• 제목/요약/키워드: 3 electrode-type

검색결과 598건 처리시간 0.026초

우라늄이온 포집을 위한 수식된 피를 고분자 피막전극 (Deposition of Uranium Ions with Modified Pyrrole Polymer Film Electrode)

  • 차성극;이상봉
    • 전기화학회지
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    • 제3권3호
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    • pp.141-145
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    • 2000
  • 전도성이 뛰어난 피롤고분자 피막을 전기화학적으로 중합하고 이를 Gr/ppy(Polypyrrole),X.O.(xylenol orange)형의 수식된 전극을 제작하여 U(VI)의 포집에 이용하였다. 사전피막제인 NBR(nitrile butadiene rubber)을 사용하였을 때 중합속도는 $3.22\times10^{-3}s^{-1}$로 이를 사용하지 않았을 때 보다 1.6배 느린 반응이었다. 포집된 U(VI)의 양은 ppy $1.70Ccm^{-2}$ 당에 $1.55\times10^{-4}g$ 이었으며, 인공해수 중에서 matrix효과는 $6.8\%$로 나타났다. ppy전극이 Gr/ppy, $X.O^{4-}UO^+$형으로 수식됨에 따라서 피막자체의 임피던스가 증가하여 ppy만일 때의 확산에 지배적인 전도과정에서 피막자체의 전자전도와 이온도핑과정이 함께 영향을 받는 결과를 보였다. ppy전극을 X.O.로 수식하여 U(VI)를 포집함에 따라 전기이중층의 용량은 각각 56과 130여 배로 증가하였다.

직접 산화와 간접 산화용 전극의 Dye 제거 성능 비교 (Comparison of Dye Removal Performance of Direct and Indirect Oxidation Electrode)

  • 김동석;박영식
    • 한국물환경학회지
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    • 제26권6호
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    • pp.963-968
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    • 2010
  • This study has carried out to evaluate the performance of direct and indirect oxidation electrode for the purpose of decolorization of Rhodamine B (RhB) in water. Four kinds of electrodes were used for comparison: Pt and JP202 (indirect oxidation electrode), Pb and boron doping diamond (BDD, direct oxidation electrode). The effect of applied current (0.5 ~ 2.5 A), electrolyte type (NaCl, KCl, HCl, $Na_2SO_4$ and $H_2SO_4$) and electrolyte concentration (0.5 ~ 2.5 g/L), solution pH (3 ~ 11) and initial RhB concentration (25 ~ 125 mg/L) were evaluated. Experimental results showed that RhB removal efficiency were increased with increase of current, NaCl dosage and decrease of the pH. However, the effect of operating parameter on the RhB removal were different with the electrode type. JP202 electrode was the best electrode from the point of view of performance and energy consumption. The order of removed RhB concentration per energy lie in: JP202>Pt>Pb>BDD.

산화제 생성율이 높은 촉매성 산화물 전극(DSA)의 개발에 관한 연구(II) (A Study on the Preparation of the Dimensionally Stable Anode(DSA) with High Generation Rate of Oxidants(II))

  • 박영식;김동석
    • 한국환경과학회지
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    • 제18권1호
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    • pp.61-72
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    • 2009
  • Fabrication and oxidants production of 3 or 4 components metal oxide electrode, which is known to be so effective to destruct non-biodegradable organics in wastewater, were studied. Five electrode materials (Ru as main component and Pt, Sn, Sb and Gd as minor components) were used for the 3 or 4 components electrode. The metal oxide electrode was prepared by coating the electrode material on the surface of the titanium mesh and then thermal oxidation at $500^{\circ}C$ for 1h. The removed RhB per 2 min and unit W of 3 components electrode was in the order: Ru:Sn:Sb=9:1:1 > Ru:Pt:Gd=5:5:1 > Ru:Sn=9:1 > Ru:Sn:Gd=9:1:1 > Ru:Sb:Gd=9:1:1. Although RhB decolorization of Ru:Sn:Sb:Gd electrode was the highest among the 4 components electrode, the RhB decolorization and oxidants formation of the Ru:Sn:Sb=9:1:1 electrode was higher than that of the 3 and 4 components electrode. Electrogenerated oxidants (free Cl and $ClO_2$) of chlorine type in 3 and 4 components electrode were higher than other oxidants such as $H_2O_2\;and\;O_3$. It was assumed that electrode with high RhB decolorization showed high oxidant generation and COD removal efficiency. OH radical which is electrogenerated by the direct electrolysis was not generated the entire 3 and 4 components electrode, therefore main mechanism of RhB degradation by metal oxide electrode based Ru was considered indirect electrolysis using electrogenerated oxidants.

PbTiO3계 세라믹스를 이용한 3차 진동모드 에너지 트랩형 고주파필터의 전기적 특성 (Electrical Characteristics of 3rd Overtone Mode Energy-trapped High Frequency Filter using PbTiO3 System Ceramics)

  • 오동언;류주현;윤현상;박창엽;이수호;김종선;정회승
    • 한국전기전자재료학회논문지
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    • 제16권7호
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    • pp.593-598
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    • 2003
  • In this paper, 3rd overtone mode energy-trapped filter using modified PbTiO$_3$ system ceramics was manufactured to apply for intermediate frequency(IF) SMD type fillet with splitted electrode and gap size. To investigate the effects of splitted electrode and gap size on filter characteristics of 3rd overtone mode energy-trapped filter, ceramic wafers were fabricated by etching splitted rectangular electrode size(b$\times$d) of b=0.4, 0.6, 0.8, 1mm, d=0.3, 0.4, 0.5, 0.6mm and gap size(c) c=0.2, 0.3, 0.4, 0.6mm, respectively. And then, SMD type ceramic filter were fabricated with the size of 3.7$\times$3.1$\textrm{mm}^2$. SMD type ceramic filter with the size of b=0.8mm, d=0.4mm and gap(c)=0.4mm, which showed insertion loss of 2.951dB, 3dB bandwidth of 54.7kHz and 20dB stop bandwidth of 129.27kHz, was suitable for IF bandpass filter application.

3차원 유한요소해석을 이용한 종자게형 진공 인터럽터의 특성고찰 (A Study of the Characteristics on the Vacuum Interrupter with Axial Magnetic Field Type using 3 Dimension Finite Element Analysis)

  • 하덕용;강형부
    • 한국전기전자재료학회논문지
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    • 제15권5호
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    • pp.460-467
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    • 2002
  • This paper deals with the distribution characteristics of the current density and axial magnetic flux density on the vacuum interrupter with axial magnetic field type using 3 dimension finite element analysis. An axial magnetic field parallel to the current flow in the arc column can improve the current breaking capacity of vacuum interrupter by affecting the arc mode. The axial magnetic flux density on the contact electrode surface is analyzed by inputting external current as a function of the transient time for sine half wave. And it also is analyzed within the gap distance of the contact electrode. The peak value of current but is decreased with the descending current on the contact electrode surface and within the gap distance of the contact electrode. The residual magnetic field is generated on the contact electrode surface and within the gap distance in the instant of zero current, which is due to the influence of eddy currents. The phase shift due to eddy currents, defined as time difference between the maximum value of current and axial magnetic field, is about 1ms in the center point of gap distance.

SPIT형 필터 제작 및 분석 (The fabrication and analysis of the SFIT type filter)

  • 유일현
    • 한국정보통신학회논문지
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    • 제14권3호
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    • pp.699-706
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    • 2010
  • 경사진 빗살무늬 변환기 필터를 제작하기 위하여 Langasite 기판위에 두 가지 형태의 빗살무늬 변환기를 형성시켰으며, 전극재료로는 Al-Cu를 사용하였다. 모의실험을 바탕으로 입력단에는 IDT를 직렬형태로 연결시킨 block 형태로 하중을 가하는 전극 방법을 쓰고 출력단은 withdrawal 형태로 하중을 가하는 방법을 써서 제작하였다. 이를 바탕으로 경사진 빗살무늬 변환기 필터 전극 설계 방식에 대한 적절한 위상조건도 얻고자 시도하였다. Langasite 기판위에 형성시킨 입출력 빗살무늬 변환기 전극수는 50쌍, 두께는 $5000\;{\AA}$으로 하였으며, 반사기 폭은 $3.6{\mu}m$으로 하였다. 첫 번째 시료에서 hot전극과 반사기사이의 거리는 $2.4{\mu}m$이고, 접지 전극과 반사기사이의 거리는 $1.8{\mu}m$이며, hot전극에서부터 접지전극까지 간격은 $1.5{\mu}m$로 제작하였다. 두 번째 시료는 hot전극과 반사기사이의 거리 및 접지 전극과 반사가사이의 거리를 $2.4{\mu}m$로 동일하게 제작하였다. 제작한 필터의 주파수 특성은 중심주파수가 대략 190MHz정도, 대역폭은 7.3MHz이하로 측정되었으며, matching 후 return loss는 -20dB 이하이고, 리플 특성은 3dB정도이며, 반사에 의한 잔향은 -22dB 이하로 측정되었다.

환경개선용 기체전기방전을 이용한 오존발생기술 개발 (Development of Ozone Generation Technology Using Gaseous Electrical Discharge for Environment Improvement)

  • 이동헌;송현직;구건효
    • 조명전기설비학회논문지
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    • 제15권3호
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    • pp.25-34
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    • 2001
  • 본 논문에서는 방전관을 채용하여 전기적 기체방전의 중침을 이용한 새로운 방전형식의 환경개선용 오존발생 기술을 개발하였다. 방전관형 오존발생기(DLO)는 설치된 3개의 전극중 접지전극인 중심전극으로 방전관을 사용 하였으며, 나머지 2개의 메쉬형 내부전극과 나선형 외부전극에 180[$^{\circ}$]의 위상차를 가진 2개의 교류고전압 전원을 인가함으로써 방전관과 내부전극, 방전관과 외부전극사이의 방전공간에서 각각 발생되는 무성방전의 중침에 의하여 오존이 발생되는 구조이다. 이때, 원료가스의 유량, 방전전력 및 DLO의 사용 개수 변화에 따른 방전특성과 오존생성특성을 연구검토하였으며, DLO로부터 생성된 오존을 대기오염물질인 NO 가스에 접촉시켰을 때 NO 제거특성이 우수하여 방전관형 오존발생기가 대기환경개선 설비로 적용가능함을 확인하였다.

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Real-time Evolution of Poly (3-hexylthiophene) type-II Phase in P3HT:PCBM Blend thin films

  • 이현휘;이시우;금희성;김한성;김제한;이동렬;김효정
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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    • pp.168.2-168.2
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    • 2015
  • We observed the temperature-dependent evolution and behavior of P3HT type-II phase during a real time annealing process from a cryo-cooled low temperature in the absence and presence of an Al electrode. A poly (3-hexylthiophene) (P3HT) Type-II phase in the P3HT:PCBM films started to form near at $-10^{\circ}C$, regardless of Al layer presence. In the absence of an Al layer, type-II phase was extinct at $30^{\circ}C$. However, the extinction temperature was extended to $50^{\circ}C$ in the presence of the Al layer. Simultaneously, combined with the type-II phase, a 1:3 ordered P3HT type-II (1/3,0,0) super-lattice peak evolved. These type-II domains tended to be formed near the Al electrode layer with higher aligned status than host P3HT crystals.

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제3전극에 의한 전계변화가 수중 전기물리화학적 특성에 미치는 영향 (The Effects of Electric Field Variation by The Third Electrode on Water Electrophysicochemical Characteristics)

  • 김진규
    • 조명전기설비학회논문지
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    • 제24권9호
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    • pp.136-141
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    • 2010
  • In this paper, after the third electrode type oxidant generator which could format non-uniform electric field in water had been manufactured and installed, by direct electrolysis, the effects of the hydrogen potential and oxidation reduction potential characteristics attendant upon electric field change on a higher concentration oxidant generation characteristics were investigated. Consequently, as the third electrode was installed in the middle of two slit electrodes and the polarity of applied power was changed, it was observed that the third electrode system with the positive electrode can generate a higher concentration oxidant, hydrogen potential and oxidation reduction potential as compared with that of the negative electrode. It is because the positive electrode was bombarded mostly energetic electrons and the negative electrode was bombarded mainly by less energetic positive ions.

대전력 펄스용 횡자계형 및 종자계형 진공스위치의 에너지 손실 특성 비교 (A Comparison of Energy Loss Characteristics between Radial and Axial Magnetic Field Type Vacuum Switches)

  • 이태호;허창수;이홍식
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권3호
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    • pp.130-136
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    • 2003
  • Crowbar system Vacuum switches, widely used In a pulsed power system, could use the magnetic force to prevent the electrode damage. Vacuum switches using the magnetic forces are classified roughly into RMF(Radial Magnetic Field) and AMF(Axial Magnetic Field) type. The RMF type switches restrain a main electrode from aging due to high temperature and high density arc by rotating the arc which is driven by the Lorenz force. The AMF type switches generate axial magnetic field which decreases the electrode damage by diffusing arc. In this paper, we present the energy loss characteristics of both RMF and AMF type switches which are made of CuCr(75:25 wt%) electrodes. The time-dependent dynamic arc resistance of high-current pulsed discharge in a high vacuum chamber(~10$^{-6}$ Torr). which occurs in RMF and AMF type switches, was obtained by solving the circuit equation using the measured values of the arc voltage and current. In addition, we compared energy loss characteristics of both switches. Based on our results, it was found that the arc voltage and the energy loss of an AMF type switch are lower than a RMF type switch.