• Journal of the Korean Society of Combustion
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• v.18 no.4
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• pp.21-28
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• 2013

HCCI engines have mainly focused on achieving low temperature combustion in order to obtain higher efficiency and lower emission. One of practical difficulties in HCCI combustion is to control the start of combustion and subsequent combustion phasing. The choice of primary reference fuels in HCCI strategy is one of various promising solutions to make HCCI combustion ignition-controlled. The behavior of ignition delay to the frequency variation of sinusoidal velocity oscillation is computationally investigated under HCCI conditions of PRF75 using a reduced chemistry in a counterflow configuration. The second-stage ignition is more delayed as the higher frequency is imposed on nozzle velocity fluctuation whereas the first-stage ignition is not much influenced.

• Journal of the Korean Chemical Society
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• v.40 no.1
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• pp.59-64
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• 1996

The 7F0→5D0excitation spectra of Eu(Ⅲ) complexed with polyfunctional monocarboxylic acid(glycolic acid, glycine and thioglycolic acid) containing a terminal O, N and S neutral donors and propionic acid were investigated using Eu(Ⅲ) luminescence spectroscopy. In the excitation spectra of Eu(Ⅲ)-propionate system, the stepwise appearance of the peaks was observed at 579.0, 579.2 and 579.5 nm with increasing in the ligand-to-metal ratio, which correspond to the formation of Eu(propionate)2+, Eu(propionate)2+ and Eu(propionate)3 species. Three maximum peaks were also obtained for Eu(Ⅲ)-glycolate, Eu(Ⅲ)-glycinate and Eu(Ⅲ)-thioglycolate systems and were found to be quite similar to those of Eu(Ⅲ)-propionate system. The q values (number of coordinated water molecules of Eu(Ⅲ) ion) obtained from the luminescence decay constants of Eu(Ⅲ)-glycolate and Eu(Ⅲ)-thioglycolate were 7.0 and 7.1, and compare well with 7.3 for Eu(Ⅲ)-propionate: Each ligand units replace around two coordinated water molecules. These results show that the polyfunctional monocarboxylates behaves like the propionate for Eu(Ⅲ) ion coordination.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.1
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• pp.17-24
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• 2004

As the environmental pollution becomes serious global problem, the regulation of emission exhausted from automobiles is strengthened. Therefore, it is very important to know how to reduce the NOx and PM simultaneously in diesel engines, which has lot of merits such as high thermal efficiency, low fuel consumption and durability. By this reason, the new concept called as Homogeneous Charge Compression Ignition(HCCI) engines are spotlighted because this concept reduced NOx and P.M. simultaneously. However, it is well known that HCCI engines increased HC and CO. Thus, the investigation of combustion characteristics which consists cool and hot flames for HCCI engines were needed to obtain the optimal combustion condition. In this study, combustion characteristics for direct injection type HCCI engine such as quantity of cool flame and hot flame, ignition timing and ignition delay were investigated to clarify the effects of these parameters on performance. The results revealed that diesel combustion showed the two-stage ignition of cool flame and hot flame, the rate of cool flame increase and hot flame decrease with increasing intake air temperature. On the other hand, the gasoline combustion is the single-stage ignition and ignition timing is near the TDC. In addition mixed fuel combustion showed different phenomenon, which depends on the ratio of gasoline component. Ignition timing of mixed fuel is retarded near the TDC and the ignition delay is increased according to ratio of gasoline.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2011.05a
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• pp.137-138
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• 2011

구리 이온은 -0.40V (vs. SCE)에서 전기화학적 환원이 일어나는 반면, 니켈 이온은 -1.19V (vs. SCE)에서 전착이 발생한다. 따라서, 단일 도금욕조 내에서 Ni-Cu 합금도금층을 제조하기 위해서는 두 금속 이온종 간의 전위차를 줄여주어야 하는데, 이를 위해 본 연구에서는 $Na_3C_6H_5O_7{\cdot}2H_2O$를 착화제로 사용하였다. 다양한 Ni-Cu 합금 도금층의 조성을 얻기 위하여 기본 도금욕 내 황산니켈과 황산구리의 비율을 10:1로 설정하였다. 도금 공정 조건에 따른 합금 도금층 조성 변화를 관찰하기 위하여 도금액 pH와 교반 속도에 따른 도금층 조성 변화를 분석하였으며, 도금액의 UV-VIS과 도금층의 XRD 와 SEM 측정을 통하여 도금욕과 도금층 간의 상관 관계를 유추하였다. 본 도금액에 사용된 $Na_3C_6H_5O_7{\cdot}2H_2O$ 착화제의 효과는 pH3에서 가장 현저하였으며, pH 변화 및 교반 속도 변화를 이용하여 다양한 합금 조성을 얻을 수 있었다.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.5
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• pp.32-38
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• 2006

Currently, due to the serious world-wide air pollution by substances emitted from vehicles, emission control is enforced more firmly and it is expected that the regulation requirements for emission will become more severe. A new concept combustion technology that can reduce the NOx and PM in relation to combustion is urgently required. Due to such social requirement, technologically advanced countries are making efforts to develop an environment-friendly vehicle engine at the nation-wide level in order to respond to the reinforced emission control. As a core combustion technology among new combustion technologies for the next generation engine, the homogenous charge compression ignition(HCCI) is expanding its application range by adopting multiple combustion mode, catalyst, direct fuel injection and partially premixed combustion. This study used a 2-staged injection method in order to apply the HCCI combustion method without significantly altering engine specifications in the aspect of multiple combustion mode and practicality by referring to the results of studies on the HCCI engine. In addition, this study confirmed the possibility of securing optimum fuel economy emission reduction in the IMEP 8bar range(which could not be achieved with existing partially premixed combustion) through forced charging, exhaust gas recirculation(EGR), compression ratio change and application of DOC catalyst.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.5
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• pp.32-39
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• 2004

HCCI (Homogeneous Charge Compression Ignition) combustion has a great advantage in reducing NOx (Nitrogen Oxides) and PM (Particulate Matter) by lowering the combustion temperature due to spontaneous ignitions at multiple sites in a very lean combustible mixture. However, it is difficult to make a diesel-fuelled HCCI possible because of a poor vaporability of the fuel. To resolve this problem, the two-stage injection strategy was introduced to promote the ignition of the extremely early injected fuel. The compression ratio and air-fuel ratio were found to affect not only the ignition, but also control the combustion phase without a need for the intake-heating or EGR (Exhaust Gas Recirculation). The ignition timing could be controlled even at a higher compression ratio with increased IMEP (Indicated Mean Effective Pressure). The NOx (Nitrogen Oxides) emission level could be reduced by more than 90 % compared with that in a conventional DI (Direct Injection) diesel combustion mode, but the increase of PM and HC (Hydrocarbon) emissions due to over-penetration of spray still needs to be resolved.

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.171-177
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• 1993

In decontamination process to remove radioactive materials of reactor cooling system, the metal ions dissolved by organic acids in decontamination solution are separated by use of ion exchange resin in the column. However, organic acids in decontamination solution decrease the apparent affinity of the resin to metal ions. In light of this, some experiments were carried out on the Amberlite IRN-77 cation resin with cobalt and iron to gain a better understanding of the complexation effects on the ion exchange process. Experimental results showed that EDTA among organic acids used as chemical decontaminants predominantly caused reduction of ion exchange capacity of cobaltous ion to resin since this reagent formed the complex with the cobaltous ion stronger than that with the ferrous ion. In contrast, the effects of oxalic acid and citric acid were found to be negligible. And, single and two-component nonlinear equilibrium relationships of the metal ions were established using experimental data.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.6
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• pp.66-73
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• 2004

In this study, combustion characteristics and various performances of a Diesel fuel DI-HCCI engine using 2-stage injection method were investigated. From these researches, application ability of 2-stage injection strategy to a DI-HCCI engine was confirmed and improvement methods of performances were considered. As the results, Using 2-stage injection method, without change of engine specifications and loss of IMEP, exhaust of NOx and Smoke emissions could be reduced to about 1/3 (at 1400rpm, IMEP 6bar) compared to conventional Diesel combustion.

• Transactions of the Korean Society of Automotive Engineers
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• v.12 no.4
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• pp.24-30
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• 2004

As the environmental pollution becomes serious global problem, the regulation of emission exhausted from automobiles is strengthened. Therefore, it is very important to know how to reduce the NOx and PM simultaneously in diesel engines, which has lot of merits such as high thermal efficiency, low fuel consumption and durability. By this reason, the new concept called as Homogeneous Charge Compression Ignition(HCCI) engines are spotlighted because this concept reduced NOx and P.M. simultaneously. However, there is trade off between output and NOx in a HCCI engine. In this study, output and emission characteristics for a gasoline direct injection type HCCI engine were investigated to clarify the effects of intake air temperature, injection time and mixture formation. From these experiments, we found that the smoke was not produced when the fuel was injected earlier than BTDC 90$^{\circ}$. In addition, the output was increased because of delay of ignition time and NOx emission was decreased because of homogeneous charge of first injection in case of split injection.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.3044-3048
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• 2008

It is well known that Premixed Charge Compression Ignition (PCCI) diesel engines according to many technologies such a change in injection timing, multiple injection strategy, cooled EGR, intake charging and SCV have the potential to achieve homogeneous mixture in the cylinder which result in lower NOx and PM as well as performance improvements. This may generate merely the infinite number of experimental conditions. The use of Response Surface Methodology (RSM) technique can considerably pull down the number of experimental set and time demand. This paper presents the effects of both fuel injection and engine operation conditions on the combustion and emissions in the PCCI diesel engine system. The experimental results have revealed that a change in fuel injection timing and multiple injection strategy along with various operating conditions affect the combustion, emissions and BSFC characteristics in the PCCI engine.