• Transactions of the Korean hydrogen and new energy society
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• v.35 no.1
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• pp.97-104
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• 2024

In this study, combustion experiments were conducted to assess engine performance and exhaust gas characteristics using four blends of 1-pentanol and diesel as fuel in a naturally aspirated 4-stroke diesel engine. The blending ratios of 1-pentanol were 5, 10, 15, and 20% by volume. The experiments were carried out under four different engine torque conditions (6, 8, 10, and 12 Nm) while maintaining a constant engine speed of 2,000 rpm for all fuel types. The results showed that the use of 1-pentanol/diesel blended fuel generally led to a decrease in brake thermal efficiency, attributed to the low calorific value of the blend and the cooling effect due to the latent heat of vaporization. Additionally, both brake specific energy consumption and brake specific fuel consumption increased. However, the use of the blended fuel resulted in a general decrease in NOx concentration, a decrease in CO concentration except some conditions, and a reduction in smoke opacity across all conditions.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.6
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• pp.767-772
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• 2023

In this study, combustion experiments were conducted at various engine speeds under full-load conditions using a single-cylinder diesel engine by blending butanol, pentanol, and octanol with diesel at a volume ratio of 10%. Experimental results revealed that higher alcohol-diesel blends resulted in lower brake torque and brake power than pure diesel due to the lower calorific value and the cooling effect during evaporation. An evident improvement in the brake thermal efficiency of the blended fuels was observed at engine speeds below 2,000 rpm, with the butanol blend exhibiting the highest thermal efficiency overall. Furthermore, the brake-specific fuel consumption of the higher alcohol-diesel blends was lower than that of pure diesel at speeds below 2,200 rpm. When using blended fuels, the exhaust gas temperature decreased under lean mixture conditions due to heat loss to the air and the cooling effect from fuel evaporation.

• Microbiology and Biotechnology Letters
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• v.41 no.1
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• pp.26-32
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• 2013

Butanol-resistant bacteria were isolated from butanol solvent. The cell growth of isolated strains declined with increasing concentrations of butanol, and isolated strain BRS02 displayed more resistance to 12.5 g/L of butanol than other isolated strains. In addition, strain BRS251, which was resistant to even higher concentrations of butanol, was developed by the mutation of BRS02 using UV. BRS251 could grow in LB medium containing up to 17.5 g/L of butanol, 32.5 g/L of propanol, or 6 g/L of pentanol, whereas the control strain Escherichia coli was found to be tolerant to 7.5 g/L of butanol, 20 g/L of propanol, or 2 g/L of pentanol. The isolated BRS02, a Gram(+) bacterium seen to have a cocci form under the microscope, grew in 6.5% NaCl. According to biochemical tests, BRS02 can metabolize and produce acid with D-galactose, D-maltose, D-mannitol, D-mannose, methyl-${\beta}$-Dglucopyranoside, D-ribose, sucrose, or D-trehalose, as carbon sources. Also, this strain showed resistance to bacitracin, vibriostatic agent O/129, and optochin, alongside positive activities for arginine dihydrolase, ${\alpha}$-glucosidase, and urease. The BRS02 strain was identified as Staphylococcus sp. by analyses of the 16S rRNA gene, phylogenetic tree, and biochemical tests.

• Journal of the Korean Chemical Society
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• v.41 no.6
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• pp.284-291
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• 1997

The critical micelle concentrations($CMC^*$) of a cationic surfactant cetylpyridinium chloride (CPC) and a nonionic surfactant triton X-100(TX-100) in aqueous solutions of n-alcohols(methanol, ethanol, 1-propanol, 1-butanol and 1-pentanol) were determined by UV spectroscopic method at 25$^{\circ}C$. The various thermodynamic values in 0.1 M n-alcohols were calculated by means of the equation derived from the pseudo-phase separation model and compared with the values in the absence of n-alcohols. The results were a good agreement with the nonideal mixed micelle model, and they showed negative deviation from the ideal behavior.

• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.581-587
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• 2005

In order to obtain a highly purified p-dioxanone (PDX) as monomer of biodegradable polymer, suitable solvent must be selected. The selection was based on the solubility of impurities, and partial layer melt crystallization were carried out under the presence of solvent. The solubility of PDX in various solvents such as ethyl acetate, tetrahydrofuran, acetone, alcohols (methanol, ethanol, 1-propanol, 1-butanol and 1-pentanol) were measured over the temperature range of $-10{\sim}15^{\circ}C$. As solubility parameters, the mixing and dissolution enthalpy between the PDX and the solvents was studied based on empirical equations and the regular solution theory. The solubility and the temperature dependency of the solubility with the solvents of acetone, ethylacetate, and tetrahydrofuran of PDX were shown to have relatively high values compared to the alcohol type solvents. Also, in same alcohols, the smaller molecules and higher polarity gave higher solvency. In partial layer melt crystallization, small amount of ethylacetate selectively dissolved impurities and gave highly purified p-dioxanone, over 99.9% purity.