관한 연구(II))

  • Park, Young-Seek;Kim, Dong-Seog
    • Journal of Environmental Science International
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    • v.18 no.1
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    • pp.61-72
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    • 2009
  • Fabrication and oxidants production of 3 or 4 components metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru as main component and Pt, Sn, Sb and Gd as minor components) were used for the 3 or 4 components electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at $500^{\circ}C$ for 1h. The removed RhB per 2 min and unit W of 3 components electrode was in the order: Ru:Sn:Sb=9:1:1 > Ru:Pt:Gd=5:5:1 > Ru:Sn=9:1 > Ru:Sn:Gd=9:1:1 > Ru:Sb:Gd=9:1:1. Although RhB decolorization of Ru:Sn:Sb:Gd electrode was the highest among the 4 components electrode, the RhB decolorization and oxidants formation of the Ru:Sn:Sb=9:1:1 electrode was higher than that of the 3 and 4 components electrode. Electrogenerated oxidants (free Cl and $ClO_2$) of chlorine type in 3 and 4 components electrode were higher than other oxidants such as $H_2O_2\;and\;O_3$. It was assumed that electrode with high RhB decolorization showed high oxidant generation and COD removal efficiency. OH radical which is electrogenerated by the direct electrolysis was not generated the entire 3 and 4 components electrode, therefore main mechanism of RhB degradation by metal oxide electrode based Ru was considered indirect electrolysis using electrogenerated oxidants.

Electrical Characteristics of 3rd Overtone Mode Energy-trapped High Frequency Filter using PbTiO3 System Ceramics (PbTiO3계 세라믹스를 이용한 3차 진동모드 에너지 트랩형 고주파필터의 전기적 특성)

  • 오동언;류주현;윤현상;박창엽;이수호;김종선;정회승
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.7
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    • pp.593-598
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    • 2003
  • In this paper, 3rd overtone mode energy-trapped filter using modified PbTiO$_3$ system ceramics was manufactured to apply for intermediate frequency(IF) SMD type fillet with splitted electrode and gap size. To investigate the effects of splitted electrode and gap size on filter characteristics of 3rd overtone mode energy-trapped filter, ceramic wafers were fabricated by etching splitted rectangular electrode size(b$\times$d) of b=0.4, 0.6, 0.8, 1mm, d=0.3, 0.4, 0.5, 0.6mm and gap size(c) c=0.2, 0.3, 0.4, 0.6mm, respectively. And then, SMD type ceramic filter were fabricated with the size of 3.7$\times$3.1$\textrm{mm}^2$. SMD type ceramic filter with the size of b=0.8mm, d=0.4mm and gap(c)=0.4mm, which showed insertion loss of 2.951dB, 3dB bandwidth of 54.7kHz and 20dB stop bandwidth of 129.27kHz, was suitable for IF bandpass filter application.

A Study of the Characteristics on the Vacuum Interrupter with Axial Magnetic Field Type using 3 Dimension Finite Element Analysis (3차원 유한요소해석을 이용한 종자게형 진공 인터럽터의 특성고찰)

  • 하덕용;강형부
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.5
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    • pp.460-467
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    • 2002
  • This paper deals with the distribution characteristics of the current density and axial magnetic flux density on the vacuum interrupter with axial magnetic field type using 3 dimension finite element analysis. An axial magnetic field parallel to the current flow in the arc column can improve the current breaking capacity of vacuum interrupter by affecting the arc mode. The axial magnetic flux density on the contact electrode surface is analyzed by inputting external current as a function of the transient time for sine half wave. And it also is analyzed within the gap distance of the contact electrode. The peak value of current but is decreased with the descending current on the contact electrode surface and within the gap distance of the contact electrode. The residual magnetic field is generated on the contact electrode surface and within the gap distance in the instant of zero current, which is due to the influence of eddy currents. The phase shift due to eddy currents, defined as time difference between the maximum value of current and axial magnetic field, is about 1ms in the center point of gap distance.

The fabrication and analysis of the SFIT type filter (SPIT형 필터 제작 및 분석)

  • You, Il-Hyun
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.3
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    • pp.699-706
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    • 2010
  • We have studied to obtain the slanted finger interdigital(SFIT) type filter was formed on the Langasite substrate and was evaporated two IDT electrode by Aluminum-Copper alloy respectively. We can fabricate that the block weighted type IDT as an input transducer of the filter and the withdrawal weighted type IDT as an output transducer of the filter from the results of our computer-simulation. Also, we have performed to obtain the properly design conditions about phase shift conditions of the SPIT type filter. We have employed that the number of pairs of the input and output IDT are 50 pairs and the thickness and the width of reflectors are $5000\;{\AA}$ and $3.6{\mu}m$ respectively. At the first sample, we have employed that the distance from the hot electrode to the reflectors is $2.4{\mu}m$ distance from the ground electrode to the reflectors is $1.8{\mu}m$ and the distance from the hot electrode to the ground is $1.5{\mu}m$ respectively. At the other sample, we have also employed that the distance from the hot electrode to the reflectors and the distance from the ground electrode to the reflectors are $2.4{\mu}m$. Frequency response of the fabricated SAW filter has the property that the center frequency is about 190MHz and bandwidth at the 3dB is probably 7.3 MHz. And we could obtain that return is less than -20dB, ripple characteristics is probably 3dB and triple transit echo(TTE) is less than -22dB after when we have matched impedance.

Development of Ozone Generation Technology Using Gaseous Electrical Discharge for Environment Improvement (환경개선용 기체전기방전을 이용한 오존발생기술 개발)

  • 이동헌;송현직;구건효
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.15 no.3
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    • pp.25-34
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    • 2001
  • In this paper, discharge lamp ozonizer(DLO) of a new discharge type using superposition of gaseous electrical discharge for environment improvement was designed and manufactured. DLO is equipped with 3 electrodes(central ground electrode of discharge lamp type internal high voltage electrode of mesh type and external high voltage electrode of spiral type), and it is composed of double gap(gap between discharge lamp and internal electrode, gap between discharge lamp and external electrode). Internal and external electrodes are respectively applied AC high voltage which has 180[$^{\circ}$] phase difference. Ozone is generated by overlaying of each silent discharge which is respectively came from two gaps. At the moment discharge characteristics and ozone generation characteristics of DLO were investigated in accordance with quantity of supplied gas, discharge power and the number of DLO. When ozone generated by DLO was in contact with NO gas, removal characteristics was excellent, so it confirmed that DLO could be used as air environment improvement facility.

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Real-time Evolution of Poly (3-hexylthiophene) type-II Phase in P3HT:PCBM Blend thin films

  • Lee, Hyeon-Hwi;Lee, Si-U;Geum, Hui-Seong;Kim, Han-Seong;Kim, Je-Han;Lee, Dong-Ryeol;Kim, Hyo-Jeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.168.2-168.2
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    • 2015
  • We observed the temperature-dependent evolution and behavior of P3HT type-II phase during a real time annealing process from a cryo-cooled low temperature in the absence and presence of an Al electrode. A poly (3-hexylthiophene) (P3HT) Type-II phase in the P3HT:PCBM films started to form near at $-10^{\circ}C$, regardless of Al layer presence. In the absence of an Al layer, type-II phase was extinct at $30^{\circ}C$. However, the extinction temperature was extended to $50^{\circ}C$ in the presence of the Al layer. Simultaneously, combined with the type-II phase, a 1:3 ordered P3HT type-II (1/3,0,0) super-lattice peak evolved. These type-II domains tended to be formed near the Al electrode layer with higher aligned status than host P3HT crystals.

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The Effects of Electric Field Variation by The Third Electrode on Water Electrophysicochemical Characteristics (제3전극에 의한 전계변화가 수중 전기물리화학적 특성에 미치는 영향)

  • Kim, Jin-Gyu
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.9
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    • pp.136-141
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    • 2010
  • In this paper, after the third electrode type oxidant generator which could format non-uniform electric field in water had been manufactured and installed, by direct electrolysis, the effects of the hydrogen potential and oxidation reduction potential characteristics attendant upon electric field change on a higher concentration oxidant generation characteristics were investigated. Consequently, as the third electrode was installed in the middle of two slit electrodes and the polarity of applied power was changed, it was observed that the third electrode system with the positive electrode can generate a higher concentration oxidant, hydrogen potential and oxidation reduction potential as compared with that of the negative electrode. It is because the positive electrode was bombarded mostly energetic electrons and the negative electrode was bombarded mainly by less energetic positive ions.

A Comparison of Energy Loss Characteristics between Radial and Axial Magnetic Field Type Vacuum Switches (대전력 펄스용 횡자계형 및 종자계형 진공스위치의 에너지 손실 특성 비교)

  • 이태호;허창수;이홍식
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.3
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    • pp.130-136
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    • 2003
  • Crowbar system Vacuum switches, widely used In a pulsed power system, could use the magnetic force to prevent the electrode damage. Vacuum switches using the magnetic forces are classified roughly into RMF(Radial Magnetic Field) and AMF(Axial Magnetic Field) type. The RMF type switches restrain a main electrode from aging due to high temperature and high density arc by rotating the arc which is driven by the Lorenz force. The AMF type switches generate axial magnetic field which decreases the electrode damage by diffusing arc. In this paper, we present the energy loss characteristics of both RMF and AMF type switches which are made of CuCr(75:25 wt%) electrodes. The time-dependent dynamic arc resistance of high-current pulsed discharge in a high vacuum chamber(~10$^{-6}$ Torr). which occurs in RMF and AMF type switches, was obtained by solving the circuit equation using the measured values of the arc voltage and current. In addition, we compared energy loss characteristics of both switches. Based on our results, it was found that the arc voltage and the energy loss of an AMF type switch are lower than a RMF type switch.