• Title/Summary/Keyword: 10 mWT

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Pervaporation Separation of Water-Ethanol Mixture Using Crosslinked PVA/PSSA_MA/TEOS Hybrid Membranes (PVA/PSSA_MA/TEOS 막을 이용한 물/에탄올 계의 투과증발 분리)

  • Rhim, Ji-Won;Lee, Byung-Seong;Kim, Dae-Hoon;Yoon, Seok-Won;Im, Hyeon-Soo;Moon, Go-Young;Nam, Sang-Yong
    • Membrane Journal
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    • v.18 no.1
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    • pp.44-52
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    • 2008
  • Pervaporation separation for water-ethanol mixtures has been carried out using crosslinked poly(vinyl alcohol) (PVA) membranes with poly(styrene sulfonic acid-co-maleic acid) (PSSA_MA) and at which tetraethylorthosilicate (TEOS) was introduced. The concentration of PSSA_MA was fixed 7 wt% over PVA and the TEOS contents, 3, 5, and 7 wt%, were varied against PVA. The composition of the feed mixtures were 10, 20, 30 and 50 wt% of water in it. PVA/PSSA_MA/5 wt% TEOS membrane showed the separation factor, 1730 and the permeability, $16.3g/m^2{\cdot}hr$ for water : ethanol = 10 : 90 at $50^{\circ}C$.

Fabrication of WC-8wt.%Co Hard Materials by Rapid Sintering Processes and Their Mechanical Properties (급속소결공정에 의한 WC-8wt.%Co 초경재료 제조와 기계적 성질평가)

  • Jeong In-Gyun;Kim Hwan-Cheol;Son In-Jin;Do Jeong-Man
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.04a
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    • pp.79-80
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    • 2006
  • 새로운 급속소결방법인 고주파유도가열 소결법과 펄스전류활성 소결법을 이용하여 습식 볼밀링으로 혼합한 WC-8wt.%Co분말에 60MPa의 압력과 90%의 고주파출력 또는 2800A의 필스전류를 가하여 상대밀도가 98.6% 이상인 초경재료를 2분이내의 짧은 시간에 제조하였다. 초기의 WC분말의 입도가 미세해짐에 따라 고주파유도가열 소결법과 펄스전류활성 소결법 모두 소결시간이 단축되는 경향을 보였으며 그 소결체의 결정립 크기도 감소하였다. 고주파유도가열 소결법으로 제조된 초경합금의 WC 결정립 크기는 초기입도가 증가함에 따라 가각 410, 540, 600, 700 및 850nm으로 측정되었으며. 그 결과를 Fig. 1.에 나타내었다. WC의 초기입도가 $0.5{\mu}m$일 경우 고주파유도가열 소결법과 펄스전류활성 소결법으로 제조된 WC-8wt.%Co 소결체의 경도와 파괴인성은 각각 $1923kg/mm^2$$10.5MPa{\cdot}m^{1/2}$$1947kg/mm^2$$10.8MPa{\cdot}m^{1/2}$ 이었다.

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Rapidly Solidified Microstructure and Phase Decomposition of Al-Cr alloys by the Single Roller Method (Single Roller법에 의한 Al-Cr 계 합금의 급냉응고 조직과 상분해)

  • Cho, Soon-Hyoung;Yoon, Eui-Pak
    • Journal of Korea Foundry Society
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    • v.7 no.2
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    • pp.108-113
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    • 1987
  • Al-Cr alloy with composition in the range from 1.5 wt% to 10 wt% Cr were rapidly solidified from the melt by the single roller method. The supersaturated solid solution was obtained up to 6 wt% Cr in Al-Cr alloy for $20{\mu}m$ thickness. Lattice parameter decreased with increasing Cr content at the rate of 0.00456A per wt% Cr up to 6 wt% Cr. Microhardness increased with increasing Cr content at the rate of $10\;Kg/mm^2$ per wt% Cr up to 6 wt% Cr. Microhardness measurements on the Al-6 wt% Cr supersaturated solid solution annealed isothermally showed no sign of age hardening. Decomposition temperature, determined by lattice parameter changes and microhardness changes, was $470^{\circ}C$ for Al-6 wt% Cr supersaturated solid solution. Transmission electron microscopy showed that decomposition within one hour below $400^{\circ}C$ occurred at grain boundaries only, and also the additional decomposition within grains being evident at $450^{\circ}C$ The coarse precipitate structure showed at $500^{\circ}C$ and $550^{\circ}C$, respectively. The coarse precipitate structure is considered $Al_7Cr$.

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Preparation of Monodisperse Blue-colored Polymeric Particles with High Zeta-potential (높은 제타전위를 갖는 단분산의 블루착색 고분자미립자의 제조)

  • Lee, Ki-Chang;Nam, Sang-Yong
    • Journal of Adhesion and Interface
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    • v.13 no.3
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    • pp.109-115
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    • 2012
  • Monodisperse blue-colored poly(styrene-co-acrylic acid) latices were successfully prepared by seeded emulsion polymerization. Blue-colored latices with carboxyl anionic charge on the surface were synthesized at the second stage with the introduction of Blue 606 dye, acrylic acid, and 0.21 ${\mu}m$-polystyrene seed. All the blue-colored latices synthesized in this study were in the size range of 0.25~0.42 ${\mu}m$ and all uniform with less than 1.01 in PSD. The particle size increased with the addition of acrylic acid being delayed and colloidally stable latices were obtained over 30 min after its addition. The blue-colored latex with 20 wt% acrylic acid showed -145 mV of zeta-potential and $-9.4{\times}10^{-6}\;cm^2/Vs$ of electrophoretic mobility, and with 25 wt% of DVB showed high $T_g$ at 396.7 K.

Mineralogy and Geochemistry of Carbonate Minerals from the Olon Ovoot Gold Mine, Mongolia (몽골 Olon Ovoot 금 광산에서 산출되는 탄산염광물의 산출상태 및 화학조성)

  • Yoo, Bong Chul;Tungalag, Naidansuren;Sereenen, Jargalen;Heo, Chul-Ho;Ko, Sang-Mo
    • Economic and Environmental Geology
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    • v.47 no.2
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    • pp.181-191
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    • 2014
  • Olon Ovoot gold mine, Mongolia, is located in the Omnogobi province which is south 500 km from Ulaanbaatar. The mine area consists of the Devonian Bot-Uul khudag formation, the Upper Devonian intrusions, and the Upper Devonian or the Early Jurassic quartz veins. The quartz veins contain from 1 to 32 g/t gold with an average of 5 g/t gold. The quartz veins vary from 0.2 m to 25 m and are concordant or discordant with foliation of the green-schist. The mineralogy of the quartz veins is simple and consists of mainly of white massive quartz with partly transparent quartz in cavity. Quartz, sericite, chlorite, pyrite and carbonates(ankerite, dolomite and siderite) were observed in the alteration zone. Carbonate minerals occur as disseminated, coarse or fine grains with quartz, sericite, chlorite and pyrite near vein margin or within wall-rock xenoliths in quartz vein. Ankerite is present as later dark grey ankerite(13.51 to 16.89 wt.% FeO) and early white grey ankerite(16.67 to 19.90 wt.% FeO). The FeO contents of early ankerite are higher than those of later ankerite. Dolomite contains from 3.89 to 10.44 wt.% FeO and from 0.10 to 0.47 wt.% MnO. Dolomite is present as dark grey dolomite(4.06 to 6.87 wt.% FeO), light white grey dolomite(6.74 to 7.58 wt.% FeO) and grey white dolomite(7.33 to 10.44 wt.% FeO). The FeO contents of white grey dolomite are higher than those of dark grey dolomite. Siderite contains from 34.25 to 48.66 wt.% FeO, from 6.79 to 14.38 wt.% MgO, from 0.06 to 0.26 wt.% MnO and from 2.08 to 8.08 wt.% CaO.

Microstructure and Mechanical Properties of P Added 0.15C-1.5Mn-1.5Al TRIP Aided Cold Rolled Steel (P 첨가 0.15C-1.5Mn-1.5Al TRIP형 냉연강판의 미세조직과 기계적 성질)

  • Ahn M. W.;Cho K. M.;Suh D. W.;Oh C. S.;Kim S. J.
    • Transactions of Materials Processing
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    • v.14 no.8 s.80
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    • pp.712-717
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    • 2005
  • Microstructure and mechanical properties are investigated for 0.15C-1.5Mn-1.5Al TRIP aided cold rolled steels containing $0.05wt\%P$ and $0.1wt\%P$. Despite of the complete replacement of Si by Al, the TRIP steel shows tensile strength of 700MPa and total elongation of $35\%$ by addition of $0.1wt\%$ P. Tensile strength of P added TRIP steels is not only affected by the solid solution hardening but also the volume fraction of retained austenite. As P content increases from $0.05wt\%$ to $0.1wt\%$, tensile strength and volume fraction of retained austenite are increased, but elongation is decreased. The lower stability of austenite in $0.1wt\%$ P added steel is responsible for the decrease of the elongation.

Response of appetite-related genes in relation to the rearing water temperature in red spotted grouper (Epinephelus akaara)

  • Jeon, Eun-Jeong;Kim, Byeong-Hoon;Lee, Chi-Hoon;Lee, Young-Don
    • Fisheries and Aquatic Sciences
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    • v.23 no.2
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    • pp.4.1-4.9
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    • 2020
  • Growth of fish is controlled by various environmental factors, including water temperature (WT). WT is also a major factor that affects the eating behavior of fish. In this study, we studied the relationship between WT and expression profiles of factors involved in appetite regulation and digestion in red spotted grouper. Fish were divided into three groups with 30 fish per group and reared for 2 weeks in a recirculating system at three different WT (natural WT, 20 ℃, and 25 ℃). After 2 weeks, they were sacrificed immediately after food intake (+ 0 h), 3 h after (+ 3 h), 6 h after (+ 6 h), and 3 h before being fed the next day (- 3 h). Fish samples were obtained for analysis of mRNA expression levels of cholecystokinin (CCK), leptin A (LepA), leptin B (LepB), and neuropeptide Y (NPY) in the brain, liver, and intestine. Expression of CCK and NPY mRNA was significantly higher at 25 ℃ compared to that at natural WT and 20 ℃, but no difference was observed for leptin. This suggests that the red spotted grouper shows characteristics typical of subtropical fish and has higher levels of feeding and digestion when reared at 25 ℃ water temperature condition.

Conversion of Mixed Fat into Biodiesel in Plug Flow Reactor Using Alkali and Mixed Catalysts (관형반응기에서 알칼리 및 혼합촉매를 사용한 혼합지방의 바이오디젤화)

  • Hyun, Young-Jin
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.123-128
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    • 2010
  • The continuous transesterification of mixed fat was done on the plug flow reactor packed with the static mixers. The transesterification using 0.5 wt% KOH, 0.8 wt% TMAH and mixed catalyst[40 v/v% KOH(0.5 wt%)+60 v/v% TMAH(0.8 wt%)] was conducted with the changes of molar ratios, weight percentage of beef, flow rates and number of static mixer's elements at $65^{\circ}C$. The overall conversion of mixed fat at 1:8 molar ratio, 50 wt% of beef and 24 of static mixer's elements increased until 0.7mL/min of flow rate. The overall conversion of mixed fat showed 96% at those conditions. So, the optimum operating conditions on tublar reactor were 1:8 molar ratio, 50 wt% of beef, 0.7 mL/min of flow rate and 24 of static mixer' s elements.

Variations in Carbon Content and Sintered Density of M3/2 Grade High Speed Steel Powders on Metal Injection Molding Process (사출성형한 M3/2계 고속도공구강 분말의 탄소함량 및 소결밀도 변화)

  • 이광희
    • Journal of Powder Materials
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    • v.4 no.3
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    • pp.170-178
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    • 1997
  • An investigation was performed to apply the M3/2 grade high speed steel for metal injection molding using both prealloyed and elementally blended powders. The injected samples were subjected to a debinding step in $H_2/N_2$ gas atmosphere at a ratio that affected the carbon content of the material. The carbon content ranged from 1.4wt.% to 1.43wt%. with increasing $H_2$ content up to 80% $H_2$ in $H_2/N_2$ atmosphere for the prealloyed powders. The carbon contents of the elementally blended powders exhibited 1.44wt.% and 1.62wt.% at 10% $H_2/N_2$ and 20% $H_2/N_2$ gas, respectively. This level decreased to 0.17wt.% upon increasing the $H_2$ content. The sintered density of both powders increased rapidly as the temperature reached the liquid phase forming temperature. After forming the liquid phase, the density rapidly increased to the optimum sintering temperature for the prealloyed powders, whereas the density of mixed elemental powders goes up slowly to the optimum sintering temperature. The optimum sintering temperature and density are 126$0^{\circ}C$ and 97.3% for the prealloyed powders and 128$0^{\circ}C$ and 96.9% for the elementally blended powders, respectively. The microstructure of the specimen at the optimum sintering temperature consisted of fine grains with primary carbides of MC and $M_6C$ type for the prealloyed powders. The elementally blended powders exhibited coarse grains with eutectic carbides of MC, $M_2C$ and $M_6C$ type.

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Adhesive Strength and Electrochemical Properties of Li(Ni0.5Co0.2Mn0.3)O2Electrodes with Lean Binder Composition (바인더 함량에 따른 Li(Ni0.5Co0.2Mn0.3)O2 전극의 접착력 및 전기화학 성능에 관한 연구)

  • Roh, Youngjoon;Byun, Seoungwoo;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.21 no.3
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    • pp.47-54
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    • 2018
  • To maximize the areal capacity($mAh\;cm^{-2}$) of $LiNi_{0.5}Co_{0.2}Mn_{0.3}O_2$(NCM523) electrode with the same loading level of $15mg\;cm^{-2}$, three NCM523 electrodes with 4, 2, and 1 wt% poly(vinylidene fluoride)(PVdF) binder content are fabricated. Due to the delamination issue of electrode composite at the edge during punching process, the 1 wt% electrode is excluded for further evaluation. When the PVdF binder content decreases from 4 to 2 wt%, both adhesion strength and shear stress decrease from 0.4846 to $0.2627kN\;m^{-1}$ by -46% and from 3.847 to 2.013 MPa by -48%, respectively. Regardless of these substantial decline of mechanical properties, their initial electrochemical properties such as initial coulombic efficiency and voltage profile are almost the same. However, owing to high loading level, the 2 wt% electrode not only exhibits worse cycle performance than the 4 wt% electrode, but also cannot maintain its mechanical integrity only after 80 cycles. Therefore, if the binder content is reduced to increase the area capacity, the mechanical properties as well as the cycle performance must be carefully evaluated.