• Nuclear Engineering and Technology
• /
• v.53 no.12
• /
• pp.3952-3965
• /
• 2021

In this study, volcanic ash was used as raw material to prepare waste forms with different silicon/aluminum (Si/Al) molar ratios to immobilize sodium-salt waste (SSW) containing simulated ¹³⁷Cs. Effects of Si/Al molar ratios (3:1 and 2:1) and sodium salts on sintering behavior of waste forms and immobilization mechanism of Cs⁺ were investigated. Results indicated that the main mineral phase of sintered waste-form matrixes was albite, and the formation of major phases was found to depend on Si/Al molar ratios. Si/Al molar ratio of 2 was favorable for the formation of pollucite, and the formation and crystallization of mineral phases were also decided based on physicochemical characteristics of sodium salts. Furthermore, product consistency test results indicated that the immobilization of Cs⁺ was related to Si/Al molar ratio, types of sodium salts, and glassy phase. Waste forms with Si/Al molar ratio of 2 exhibited better ability to immobilize Cs⁺, whereas the influence of sodium salts and glassy phases on the immobilization of SSW showed more complicated relationship. In waste forms with Si/Al molar ratio of 2, Cs⁺ leaching concentrations of samples containing Na₂B₄O₇·10H₂O and NaOH were low. Na₂B₄O₇·10H₂O easily transformed into liquid phase during sintering to consequently achieve low temperature liquid-phase sintering, which is beneficial to avoid the volatilization of Cs⁺ at high temperature. Results clearly reveal that waste forms with Si/Al molar ratio of 2 and containing Na₂B₄O₇·10H₂O show excellent immobilization of Cs⁺.

• Journal of Korean Society on Water Environment
• /
• v.23 no.1
• /
• pp.138-143
• /
• 2007

This study goes in for the observation of the characteristics of nitrogen removal from swine wastewater by struvite crystallization. In addition, the struvite formation potential in supernatants after struvite crystallization was investigated. In the study for nitrogen removal by struvite crystallization, the effects of pH and molar ratio of magnesium (Mg) injected using bittern as Mg source were investigated. Also, the potential of struvite formation in the supernatant with amount of Mg added was carefully observed. As the results, the optimum pH in the removal of nitrogen was 8.8 and sludge volume was increased as pH was raised from 7 to 12 under the condition that the molar ratio of $Mg^{2+}$ to ${NH_4}^+$-N to ${PO_4}^{3-}$-P was 1:1:1. An optimum removal efficiency of ammonia-N was observed at 1 molar ratio of Mg to ${NH_4}^+$-N, showing no further increase at over 1 molar ratio and dramatical deterioration at under 1 molar ratio. However, the sludge volume was increased by increasing the molar ratio of Mg. In the experiments for the potential of struvite formation in the supernatants, initial -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was much lower than $pK_{sp}$ and gradually reached $pK_{sp}$ at 2 days, as the molar ratio of Mg increased over 1.2. At 31 days, -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was returned to the initial value. In addition, the supernatants had a potential precipitation of hydroxylapatite due to calcium contained in bittern, $K_2Mg(SO_4)_3$ and $K_3Na(SO_4)_2$ resulting from the decrease of sodium and potassium in supernatants formed after struvite crystallization as times go by. Based on the results, it appears that some retention time and proper dosage of Mg may be needed for the prevention of scale in pipe line.

• Journal of Environmental Science International
• /
• v.32 no.10
• /
• pp.731-739
• /
• 2023

In this study, lab-scale phosphorus coagulation/precipitation experiments were performed using three types of polyaluminum chloride (PAC) with different Al contents (10%, 12%, and 17%). The PO₄-P removal efficiencies at various operating conditions, such as initial PO₄-P concentration, initial pH, and Al/P molar ratio, were evaluated, and correlations among the operating factors affecting phosphorus coagulation/precipitation with PAC were derived to optimize the process efficiency. When the initial PO₄-P concentration was 0.065 and 0.161 mmol P/L under an initial pH of 8-10, the optimal PAC dose was 0.126-0.378 and 0.189-0.667 mmol Al/L, respectively. Under these conditions, the Al/P molar ratio was 2.16-6.18 and 1.28-4.30, respectively, and the PO₄-P removal efficiency was in the range of 40.2-92.5%. When the Al/P molar ratio was 2 or less under an initial pH condition of 6-8, the PO₄-P removal efficiency was approximately ≤40% owing to insufficient Al³⁺ ions. However, when the Al/P molar ratio is 3-5, the PO₄-P removal efficiency improved to approximately 80-90%. Thus, the optimal Al/P molar ratio to achieve a PO₄-P removal efficiency of over 90% was determined to be approximately 4 in the PO₄-P coagulation/precipitation process using PAC.

• Journal of Environmental Science International
• /
• v.33 no.9
• /
• pp.667-674
• /
• 2024

In the present study, we aimed to determine the optimal polyaluminum chloride (PAC) dosage in raw water based on the PO₄^3--P concentration using PAC coagulants with aluminum concentrations of 10%, 12%, and 17%. The correlation between the Al/P molar ratio and the removal efficiency of aggregated Al-PO₄^3--P flocs was evaluated using sedimentation and flotation processes. As the PO₄^3--P concentration in the raw water increased, the Al/P molar ratio gradually decreased from 6.14 to 1.98. The Al/P molar ratio of PAC formulations with higher aluminum contents showed a decreasing trend in the following order: PAC 17% < PAC 12% < PAC 10%. An increase in the Al/P molar ratio led to a slight increase in the average particle size of Al-PO₄^3--P flocs formed during the coagulation process. At optimal Al/P molar ratios, PO₄^3--P removal efficiency ranged from approximately 80% to 93% for both the coagulation/precipitation and coagulation/flotation processes. The coagulation/flotation process exhibited a slightly higher PO₄^3--P removal efficiency than coagulation/precipitation.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.30 no.12
• /
• pp.812-816
• /
• 2017

$Fe_3O_4$ was prepared on the $TiO_2-coated$ natural mica substrate. The natural mica has an average particle size of $22{\mu}m$. The substrate was coated on $TiO_2$ thin films using hydrothermal synthesis at pH 1.5-2.5 at $75^{\circ}C$. The Fe precursor solution was prepared by mixing $FeSO_4$ (for $Fe^{2+}$ ion) and $FeCl_3$ (for $Fe^{3+}$ ions) with different molar ratios such as 1/2, 1/1, 2/1, 3/0, and $Fe_3O_4$ only. X-ray diffraction analysis shows that the crystal structure depends on the $FeCl_3-to-FeSO_4$ molar ratio. $Fe_3O_4$ crystal phase could be obtained at higher $FeSO_4$ contents.

• Journal of Environmental Science International
• /
• v.29 no.8
• /
• pp.793-800
• /
• 2020

The conventional development of multi-component electrodes is based on the researcher's experience and is based on trial and error. Therefore, there is a need for a scientific method to reduce the time and economic losses thereof and systematize the mixing of electrode components. In this study, we use design of mixture experiments (DOME)- in particular a simplex lattice design with Design Expert^Ⓡ program- to attempt to find an optimum mixing ratio for a three-component electrode for the high RNO degradation; RNO is an indictor of OH radical formation. The experiment included 12 experimental points with 2 center replicates for 3 different independent variables (with the molar ratio of Ru, Ti, Ir). As the Prob > F value of the 'Quadratic' model is 0.0026, the secondary model was found to be suitable. Applying the molar ratio of the electrode components to the corrected response model results is an RNO removal efficiency (%) = 59.89 × [Ru] + 9.78 × [Ti] + 67.03 × [Ir] + 66.38 × [Ru] × [Ir] + 132.86 × [Ti] × [Ir]. The R² value of the equation is 0.9374 after the error term is excluded. The optimized formulation of the ternary electrode for an high RNO degradation was acquired when the molar ratio of Ru 0.100, Ti 0.200, Ir 0.700 (desirability d value, 1).

• Environmental Engineering Research
• /
• v.22 no.1
• /
• pp.12-18
• /
• 2017

Struvite precipitation has been proven to be an effective method in removing and recovering ammonia nitrogen (N) and phosphate phosphorus (P) from wastewater. In this study, effects of pH, molar ratios and pre-treatment of effluent of anaerobically digested swine wastewater were investigated to improve struvite crystallization. The magnesium : ammonium : phosphate ratio of 1.2 : 1.0 : 1.0 was found to be optimal, yet the molar ratio in the wastewater was 1 : 74.9 : 1.8. From the analysis, the optimum pH was between 8.0 and 9.0 for maximal phosphate P release and from 8.0 to 10.0 for maximal ammonia N and phosphate P removal from real wastewater. Analysis from Visual MINTEQ predicted the pH range of 7-11 for ammonia N and phosphate P removal and recovery as struvite. For pre-treatment, microwave pre-treatment was ineffective for phosphate P release but ultrasound pre-treatment showed up to 77.4% phosphate P release at 1,000 kJ/L of energy dose. Precipitates analysis showed that phosphorus and magnesium in the collected precipitate had almost same values as theoretical values, but the ammonia content was less than the theoretical value.

• Journal of Pharmaceutical Investigation
• /
• v.11 no.3
• /
• pp.1-13
• /
• 1981

A new application of monoacidic dye is reported for the determination of pipethanate hydrochloride(PTH). The method is based on solvent extraction into chloroform of an ion-pair compound formed between methyl orange(MO) and PTH. PTH is determined by measuring absorbance of the extracts over the range of $2.0{\sim}12.0{\mu}g/ml$ at 420nm. Best accuracy can be obtained for solutions containing $3.0{\sim}8.0{\mu}g/ml$. The color was stable for at least 5 days. The molar absorptivity was $2.88\;{\times}\;10^4\;l,\;mol^{-1},\;cm^{-1}$. Molar ratio and continuous variation plots have a maximum at 0.5 mol fraction of MO, indicating a 1 : 1 MO-PTH ratio.

• Journal of the Korean Ceramic Society
• /
• v.39 no.6
• /
• pp.589-593
• /
• 2002

The single crystalline thick fi1ms of Bi:Y$_3$Fe$_{5}$ $O_{12}$(Bi:YIG) were grown on (GdCa)$_3$(GaMgZr)$_{5}$ $O_{12}$(SGGG) by Liquid Phase Epitaxy (LPE). The changes of lattice mismatch and Bi concentration were investigated in the thick film growth as a function of PO/Bi$_2$ $O_3$ molar ratio, with keeping constant of substrate rotation speed, supercooling and growth time. It was grown that the lattice constant of the garnet single crystalline thick films and Bi content increased with decreasing of PO/Bi$_2$ $O_3$ molar ratio. Bi concentration decreased with increasing of the film thickness.

• The korean journal of orthodontics
• /
• v.24 no.3 s.46
• /
• pp.555-567
• /
• 1994

The purpose of this study is to observe the effect of high pull headgear on the craniofacial structures of mixed dentition with Class II malocclusion. The cephalometric headplates of 16 children treated by high pull headgeaar during 6 months and 18 children during 12 months were traced, digitized and statistically analyzed. The results were as follows. 1. Inhibition of foreward growth of maxilla was observed in both group. 2. Clockwise rotation of maxilla was observed in both group. 3. There were distal movement of maxillary 1st molar and inhibition of alveolar bone growth of maxilla. 4. There was compensatory extrusion on mandibular 1st molar. 5. The ratio of anterior facial height to posterior facial height was almostly not changed. In the treatment plan of C II malocclusion by high pull headgear, ire must prevent the mandibulasr 1st molar from extruding and for orthopedic effect, at least 6 months is needed.