• 대한기계학회논문집A
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• 제22권1호
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• pp.177-189
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• 1998

The contents of this paper include a non-destructive technique for evaluating the degradation of the boiler superheater tube in a fossil power plant through an electrochemical polarization test. Correlation between Ip of polarization parameter and SP-DBTT for the superheater tubes in long-term use was obtained. 1.0Cr-0.5Mo steel was degraded by softening, and the degree of degradation was dependent upon carbides with Cr and Mo elements. Since brittle fracture at low temperature and ductile fracture mode at high temperature were shown, similarity between standard Charpy and small punch tests could be found. In addition, SP-DBTT showing the degree of degradation was higher, as the time-in use of the materials got longer. Electrolyte including picric acid of 1.3 g in distilled water of 100ml at 25.deg. C temperature and sodium tridecylbenzene sulfonate with 1g could be applied to evaluate the degradation of 1.0Cr-0.5Mo steel by means of the electrochemical polarization test. Ip and Ipa values measured through the electrochemical test are the appropriate parameters for representing the degradation of the superheater tube(1.0Cr-0.5Mo steel) for the fossil power plant. It is poassible to evaluate the degradation of materials with different time histories electrochemically, by Ip value only, at field test.

• 대한금속재료학회지
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• 제47권4호
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• pp.235-241
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• 2009

The STS304 stainless steel was oxidized isothermally and cyclically at temperatures between 1050 and $1200^{\circ}C$ for 1 hr in air. During isothermal oxidation, it displayed good oxidation resistance at $1050^{\circ}C$. However, it suffered from breakaway oxidation above $1100^{\circ}C$, being accompanied with internal oxidation. During cyclic oxidation, it also displayed good oxidation resistance at $1050^{\circ}C$, but it suffered from massive weight loss above $1125^{\circ}C$. The oxide scales formed consisted primarily of $Fe_2O_3$, $Fe_3O_4$ with and without $Cr_2O_3$. They were generally non-adherent.

• Journal of Welding and Joining
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• 제8권3호
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• pp.39-52
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• 1990

The research is to insure the soundness of the stainless steel overlaid weld metal(21/4Cr-IMo steel + SUS 309L) for a pressure vessel application. Detail studies were conducted for the PWHT influence on the micrstructure and intergranular corrosion characteristics of the overlaid weld metal as well as initiation of hydrogen embrittlement crack(or Disbonding) when welded metal are exposed to the hydrogen atmosphere. Hydrogen was experimentally charged to the overlaid weld metal in order to study PWHT effect on the susceptibility of hydrogen embrittlement crack. The results of this research are as follows: 1. At the bond region, austenite grain of the stainless steel side became coarsed and Cr23C6 type carbide was precipitated at the coarsed austenitic grain boundaries. Intergranular Corrosion width(by Straiss test) increased with increasing PWHT temperature and PWHT time.

• 한국분말재료학회지
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• 제16권3호
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• pp.185-190
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• 2009

Fe-Cr steels are the most promising candidate for interconnect in solid oxide fuel cells. In this study, an effective, dense and well adherent (LaSr)(CrCo)$O_3$ [LSCC] coating layer was produced onto 430 stainless steel (STS-430) by atmospheric plasma spraying and the oxidation behavior as well as electrical properties of the LSCC coated STS-430 were investigated. A significant oxidation of pristine STS-430 occurred at $800^{\circ}C$ in air environment, leading to the formation of $Cr_2O_3$ and $FeCr_2O_4$ scale layer up to ${\sim}7{\mu}m$ after 1200h, and consequently increased an area specific resistance of $330\;m{\Omega}{\cdot}cm^2$. Although the plasma sprayed LSCC coating contained the characteristic pore network, the coated samples presented apparent advantages in reducing oxidation growth of STS-430, resulting a decrease in oxide scale thickness of ${\sim}1{\mu}m$ at $800^{\circ}C$ after 1200h. The area specific resistance of the LSCC coated STS-430 was much reduced to ${\sim}7\;m{\Omega}{\cdot}cm^2$ after exposure at $800^{\circ}C$ for 1200h, compared to that of the pristine STS-403.

• 한국주조공학회지
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• 제16권2호
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• pp.124-131
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• 1996

High temperature properties such as hot hardness and thermal fatigue resistance of high speed steel roll of hot finishing mill have been investigated. Two kinds of roll having compositions, Fe-1.75%C-5.9%Cr-1.74%Mo-4.94%V-2.03%W(A specimen) and Fe-2.27%C-8.86%Cr-2.91%Mo-3.92%V-1.86%W(B specimen)were prepared for investigating the microstructure and crack propagation mode. A specimen has greater amounts of $M_7C_3$ type carbides and less amounts of MC type carbides in comparison with B specimen. Hot hardness showed sudden decrease over $400^{\circ}C$, resulting in the hardness decrease of 50% at the temperature of $600^{\circ}C$, and showed little variation with time at $500^{\circ}C$ and $800^{\circ}C$. Thermal crack was developed at $550^{\circ}C$ in A specimen and $600^{\circ}C$ in B specimen.

• 열처리공학회지
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• 제10권1호
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• pp.55-62
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• 1997

The morphology of deformation induced dislocations in polycrystalline $Ni_3$(Al, Cr) containing $M_{23}C_6$ precipitates has been investigated in terms of transmission electron microscopy(TEM). Fine Polyhedral precipitates of $M_{23}C_6$ appeared in the matrix by aging at temperatures around 973 K after solution annealing at 1423 K. TEM examination revealed that the $M_{23}C_6$ phase and the matrix lattices have a cube-cube orientation relationship and keep partial atomic matching at the {111} interface. After deformation at temperature below 973 K, typical Orowan loops were observed surrounding the $M_{23}C_6$ particles. At higher deformation temperatures, the Orowan loops disappeared and the morphology of dislocations at the particle-matrix interfaces suggested the existence of attractive interaction between dislocations and particles. The change of the interaction modes between dislocation and particles with increasing deformation temperature can be considered as a result of strain relaxation at the interface bet ween matrix and particles.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 D
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• pp.1555-1557
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• 1998

In order to investigate the core material for over-head transmission line with non-magnetic and high strength nitrogen steel, microstructure and several basic properties of Fe-Mn-Cr-Ni-N steel have been studied. It is necessary that core material have a $\gamma$ phase to have a non-magnetic characteristics. To acquire a $\gamma$ phase, Mn, Ni and C are added as a alloying element. It was found that Fe-25Mn-16Cr-1Ni-N alloy have a stable $\gamma$ phase. The precipitate from this alloy system was $(Cr, Fe)_7C_3$. High Mn and N steel satisfies Sievert's relation that solubility of nitrogen increases with the square root of partial pressure of gas in metal-gas system and the hardness have proportional relation with nitrogen concentration.

• 한국분말재료학회지
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• 제25권1호
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• pp.36-42
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• 2018

In order to expand the application of oxide dispersion-strengthened (ODS) steel, a composite material is manufactured by adding mechanically alloyed ODS steel powder to conventional steel and investigated in terms of microstructure and wear properties. For comparison, a commercial automobile part material is also tested. Initial microstructural observations confirm that the composite material with added ODS steel contains i) a pearlitic Fe matrix area and ii) an area with Cr-based carbides and ODS steel particles in the form of a $Fe-Fe_3C$ structure. In the commercial material, various hard Co-, Fe-Mo-, and Cr-based particles are present in a pearlitic Fe matrix. Wear testing using the VSR engine simulation wear test confirms that the seatface widths of the composite material with added ODS steel and the commercial material are increased by 24% and 47%, respectively, with wear depths of 0.05 mm and 0.1 mm, respectively. The ODS steel-added composite material shows better wear resistance. Post-wear-testing surface and cross-sectional observations show that particles in the commercial material easily fall off, while the ODS steel-added material has an even, smooth wear surface.

• 한국분말재료학회지
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• 제24권2호
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• pp.133-140
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• 2017

This study investigates the oxidation properties of Fe-14Cr ferritic oxide-dispersion-strengthened (ODS) steel at various high temperatures (900, 1000, and $1100^{\circ}C$ for 24 h). The initial microstructure shows that no clear structural change occurs even under high-temperature heat treatment, and the average measured grain size is 0.4 and $1.1{\mu}m$ for the as-fabricated and heat-treated specimens, respectively. Y-Ti-O nanoclusters 10-50 nm in size are observed. High-temperature oxidation results show that the weight increases by 0.27 and $0.29mg/cm^2$ for the as-fabricated and heat-treated ($900^{\circ}C$) specimens, and by 0.47 and $0.50mg/cm^2$ for the as-fabricated and heat-treated ($1000^{\circ}C$) specimens, respectively. Further, after 24 h oxidation tests, the weight increases by 56.50 and $100.60mg/cm^2$ for the as-fabricated and heat-treated ($1100^{\circ}C$) specimens, respectively; the latter increase is approximately 100 times higher than that at $1000^{\circ}C$. Observation of the surface after the oxidation test shows that $Cr_2O_3$ is the main oxide on a specimen tested at $1000^{\circ}C$, whereas $Fe_2O_3$ and $Fe_3O_4$ phases also form on a specimen tested at $1100^{\circ}C$, where the weight increases rapidly. The high-temperature oxidation behavior of Fe-14Cr ODS steel is confirmed to be dominated by changes in the $Cr_2O_3$ layer and generation of Fe-based oxides through evaporation.

• 콘크리트학회논문집
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• 제18권5호
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• pp.621-630
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• 2006

산업부산물을 활용한 고강도 경량 콘크리트 보의 역학적 거동 구명과 함께 경량 콘크리트 보의 이론식을 바탕으로 합리적인 전단강도식을 제안하였다. 보는 경량 골재를 사용한 고강도 경량 콘크리트 보(L) 8개와 일반 골재를 사용한 고강도콘크리트 보(H) 4개의 실험체를 제작하였다. 그리고 전단스팬비(a/b=1.5, 2.5, 3.5, 4.5), 인장철근비(${\rho}$=0.57, 1.0, 1.59, 2.3%), 콘크리트의 압축강도(35.4, 65.3MPa)를 주요 변수로 설정하여 실험하였다. 이로부터 보에 대한 하중-처짐관계 및 변형률 분포, 파괴성상, 최대내력 등에 대하여 측정하였다. 또한 보의 전단강도식의 제안을 위하여 사인장 균열 강도와 극한전단강도로 세분화하여 기존 제안식과 규준식에 적용시켜 상호 비교 분석을 하였다. $V_{cr}$에 있어서는 a/b=2.5 이상에서는 ACI 규준식과 Zsutty제안식에서 감소하는 결과였지만, Mathey의 제안식에서는 약간의 상승 경향을 보였다. 또한, ${\rho},\;f_c$의 증가에 따라 $V_{cr,\exp}/V_{cr,cal}$은 과대평가의 경향이 나타났다. 한편, $V_{u, \exp}/V_{u,cal}$에서는 통계적인 방법으로 유도된 Zsutty의 제안식이 실험결과와의 일치성에서 좋은 결과를 보였다. 이 식으로부터 유도 수정된 전단강도에 대한 제안식은 $V_{cr},\;V_u$에서 합리적으로 예측할 수 있음을 알 수 있었다. 따라서 본 연구에서 제안된 전단강도 식은 경량 콘크리트의 전단스팬비, 인장철근비, 콘크리트 압축강도의 변화에 따른 전단내력을 합리적으로 평가하는데 유용하게 활용될 수 있을 것으로 사료된다.