• Title/Summary/Keyword: 2D-hexagonal

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Fabrication and characterization of CdS film, nanowires and nanobelts grown by VPE

  • Son, Moon-A;Lee, Dong-Jin;Kang, Tae-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.69-69
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    • 2010
  • The research is the structural and optical characteristics of the Cadmium Sulfide(CdS) film, nanowires and nanobelts grown on the $Al_2O_3$ substrate using the vapor phase epitaxy method. The field-emission scanning electron microscopy(FE-SEM) were used to identify the shape of the surface of the nanostructures and x-ray diffraction(XRD) and transmission electron microscopy (TEM) were used to evaluate the structural characterisitcs. As a result, the XRD was confirmed the CdS peak and the substrate peak and TEM showed single crystals with wurtzite hexagonal structure on the nanostructures. As for the optical characteristic of the nanostructures, photoluminescence(PL) and micro-raman spectrum were measured. The PL measurements confirmed the emission peak related bound exciton to neutral donor($D^0X$) peak and free exciton(FX) peak. The micro-raman spectrum showed that the peak of the nanostructures were similar to the pure crystalline CdS peak and each peak were overtone of LO phonon of the hexagonal CdS of the longitudinal optical(LO) phonon mode. Therefore, it is confirmed that the CdS nanostructures grown in this research have superior crystallinity.

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A Fast Block Matching Motion Estimation Algorithm by using the Enhanced Cross-Hexagonal Search Pattern (개선된 크로스-육각 패턴을 이용한 고속 블록 정합 움직임 추정 알고리즘)

  • Nam Hyeon-Woo
    • Journal of the Korea Society of Computer and Information
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    • v.11 no.4 s.42
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    • pp.77-85
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    • 2006
  • There is the spatial correlation of the video sequence between the motion vector of current blocks. In this paper, we propose the enhanced fast block matching algorithm using the spatial correlation of the video sequence and the center-biased properly of motion vectors. The proposed algorithm determines an exact motion vector using the predicted motion vector from the adjacent macro blocks of the current frame and the Cross-Hexagonal search pattern. From the of experimental results, we can see that our proposed algorithm outperforms both the prediction search algorithm (NNS) and the fast block matching algorithm (CHS) in terms of the search speed and the coded video's quality. Using our algorithm, we can improve the search speed by up to $0.1{\sim}38%$ and also diminish the PSNR (Peak Signal Noise Ratio) by at nst $0.05{\sim}2.5dB$, thereby improving the video qualify.

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One-Dimensional Eu(III) and Tb(III)-Doped Gd Oxide Nanorods

  • Kim, Wonjoo;Sohn, Youngku
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.664-664
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    • 2013
  • Red europium(III) and green terbium(III) activating phosphors have been doped and co-doped in gadolinium oxide supports by a hydrothermal method. Scanning electron microscope images reveal that they are one-dimensional nanorods of 40~50 wide and 250~300 nm long. The gadolinium oxide supports show Gd(OH)3 of hexagonal phase and Gd2O3 of cubic crystal structure before and after a thermal annealing, respectively based on X-ray diffraction analysis. Their physicochemical characteristics have further been examined by photoluminescence spectroscopy, FT-IR, UV-visible absorption, and optical microscope. The emission colors are characterized by CIE coordinates. In addition, the emissions from Eu(III) and Tb(III) are assigned to $5D0{\rightarrow}7FJ$ (J=0,1,2,3,4) and $5D4{\rightarrow}FJ$ (J=6,5,4,3), respectively.

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Ferromagnetic Domain Behaviors in Mn doped ZnO Film

  • Soundararajan, Devaraj;Santoyo-Salazar, Jaime;Ko, Jang-Myoun;Kim, Ki-Hyeon
    • Journal of Magnetics
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    • v.16 no.3
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    • pp.216-219
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    • 2011
  • Mn doped ZnO films were prepared on Si (100) substrates using sol-gel method. The prepared films were annealed at $550^{\circ}C$ for decomposition and oxidation of the precursors. XRD analysis revealed the presence of ZnMnO hexagonal wurtzite phase along with the presence of small quantity of $ZnMn_2O_3$ secondary phase and poor crystalline nature. The 2D, 3D views of magnetic domains and domain profiles were obtained using magnetic force microscopy at room temperature. Rectangular shaped domains with an average size of 4.16 nm were observed. Magnetic moment measurement as a function of magnetic field was measured using superconducting quantum interference device (SQUID) magnetometry at room temperature. The result showed the ferromagnetic hysteresis loop with a curie temperature higher than 300 K.

Morphology Control of NTO Crystals with Various Recrystallization Techniques

  • Lee, H.Y.;K.K. Koo;Kim, K.J.;G.B. Lim;W.B. Jeong;Kim, S.H.;Kim, H.S.;Park, B.S.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.123-127
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    • 1997
  • Various recrystallization techniques has been applied to control morphology and size of NTO(3-nitro-1, 2, 4-triazole-5-one) crystals. With cooling method, it was found that the size of NTO at aqueous solution was controlled in the range of 5 to 500 $\mu\textrm{m}$. The spherical or cubic shapes of particles were obtained by adjusting operating conditions. Hexagonal and cubic shaped crystals of NTO were also obtained by sonication and evaporative method using aqueous solution of NTO. Their particle sizes were ranged 20 to 30 $\mu\textrm{m}$. In gas anti-solvent method with NTO/DMF and NTO/DMSO solutions, cubic type of NTO was obtained and the range of their sizes was 0.5-2$\mu\textrm{m}$.

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The Crystal and Molecular Structure of Fluocinolone Acetorlide $(C_{24}H_{30}F_2O_8)$ (FloucinoloneAcetonide의 결정 및 분자구조)

  • Jeong, Jong-Sun;Jo, Seong-Il;Jeong, Yong-Je
    • Korean Journal of Crystallography
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    • v.3 no.1
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    • pp.31-36
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    • 1992
  • 6, 9-Difluoro-11, 21-dihydroxyl-16, 17-[(1methylehtylidene)bis(oxy)]-pregna-1, 4-diene-3, 20-dione (fluorocinolone acetonide) , C24H3OF106, trigonal, R3 (defined as a hexagonal lattice), a =b = 17.896 k, c: 18.365 k, V=5094.3 A', Z=9, 1 (MoK a) =0.7107 A, D=1.31 g/cm3, D.: 1.328 g/cm3 T=298 K, final R=0.050 for 1101 unique observed reflections. The molecule has conformational features in common with other corticosteroids. Three molecules related by 3-fold symmetry are involved in hydrogen bonding, forming a layer of molecules perpendicular to the c-axis.

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Synthesis of Monodisperse ZnO Nanoparticles Using Semi-batch Reactor and Effects of HPC Affecting Particle Size and Particle Size Distribution (반회분식 반응을 이용한 단분산 ZnO 나노 입자의 제조 및 입자의 크기와 입도 분포에 영향을 미치는 HPC의 작용)

  • Rho, Seung Yun;Kim, Ki Do;Song, Gun Yong;Kim, Hee Taik
    • Applied Chemistry for Engineering
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    • v.17 no.3
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    • pp.274-279
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    • 2006
  • To synthesize ZnO colloidal solution by a sol-gel process, zinc acetate ($C_{4}H_{6}O_{4}Zn{\cdot}2H_{2}O{\cdot}0.2\;mol$) and lithium hydroxide ($LiOH{\cdot}H_{2}O{\cdot}0.14\;mol$) in the ethanol were added to the solution containing a dispersing agent, hydroxypropyl cellulose (HPC). The nanosize and physical shape of the synthesized ZnO particles were determined by HPC acting as the dispersing agent. Nanosized ZnO particles were also obtained by a precipitation method based on zinc-2-ethylhexagonate. The precipitates were characterized by DLS, XRD, FE-SEM, and UV-vis. As the results, the ZnO colloids tend to self-assemble into a well-ordered hexagonal close-packed structure. The ZnO nanoparticles have an average diameter of nearly 40 nm with a narrow size distribution.

Adsorption and Photocatalytic Degradation of Dyes Using Synthesized Metal-Organic Framework NH2-MIL-101(Fe) (합성 금속-유기 골격체 NH2-MIL-101(Fe)를 이용한 염료의 흡착 및 광분해 제거)

  • Lee, Joon Yeob;Choi, Jeong-Hak
    • Journal of Environmental Science International
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    • v.27 no.7
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    • pp.611-620
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    • 2018
  • In this study, a metal-organic framework (MOF) material $NH_2$-MIL-101(Fe) was synthesized using the solvothermal method, and characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), UV-visible spectrophotometry, field-emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), and surface area measurements. The XRD pattern of the synthesized $NH_2$-MIL-101(Fe) was similar to the previously reported patterns of MIL-101 type materials, which indicated the successful synthesis of $NH_2$-MIL-101(Fe). The FT-IR spectrum showed the molecular structure and functional groups of the synthesized $NH_2$-MIL-101(Fe). The UV-visible absorbance spectrum indicated that the synthesized material could be activated as a photocatalyst under visible light irradiation. FE-SEM and TEM images showed the formation of hexagonal microspindle structures in the synthesized $NH_2$-MIL-101(Fe). Furthermore, the EDS spectrum indicated that the synthesized material consisted of Fe, N, O, and C elements. The synthesized $NH_2$-MIL-101(Fe) was then employed as an adsorbent and photocatalyst for the removal of Indigo carmine and Rhodamine B from aqueous solutions. The initial 30 min of adsorption for Indigo carmine and Rhodamine B without light irradiation achieved removal efficiencies of 83.6% and 70.7%, respectively. The removal efficiencies thereafter gradually increased with visible light irradiation for 180 min, and the overall removal efficiencies for Indigo carmine and Rhodamine B were 94.2% and 83.5%, respectively. These results indicate that the synthesized MOF material can be effectively applied as an adsorbent and photocatalyst for the removal of dyes.

Microbial Control of Forest Insect Pests (II) (산림해충의 미생물적 방제 2)

  • 이응래;황계성
    • Korean Journal of Microbiology
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    • v.9 no.2
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    • pp.69-73
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    • 1971
  • On June in 1970 the authors discovered a pathogenecity, cytoplasmic polyhedrosis virus, of the Smithia virus in the larvae of Liparis dispay L. appeared on quercus forest in Chung-Neung district and had carried out a experiment to detect the pathogenecity of Smithia virus through the inoculation of it into the larvase, such as Liparis dispay L. Hyphantrea cunea DRURY, and Dendrolinus spectabilis BUTLER. The results obtained were as follows ; 1) Death rate of L.dispay and D.spectabilis treated by 10$^{6}$ /ml cytoplasmic polyhedrosis virus of Smithis virus were 88.0% and 85.5% respectively, when the larvaes of these insects are big enough. But there were none of pathogenecity in case of Hyphantrea cunea DRURY. 20 Dead larvae caused by the injection of Smithia virus had begum to find out about on 10 days after inoculation. Miximum death rate of L. didpay and D. spectabilis appeared on 20-25days nad on 25-30days, respectively, after the incoulation. 3) In the cytoplasm of Mid-gut cylindrical cells of both of these insects, polyhedrosis, such s hexagonal (0.5-2.0-6.0 micron) were found out and in these insects, polyhedrosis, such as hexaginal (0.5-2.0-6.0 mivton) were found out and in case of D.spectabilis were a few polyhedrosis, such as tetragonal, trianglar polyhedrosis. 4) Diluted concentration of `0$^{6}$ /ml cytoplasmic polyhedrosis virus of Smithia virus were spread out in the field conditions. The corrected mortality was confirmed as about 87.8%.

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Solution Behaviour of Nonionic Surfactants with Polyolic Group as Hydrophilic Portion (폴리올류를 친수부로 한 비이온성 계면활성제의 용액거동)

  • Kim, S.C.;Kim, T.Y.;Lee, S.Y.;Roh, S.H;Nam, K.D.
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.573-579
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    • 1994
  • 1-O-oleoyl glycerol, 2-O-oleoyl myo-inositol and methyl 2-O-oleoyl-${\alpha}$-D-glucopyranoside were used as surfactants in this study. The solution properties and solubilization process of those nonionic surfactants were examined by the phase equilibria. As a result of this study, we have found that phase behavior of two component systems of surfactants/$H_2O$/cyclohexane depends on temperature respectively. The three phase regions of three component systems appeared in the temperature range of $27^{\circ}C{\sim}32^{\circ}C$, $36^{\circ}C{\sim}45^{\circ}C$ and $38^{\circ}C{\sim}52^{\circ}C$ and solubilization of water and oil was high in those three phase ranged As the temperature was varied in the two component systems, liquid crystals of hexagonal were observed to in the case of 1-O-oleoyl glycerol, and liquid crystal of lamella types were observed in the case of 2-O-oleoyl myo-inositol and methyl 2-O-oleoyl-${\alpha}$-D-glucopyranoside.

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