• Korean Chemical Engineering Research
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• 제53권3호
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• pp.391-396
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• 2015

n-부텐의 산화탈수소화에서 제조방법이 촉매의 반응활성에 미치는 영향을 조사하기 위하여 $BiFe_{0.65}MoP_{0.1}$ 산화물 촉매를 모델 촉매로 선정하여 공침법, 시트르산법, 수열합성법, 주형법 등의 방법으로 촉매를 제조하였다. 제조한 촉매의 물리 화학적 특성을 알아보고 반응 활성과 연관시키기 위하여 X-선 회절분석(XRD), 질소 흡착 탈착분석($N_2$ sorption), 암모니아/1-부텐-승온탈착분석($NH_3/1$-butene-TPD) 등의 특성분석을 수행하였다. 공침법으로 제조한 촉매의 활성이 가장 높게 관찰되었으며, 14시간 동안의 산화탈수소화 반응 기준으로 n-부텐의 전환율은 79.5%, 1,3-부타디엔의 선택도는 85.1%, 1,3-부타디엔 수율은 67.7%의 수치를 보였다. 암모니아 승온탈착 실험으로부터 촉매의 반응 활성은 촉매의 산특성과 밀접하게 관련이 있으며, 공침법으로 제조한 산화물 촉매가 다른 합성방법으로 제조한 촉매와 비교하여 가장 큰 산량을 갖는 것으로 관찰되었다. 또한, 1-부텐의 승온탈착 분석결과, 촉매의 활성은 흡착된 1-부텐과 촉매의 표면반응에 기인한 중간체의 흡 탈착 특성, 즉 약하게 흡착된 중간체(< $200^{\circ}C$)의 상대적인 양과 강하게 흡착된 중간체의 탈착 온도(> $200^{\circ}C$)와 밀접하게 관련이 있었다.

• Korean Journal of Chemical Engineering
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• 제35권12호
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• pp.2348-2354
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• 2018

We designed a conceptual model of the 2.3-BDO dehydration process using a hydroxyapatite-alumina catalyst and estimated its economic feasibility to predict the appropriate range of the purchase price of 2,3-BDO on commercial scale. The conceptual design and economic analysis can offer valuable information for the industrial application of 2,3-BDO because the most relevant studies have limitation in laboratory scale. Furthermore, the adequate range of 2,3-BDO price, in which the process has profitability, was investigated with the current market prices of 1,3-BD. The investigated price in terms of 2,3-BDO dehydration can pertain to estimation of the economic feasibility in 2,3-BDO production process.

• 폴리머
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• 제38권1호
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• pp.103-107
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• 2014

이축압출공정을 이용하여 poly(acrylonitrile-butadiene-styrene)(ABS)에 titanium dioxide($TiO_2$), barium sulfate($BaSO_4$), calcium carbonate($CaCO_3$)를 함량별로 첨가하여 복합체 쉬트를 제조하였고 복합체 쉬트의 반사율과 굴곡 탄성률을 측정하였다. ABS에 첨가된 충전제의 분산성이 우수한 것을 형태학을 통해 알 수 있었다. $TiO_2$와 $BaSO_4$의 함량에 따라 복합체 쉬트의 반사율이 증가하였고, 특히 $TiO_2$ 20 wt%에 $BaSO_4$를 5~20 wt%를 첨가한 복합체 쉬트의 경우 반사율이 95%이상이 얻어졌다. 굴곡 탄성률 또한 $TiO_2$와 $BaSO_4$의 함량에 따라 증가하여 $ABS/TiO_2/BaSO_4$ 조성비 85/10/5(w/w/w)의 1864 MPa에서 $ABS/TiO_2/BaSO_4$ 조성비 55/20/25(w/w/w)의 3134 MPa로 증가하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.36-36
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• 2010

Low-pressure fluorocarbon plasmas are widely used in microelectronics fabrication for a variety of surface modification purposes. In particular, fluorocarbon plasmas are used for the etching of dielectrics such as silicon dioxide and silicon nitride. Among the various fluorocarbons, this study focuses on C4F6 molecules (C4F6s) which are composed of hexafluorocyclobutene (c-C4F6), hexafluoro-1, 3-butadiene (1, 3-C4F6), and hexafluoro-2-butyne (2-C4F6). We have investigated the dissociation reactions of C4F6s, resulting in CF2, CF3, C2F3, and C3F3 fragments, by using the wB97X-D functional with various basis sets. In this presentation, the geometrical properties, energetics, and dissociation mechanisms of C4F6s will be suggested.

• Bulletin of the Korean Chemical Society
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• 제31권2호
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• pp.503-506
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• 2010

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 하계학술대회 논문집
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• pp.648-651
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• 2001

We studied about luminance characteristics of blue organic electroluminecent device as thickness ratio. The device is fabricated TPD(N,N'-dyphenyl-N-N'-bis(3-methyphenyl) -1,1'-biphenyl-4,4'-diamine) as hole transport layer and Butyl -PBD(1,1,4,4-Tetraphenyl-1,3-butadiene) as emission layer and electron transport layer. Total thickness is 1000${\AA}$ as HTL and ETL, each devices has 500${\AA}$:500${\AA}$. 400${\AA}$:600${\AA}$ and 600${\AA}$:400${\AA}$ of TPD : Butyl-PBD. We obtained the maximum brightness about 175cd/㎡ 500${\AA}$: 500${\AA}$ thickness devices as HTL:ETL

• Macromolecular Research
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• 제15권4호
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• pp.308-314
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• 2007

The effects of a compatibilizer on polypropylene (PP)/poly(acrylonitrile-butadiene-styrene) (ABS) blends were studied. Blends of the PP/ABS, with PP-g-SAN copolymer as a compatibilizer, were prepared using a twin screw extruder. The flexural and impact strength of the PP/ABS blends with the PP-g-SAN copolymer increased significantly with PP-rich compositions on the addition of the PP-g-SAN copolymer at 3 phr. The increase in the mechanical properties of the PP/ABS/PP-g-SAN blend may have been due to the toughening effects of the ABS in the PP-rich compositions. In the morphology study of the PP/ABS/PP-g-SAN (80/20) blend with the PP-g-SAN copolymer, the minimum droplet size, $5.1{\mu}m$, was observed with the addition on phr of the PP-g-SAN copolymer. The complex viscosity of the PP/ABS/PP-g-SAN (80/20) blends increased with the addition of3 phr of the PP-g-SAN copolymer. From the above mechanical properties, morphology and complex viscosity results for the PP/ABS blends, it is suggested that the compatibility is more increased with the PP-rich composition (PP:ABS=80/20 wt%) of the PP/ABS blend on the addition of 3 phr of the PP-g-SAN copolymer.

• Elastomers and Composites
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• 제7권1호
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• pp.38-44
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• 1972

As a series of the studies of EPDM-polymer blonds, the experiments are concentrated to the investigation of the physical properties of the EPDM-BR blends. The results are shown as follows: 1. In blending, tensile strength and elongation decreased with increase in EPDM contents. 2. The resistance for aging and ozone were much improved after blending. It was effective more :han the ratio of EPDM/BR is 50/50. 3. Tear strength is less influenced after blending and rebound character decreased with increase in EPDM contents.

• 한국응용약물학회:학술대회논문집
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• 한국응용약물학회 1993년도 제2회 신약개발 연구발표회 초록집
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• pp.119-119
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• 1993

안트라싸이클린계 항암항생제의 부작용 발생기전으로는 C-고리의 퀴논 부위에 전자가 전달되어 퀴논 고리가 환원되는 과정이 제시되고 있으며 그 중 하나의 전자가 전달되어 생성되는 활성산소(activated oxygen)가 심장독성과 관련이 있는 것으로 알려져 있다. 이 때 퀴논 고리의 환원력(전자흡수능력)이 C-고리자체의 변환, 또는 인접 B-고리에 도입된 치환체의 영향으로 억제될 수 있다는 보고를 이론적 근거로 하여 안트라싸이클리논 골격을 전자흡수 능력을 가진 acridone 골격으로 치환한 화합물(1)과 안트라싸이클리논 골격을 유지하면서 aminosugar 부위를 pentopyranose계열을 도입 한 2 합성하였다. 화합물 1은 1,3-butadiene 과 1,4-benzoquinone 의 Diels-Alder adduct 3을 출발물질로 하여 7 단계의 반응과정으로 합성하였다.

• 통합자연과학논문집
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• 제2권2호
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• pp.65-68
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• 2009

Siloles of considerable current interest, both because of their unusual electronic properties and because of their possible application as electron-transporting materials in devices such as light-emitting diodes (LED's) and chemical sensor. Siloles have been characterized by NMR, FT-IR, and UV-vis absorption spectroscopy. Their optical characteristics have been also investigated using photoluminescence spectroscopy. Thus siloles exhibit a low reduction potential and a low-lying LUMO energy level, attributed to ${\sigma}^*-{\pi}^*$ conjugation arising from the interaction between the ${\sigma}^*$ orbital of the sigma-bonded silicon atom and the $\pi^*$ orbital of the butadiene moiety of the ring.