• Title/Summary/Keyword: 2b-site

Search Result 1,255, Processing Time 0.028 seconds

Phase transition and crystal structure analysis of PTCR $BaTiO_3$ ceramics with dopants (Y, Nb) (첨가제(Y, Nb)에 따른 PTCR $BaTiO_3$계 세라믹스의 결정구조 해석과 상전이 특성)

  • 차용원;원승신;백종후;이희수;엄우식;송준광;이인식;정훈택
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.7 no.2
    • /
    • pp.253-258
    • /
    • 1997
  • The characteristics of crystal structure and phase transition with dopants ($Nb_2O_5$= 0.1~0.4 mol% and $Y_2O_3$ : 0.2~0.4 mol%) on the PTCR $BaTiO_3$ system were investigated. In the case of $Nb_2O_5$ additive, the lattice parameter of PTCR $BaTiO_3$ was changed linearly with the increasement of $Nb_2O_5$ which substituted B-site of BaTiO$_3$ and the lattice parameter of c-axis decreased abruptly at 0.3 mol%. These phenonmena were assumed to originate from the distortion of octahedron and we could confirm that the change of lattice parameter accorded with the characteristics of the phase transition temperature. $Y^{3+}$ ions substituted both of A- and B-site until the 0.3 mol% addition, but $Y^{3+}$ substitution preferred A- to B-site above 0.3 mol%. This was affirmed by the variation ,of lattice parameter and the characteristics of phase transition. It also was found that $Y^{3+}$ions in the A-site substituted both of $Ba^{2+}$ and $Ca^{2+}$ ions with equal ratio by Rietveld method.

  • PDF

Electronic and Magnetic Properties of Rare-earth Permanent Magnet : $Nd_2Fe_{14}B$ ($Nd_2Fe_{14}B$ 희토류의 영구자석의 전자기적 물성연구)

  • Min, Byeong-Il;Jeong, Yun-Hui;Yang, Chung-Jin
    • Journal of the Korean Magnetics Society
    • /
    • v.2 no.3
    • /
    • pp.193-199
    • /
    • 1992
  • 희토류 영구자석, $Nd_2Fe_{14}B$ 화합물에 대한 자체충족적 국재밀도함수근사 전자 구조 계산을 수행하여 이 물질의 전자기적 물성을 연구하였다. LMTO(Linearized Muffin-Tin Orbital)에너지 띠 방법을 사용하여 상자성, 강자성상에서 구한 $Nd_2Fe_{14}B$ 화합물의 에너지 띠구조를 토대로 하여 자성을 포함한 제반 물성, 즉 희토류금속과 천이금속의 결합(bonding)효과, 전기적, 자기적 구조등을 고찰하였다. Boron 원자의 역학은 근접 Fe 원자와의 혼합 상호작용을 통하여 Fe의 원자의 자기모멘트를 많이 줄이는 효과를 주며 또한 구조 안정성에 기여한다는 결과를 얻었다. 강자성상에서의 Fe 원자들의 평균 자기모멘트는 약 2.15 ${\mu}B$로 계산되었는데 이중 Boron 원자로 부터 가장 멀리 떨어져 있으며 12개의 Fe 원자들로 둘러싸인 Fe(j2-site)원자가 가장 큰 값(2.7 ${\mu}B$)의 자기모멘트를 갖고 Boron 원자와의 혼합 상호작용이 가장 큰 Fe(e-site)원자가 가장 작은 값(1.9 ${\mu}B$)의 자기모멘트를 갖는다.

  • PDF

The Thermal Dynamics of Fe Ion on the M-type Ba-ferrite (M형 Ba-Ferrite에서 Fe 이온의 열 진동에 관한 연구)

  • Sur, Jung-Chul;Ghim, Jin-Soo;Choi, Jong-Wan
    • Journal of the Korean Magnetics Society
    • /
    • v.21 no.1
    • /
    • pp.5-9
    • /
    • 2011
  • M$\ddot{o}$ssbauer and Raman spectrum studies have been carried out on the 2b-site Fe ion in the Ba-ferrite (M-type). The thermal dynamics of Fe ion was analyzed by M$\ddot{o}$ssbauer spectra at different angles between the $\gamma$-ray direction and c-axis. The vibration on the 2b-site was more active compare to other direction and had very strong intensity in the Raman spectrum.

Occurrence of canine brucellosis in Korea and polymorphism of Brucella canis isolates by infrequent restriction site-PCR

  • Bae, Dong Hwa;Lee, Young Ju
    • Korean Journal of Veterinary Research
    • /
    • v.49 no.2
    • /
    • pp.105-111
    • /
    • 2009
  • In this study, occurrence of canine brucellosis was surveyed in kennels, indoor dogs and stray dogs in Korea, and infrequent restriction site-polymerase chain reaction (IRS-PCR) was applied to analyze DNA polymorphism of Brucella canis (B. canis) isolates. Among a total of 501 dogs tested, B. canis antibodies by both rapid screening agglutination with 2-mercaptoethanol (2-ME RSAT) and immunochromatographic assay were detected in only 14.1% of kennel dogs. There were no seropositive cases in indoor dogs and stray dogs. DNA polymorphism was observed in 16 B. canis isolates by the IRS-PCR. Sixteen isolates were tested with primers, PsalA, PsalC, PsalG and PsalT, and different primers produced different DNA patterns. In regard to the IRS-PCR pattern of 16 isolates, 9 (56.3%) belonged to the IRS-PCR type I. The remaining 7 were differentiated as type II, III and IV. An application of the primer PsalC provided discrimination between B. canis isolated in 2005 and others.

Soil Microarthropods at the Kwangyang Experiment (3. Relationship between Soil Oribatid Mite and Vegetation) (서울대 광양연습림내 토양 미소 절지동물에 관한 연구 - 3. 날개응애와 식생과의 관계)

  • Kwak, Joon-Soon;Kil, Bong-Seop
    • The Korean Journal of Ecology
    • /
    • v.12 no.3
    • /
    • pp.191-202
    • /
    • 1989
  • This study was carried out to investigate the relationship between soil mites(Acarina:Cryptostigmata) and vegetation in sampled area. From July 1984 to June 1985, samples were taken monthly from coniferous forests; a pinenut (Pinus koraiensis S. et Z.) forest (site C-1), a whitepine(Pinus strobus L.) forest (site C-2), a needle fir tree(Abies holophyla Max.) forest (site C-3), and three broad-leaved forests; site B-1, B-2, and B-3 in Cholanamdo province, southerm part of Korea. Vascular plants of 152 species belonging to 115 genera (53 families) were identified. The flora in the coniferous forests were more diverse than in the broad-leaved forest. Similarity coefficient to the flora was shown highly between the neighbouring sites. The oribatid species in the coniferous forests were more diverse than those in the broadleaved forests. The similarity index suggested that oribatid mites in those surveying sites could be divided into "coniferous forest type" and "broad-leaved forest type".d forest type".uot;.

  • PDF

Catalytic Combustion of Benzene over Perovskite-type Oxides Prepared Using Malic Acid Method (능금산법으로 제조된 페롭스카이트형 산화물에서 벤젠의 촉매연소반응)

  • Jung, Won-Young;Hong, Seong-Soo
    • Clean Technology
    • /
    • v.18 no.3
    • /
    • pp.259-264
    • /
    • 2012
  • Perovskite-type oxides were successfully prepared using malic acid method, characterized by TG/DTA, XRD, XPS, TEM and $H_2$-TPR and their catalytic activities for the combustion of benzene were determined. Almost of catalyst showed perovskite crystalline phase and 15-70 nm particle size. The $LaMnO_3$ catalysts showed the highest activity and the conversion reaches almost 100% at $350^{\circ}C$. The catalysts were modified to enhance the activity through substitution of metal into the A or B site of the perovskite oxides. In the $LaMnO_3$-type catalyst, the partial substitution of Sr into site the A-site enhanced the catalytic activity in the benzene combustion. In addition, the partial substitution of Co or Cu into site the B-site also enhanced the catalytic activity and the catalytic activity was in the order of Co > Cu > Fe in the $LaMn_{1-x}B_xO_3$ (B = Co, Fe, Cu) type catalyst.

Selection of Indicator Insects for the Evaluation of Agricultural Environment (농업환경 평가를 위한 지표곤충 선발)

  • Choi Young-Cheol;Park Hae-Chul;Kim Jong-Gill;Sim Ha-Sik;Kwon Oh-Seok
    • Korean journal of applied entomology
    • /
    • v.43 no.4 s.137
    • /
    • pp.267-273
    • /
    • 2004
  • To select indicator insects, the abundance of which is one of the major criteria for the evaluation of agricultural environment, was designated and monitored in the three sites (Hongcheon A, B, and Yangpyeong) from 2001 to 2003. Characteristics of rice cultivation are usual cultivation with 2 or 3 times sprayed chemical agents per year in Hongcheon A site, duck cultivation with non-sprayed chemical agent, green manure and mowing in Hongcheon B site, and pond snail with non-sprayed chemical agent, green manure and mowing in Yangpyeong site. Dominant floral species are Digitaria ciliaris (Retz.) Koel., Persicaria thunbergii (Siebold & Zuccarini) H. Gross, Echinochioa crus-galli (L.) Beauvois, and Humulus scandens (Lour.) Merr. in Hongcheon A site, Digitaria ciliaris (Retz.) Koel., Persicaria thunbergii (Siebold & Zuccarini) H. Gross, and Echinochloa crus-galli (L.) Beauvois in Hongcheon B site, and Digitaria ciliaris (Retz.) Koel., Setaria viridis (L.) Beauv., and Persicaria langiseta (De Btuyn) Kitagawa in Yangpyeong site. Degree of green naturality (DGN) was higher in Hongcheon B site (2.0) and Yangpyeong site (3.6) than in Hongcheon A site (1.6). Number of species and individual of insects collected in the three sites were abundant on August and September. The species diversity was higher in Hongcheon B and Yangpyeong than in Hongcheon A. And Coleoptera was dominant in the all sites. The dominance index (DI) was the lowest, but diversify index (H'), evenness index (E) and richness index (RI) were the highest in Hongcheon B site. Based on three results, indicator insects for the evaluation of agricultural environment were selected as Dolichus halensis in Hongeheon A site, as Pheropsophus. javanus and Polionemobius mikado in Hongcheon B and Yangpyeong sites.

Replication origins oriGNAI3 and oriB of the mammalian AMPD2 locus nested in a region of straight DNA flanked by intrinsically bent DNA sites

  • Balani, Valerio Americo;De Lima Neto, Quirino Alves;Takeda, Karen Izumi;Gimenes, Fabricia;Fiorini, Adriana;Debatisse, Michelle;Fernandez, Maria Aparecida
    • BMB Reports
    • /
    • v.43 no.11
    • /
    • pp.744-749
    • /
    • 2010
  • The aim of this work was to determine whether intrinsically bent DNA sites are present at, or close to, the mammalian replication origins oriGNAI3 and oriB in the Chinese hamster AMPD2 locus. Using an electrophoretic mobility shift assay and in silico analysis, we located four intrinsically bent DNA sites (b1 to b4) in a fragment that contains the oriGNAI3 and one site (b5) proximal to oriB. The helical parameters show that each bent DNA site is curved in a left-handed superhelical writhe. A 2D projection of 3D fragment trajectories revealed that oriGNAI3 is located in a relatively straight segment flanked by bent sites b1 and b2, which map in previously identified Scaffold/Matrix Attachment Region. Sites b3 and b4 are located approximately 2 kb downstream and force the fragment into a strong closed loop structure. The b5 site is also located in an S/MAR that is found just downstream of oriB.

Microscopic Studies of the Magnetic and Thermal Properties in Ba-ferrite Single Crystal (Ba-Ferrite 단결정의 자기적 및 열적 현상에 관한 미시적 연구)

  • Sur, J.C.;Choi, J.W.
    • Journal of the Korean Magnetics Society
    • /
    • v.19 no.4
    • /
    • pp.152-155
    • /
    • 2009
  • Ba-Ferrite single crystals were prepared and the magnetic and thermal properties were characterized by Mossbauer spectroscopy. The single crystal layer was cut in the c-axis and radiated to the surface by ${\gamma}$-rays for Mossbauer spectroscopy. We found out that the spin states in Fe ions were parallel to the ${\gamma}$-rays direction and the whole crystal bulk formed only one crystal with the same spin direction. $M\"{o}ssbauer$ spectra in single crystal have only 4 sets of 4 absorption lines in each Fe site when the ${\gamma}$-rays have the same radiation direction with the c-axis in the crystal, and there was no 2b-site spectrum. The zero absorption of 2b-site means that there was a fast diffusion motion in a double-well atomic potential at room temperature, in which bipyramidal Fe ions have the two minima at each side mirror plane.