• 한국대기환경학회지
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• 제20권4호
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• pp.555-569
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• 2004

Size -segregated measurements of aerosol composition using 8-stage DRUM impactor are used to determine the transport of natural and anthropogenic aerosols at Gosan site from 29 March to 30 May in 2002. Separation of ambient aerosols by DRUM impactor offers many Advantages over other standard filtration techniques. Some of the most important advantages are the ability to segregate into details by particle tire, to better preserve chemical integrity since the air stream doesn＇t pars through the deposit, to collect samples as a function of time, and to have a wide variety of impaction surfaces available to match analytical needs. Although the transport of Yellow sand is a well-known phenomenon in springtime, the result of measurement shows that not only soil dust but also anthropogenic aerosols, including sulfur, enriched trace metals such as Pb, Ni, Zn. Cu, Cr, As, Se, Br, are transported to Gosan in springtime. This study combines the size- and time-resolved aerosol composition measurements with isentropic, backward air-mass trajectories in order to identify some potential source regions of anthropogenic aerosols. As a result, during the NYS period, the average concentration of PM$_{10}$ was 46$\mu\textrm{g}$/㎥, Si, Al. S, Fe, Cl, K, Ca were higher than 1,000 ng/㎥ and Ti was about 100 ng/㎥. The concentrations of Zn, Mn, Cu. Pb, Br, Rb, V, Cr, Ni. At, Se ranged between 1 and 70 ng/㎥. More than 50% typical soil elements, tuck as Al, Si, Fe, Cd. Ti, Cr, Cu, Br. were distributed in a coarse particle range(5.0-12${\mu}{\textrm}{m}$). In other hand, anthropogenic pollutants, luck as S, N, Vi, were mainly distributed in a fine particle range (0.09-0.56${\mu}{\textrm}{m}$). During the YS period, PM$_{10}$ increased about 8 times than NYS period, and main soil elements, such as Al, Si, S, K, V, Mn, Fe also doubled in coarse particle range (1.15-12${\mu}{\textrm}{m}$). But Zn, As, Pb, Cu and Se, which distributed in the time aerosols (0.09-0.56${\mu}{\textrm}{m}$), were on the same level with or decreased than NYS period. Finally. except the YS Period, coarse particles (2.5-12${\mu}{\textrm}{m}$) are inferred to be influenced by soil, coal combustion, waste incineration, ferrous and nonferrous sources through similar pathways with Yellow Sand. But fine particles have different sources, such as coal combustion, gasoline vehicle, biomass burning, oil or coal combustion, nonferrous and ferrous metal sources, which are transported from China, Korea peninsula and local sources.ces.

• 환경영향평가
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• 제27권5호
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• pp.431-446
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• 2018

본 연구에서는 충청남도 논산시 농촌지역의 대기 중 블랙카본, 이온, 금속원소 등을 포함한 $PM_{2.5}$의 화학적 특성을 규명하고 $PM_{2.5}$의 오염원을 정량적으로 평가하였다. 분석의 정도관리를 평가한 결과, 금속원소를 포함한 대부분의 미량성분의 분석값은 상대오차와 상대표준편차가 10% 미만이었다. 농촌지역의 $PM_{2.5}$의 평균 농도($20.1{\pm}10.1{\mu}g/m^3$)는 2018년에 강화된 연평균 기준을 초과하는 수준이었다. $PM_{2.5}$와 탄소 및 이온성분은 서로 유의한 상관성을 보였고, 미량성분의 농도는 $10^{-3}{\sim}10^4ng/m^3$ 범위인 것으로 나타났다. 양의 인자 분석법(PMF, Positive Matrix Factorization)을 이용하여 오염원을 평가한 결과, 농촌지역의 $PM_{2.5}$의 오염원은 secondary aerosol(34.4%), soil/road dust(20.1%), biomass burning(16.9%), incineration/fuel combustion(13.2%), vehicle exhaust(12.2%), sea-salt(3.17%) 이었다. 도시지역과 달리 농촌지역은 연소와 관련된 오염원이 중요하였고 따라서, 농촌지역의 관리 대상 오염원으로서 불법소각은 세심한 대책을 필요로 한다.

• 한국환경보건학회지
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• 제33권6호
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• pp.479-487
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• 2007

[ $PM_{2.5}$ ], particulate matter less than 2.5 um in a diameter, can penetrate deeply into the lungs. Exposure to $PM_{2.5}$ has been associated with increased hospital visits for respiratory aliments as well as increase mortality. $PM_{2.5}$ is a byproduct of combustion processes and as such has a complex composition including a variety of metallic elements, inorganic and organic compounds as well as biogenic materials (microorganisms, proteins, etc). In this study, the average concentrations of fine particulates $PM_{2.5}$ have been measured simultaneously in Asan and Seoul, Korea, by using particulate matter portable sampler from September 2001 to August 2002. Sample collection filters were analyzed by ICP-OES to determine the concentrations of metallic elements (As, Ni, Fe, Cr, Cd, Cu, Pb, Zn, Si). Annual mean $PM_{2.5}$ concentrations in Asan and Seoul were 37.70 and $45.83\;{\mu}g/m^3$, respectively. The highest concentrations of $PM_{2.5}$ were found in spring season in both cities and the concentrations of measured metallic elements except As in Asan were higher than those in Seoul, suggesting that yellow dust in spring could affect $PM_{2.5}$ concentrations in Asan rather than Seoul. The correlation coefficients of Pb and Zn were 0.343 for Asan and 0.813 for Seoul during non-yellow dust condition, suggesting that Pb and Zn were influenced with the same sources. The correlation coefficients between Si and Fe in the fine particulate mode were 0.999 (Asan) and 0.998 (Seoul) during yellow dust condition. It was suggested that these two elements were impacted by soil-related transport from China during the yellow dust storm condition.

• 한국산업융합학회 논문집
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• 제27권3호
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• pp.655-663
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• 2024

In order to meet the technological demand for indoor heating systems that ensure winter thermal comfort during the transition from internal combustion engines to electrification, a localized proximity heating module using surface heating elements was developed. The operational performance of heating module was tested in the low temperature chamber. The experiment conditions were varied by changing the chamber temperature (-10, 0℃), the air flow rate (6.2, 6.0, 4.2m³/h), the heater power (100, 80, 60, 40W). Thermal comfort model was confirmed using the CBE Thermal Comfort Tool applying ASHRAE standard 55. Under -10℃ condition, thermal comfort was satisfied at 23.4, 23.2℃ at power of 100W and air flow rate 6.0, 4.6m³/h. Under 0℃ condition, at power of 80W, air flow rate 6.2, 6.0m³/h, and at power of 60W, air flow rate 4.6m³/h showed results of 25.7, 26.1, 23.0℃, respectively, satisfying thermal comfort. This study analyzed the operating performance of the local proximity heating module in the low temperature chamber and applied thermal comfort model to prove applicability of local proximity heating module using surface heating elements and how to utilize the thermal comfort model.

• 한국자동차공학회논문집
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• 제17권1호
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• pp.80-86
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• 2009

Main bearing cap is one of the essential structural elements in internal combustion engine. Main bearing cap guides and holds the crankshaft, withstanding the full combustion and inertia loads of the engine. A seamless design methodology using FEA has been proposed to produce a reliable design of main bearing cap. A Levy's thick cylinder model was applied to calculate the contact pressure between bearing shell and housing bore. A calculated contact pressure at housing bore is within the allowed limit comparing with that from bearing shell model. An adequate FEA model was suggested to obtain reliable solutions for the durability of main bearing cap. 3D global model consists of engine bulkhead, main bearing cap, and bolts. Sub-model consisting of cap and part of bolts is used to get detailed solution of main bearing cap. A very careful contact modeling practice is needed to resolve the convergence problems frequently encountering during combined geometric and material non-linear problems. A proposed methodology has been applied to the main bearing cap model successfully and obtained reliable stress results and fatigue safety factors.

• 분석과학
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• 제21권4호
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• pp.284-295
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• 2008

플라스틱 시료 중 각종 유해물질 유무 확인을 위한 여러 가지 시험항목을 저비용으로 빠르게 분석할 수 있는 방법으로 Combustion ion chromatography(연소IC)를 사용한 방법을 채택하였다. F, Cl 및 Br의 3개 항목에 대하여 연소IC로 시험법 유효화 검증을 실시한 결과, 검량선은 0.5~4.0 mg/kg 농도범위에서 $r^2$ = 0.999~1.000의 상관관계 계수를 갖는 좋은 직선성을 나타내었으며, 검출한계는 0.005~0.024 mg/kg, 정량한계는 0.014~0.073 mg/kg 이였다. 인증표준물질(CRM)을 사용한 연소IC의 회수율은 95.5~104.9%이었다. 본 결과를 토대로 국내외 시험기관간 비교 숙련도 시험을 실시하였으며, 그 결과 연소IC 방법이 전기전자제품 중에 halogen-free 및 기타 유해물질 규제 대응을 위한 효율적인 분석방법임을 확인하였다.

• Asian Journal of Atmospheric Environment
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• 제7권3호
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• pp.169-175
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• 2013

Measurement of the phosphorus concentration in aerosols in Beijing, which was a representative East Asian mega-city, was carried out. The optimum procedure for analyzing phosphorus in aerosols was found in this study. Recovery of phosphorus in environmental samples through the improved method was almost 100%. The concentration of phosphorus in TSP was $145{\pm}47\;ng/m^3$, with a seasonal variation showing high concentrations in winter and low concentrations in summer. The concentrations of phosphorus in $PM_{2.5}$ accounted for $35{\pm}6%$ of those in TSP, with no seasonal variations. The major source of phosphorus in aerosols in Beijing was soil dust, and additional sources of phosphorus in fine particles could be coal combustion and biomass burning.

• 한국재료학회지
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• 제22권9호
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• pp.470-475
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• 2012

$La_{1-x}Sr_xMnO_3$(LSM,$0{\leq}x{\leq}0.5$) powders as the air electrode for solid oxide fuel cell were synthesized by a glycine-nitrate combustion process. The powders were then examined by X-ray diffraction(XRD) and scanning electron microscopy (SEM). The as-formed powders were composed of very fine ash particles linked together in chains. X-ray maps of the LSM powders milled for 1.5 h showed that the metallic elements are homogeneously distributed inside each grain and in the different grains. The powder XRD patterns of the LSM with x < 0.3 showed a rhombohedral phase; the phase changes to the cubic phase at higher compositions($x{\geq}0.3$) calcined in air at $1200^{\circ}C$ for 4 h. Also, the SEM micrographs showed that the average grain size decreases as Sr content increases. Composite air electrodes made of 50/50 vol% of the resulting LSM powders and yttria stabilized zirconia(YSZ) powders were prepared by colloidal deposition technique. The electrodes were studied by ac impedance spectroscopy in order to improve the performance of a solid oxide fuel cell(SOFC). Reproducible impedance spectra were confirmed using the improved cell, which consisted of LSM-YSZ/YSZ. The composite electrode of LSM and YSZ was found to yield a lower cathodic resistivity than that of the non-composite one. Also, the addition of YSZ to the $La_{1-x}Sr_xMnO_3$ ($0.1{\leq}x{\leq}0.2$) electrode led to a pronounced, large decrease in the cathodic resistivity of the LSM-YSZ composite electrodes.

• 오토저널
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• 제12권3호
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• pp.41-52
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• 1990

In this study are determined the unsteady temperature and thermal stress fields for a domestic 4-cylinder, 4-cycle gasoline engine cylinder head by the three-dimensional finite element method. A representative part of the cylinder head is modelled as a combination of hexahedron isoparametric elements, and the time-dependent temperature and the heat transfer coefficient of the gas are imposed as the thermal boundary conditions for the engine speeds of 500 rpm and 2000 rpm. The obtained results, which are represented graphically, indicate that the amplitudes of temperature fluctuation during a cycle are about 10.deg. C and 3.deg. C respectively on the surface of combustion chamber, and the maximum temperature fields occur at 30.deg. , 10.deg. respectively before the initiation of the exhaust stroke. Thermal stress fields due to non-uniform temperature distributions show that compressive stress is much larger than tensile stress throughout a cycle. It is also found that the compressive stress varies with substantial amplitude between the exhaust port and ignition plug hole, and the high tensile stress with small fluctuation occurs between exhaust port and the adjacent head bolt hole.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2003년도 춘계학술대회논문집
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• pp.1128-1133
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• 2003

A gas driven heat pump (GHP) core design comprises internal combustion engine, compressors incorporated to a cooling/heating system, rubber mountings and belt transmissions. Main excitation farces are generated by an engine, compressors themselves and belt fluctuation. It leads to high vibration level of the mount that can cause damage of GHP elements. Therefore an appropriate design of the mounting system is crucial in terms of reliability and vibration reduction. In this paper oscillation of the engine mount is explored both experimentally and analytically. Experimental analysis of natural frequencies and operational frequency response of the GHP engine mounting system enables to create simplified model for numerical and analytical investigations. It is worked out criteria f3r vibration abatement of the isolated structure. Influence of bracket stiffness between engine and compressors, suspension locations and damper performance is investigated. Ways to reduce excitation forces and improve dynamic performance of the engine-compressor mounting system are considered from these analyses. Implementation of the proposed approach permits to choose appropriate rubber mountings and their location as well as joining elements design A phase matching technique can be employed to control forces from main exciters. It enables to changing vibration response of the structure by control of natural modes contribution. Proposed changes lead to significant vibration reduction and can be easily utilized in engineering practice.