• 한국결정학회지
• /
• 제10권2호
• /
• pp.130-135
• /
• 1999

The title compound consisting of a calix[4]arene molecule with four phenyl rings bridged by four methylene groups and arranged alternately in anti-orientation fashion, two 25,27-bis(1-pro-pyloxy) groups attached on the two lower rims of calix[4]arene, and crown-6 chain attached on the other set of lower rims of calix[4]arene offers a big cavity inside a molecule which might possess a potential for forming host-guest complexes. The molecular packing is accomplished by van der Waals forces.

• 대한화학회지
• /
• 제21권3호
• /
• pp.187-192
• /
• 1977

2-amino-5,6-dimethoxy-1,2,3,4-tetrahydronaphthalene hydrochloride를 2-nitro-3,4-dihydro-5,6-dimethoxy-(2H)-naphthalenone으로부터 합성하여서 Neber rearrangement로부터 얻은 2-amino-3,4-dihydro-5,6-dimethoxy-1(2H)-naphthalenone hydrochloride로부터 합성한 방법과 수득률 및 실업적인 조작을 비교 설명하였다.

• 식물병연구
• /
• 제14권2호
• /
• pp.102-106
• /
• 2008

Bacillus subtilis QST713(BS QST713)의 단독, 살균제와 혼합 및 교호처리하여 인삼 점무늬병의 방제효과를 검정하였다. BS QST713를 10일 간격으로 단독으로 처리했을 때, 인삼 점무늬병에 대한 방제가는 83.3%, azoxystrobin, chlorothalonil copper sulfate basic, copper sulfate basic, kresoxim-methyl, difenoconazole, mancozeb 단독 처리구는 $80.4{\sim}83.7%$로 나타났다. BS QST713와 mancozeb를 혼합하여 14일 간격으로 처리하였을 때의 방제가는 83.6%, BS QST713와 azoxystrobin 혼합 처리구는 82.6%이었으나, difenoconazole, kresoxim-methyl, copper sulfate basic 및 chlorothalonil copper sulfate basic와 혼합 처리구는 $61.1{\sim}76.4%$로 방제효과가 약간 감소하였다. 대전에서 BS QST713와 copper sulfate basic를 10일 간격으로 교호처리시 방제가가 85.9%이었으나, 다른 살균제와의 교호처리 시는 $55.5{\sim}78.2%$로 낮아 졌다. 그러나 무주에서 모든 교호처리에서 방제가가 90% 이상으로 나타났다. 이상의 결과에 의하면 BS QST713의 단독, 혼합 및 교호처리는 살균제의 사용량을 줄일 수 있는 방제법으로 이용될 것이다.

• 대한치과교정학회지
• /
• 제49권1호
• /
• pp.49-58
• /
• 2019

Objective: The aim of this retrospective study was to evaluate and compare the changes in the pharyngeal airway (PA), maxillary sinus volume, and skeletal parameters after rapid maxillary expansion (RME) and alternate rapid maxillary expansion and constriction (Alt-RAMEC) followed by facemask (FM) therapy. Methods: The records of 40 patients with skeletal Class III malocclusion due to maxillary retrognathism were collected, and the patients were assigned into two groups. The first group comprised 8 male and 12 female patients (mean age, $10.0{\pm}1.1years$) treated using RME/FM for an average of 10 months. The second group comprised 10 male and 10 female patients (mean age, $9.64{\pm}1.3years$) treated using Alt-RAMEC/FM for an average of 12 months. Cone-beam computed tomography images acquired before (T0) and after treatment (T1) were evaluated. Results: Regarding the skeletal effects, significant differences between the groups were the increase in ANS-HRP (perpendicular distance of ANS to the horizontal reference plane, 0.99 mm, p <0.05) in the Alt-RAMEC/FM group and the decrease in PP-SN (palatal plane to Sella-Nasion plane, $0.93^{\circ}$, p < 0.05) in the RME/FM group. Maxillary sinus volumes increased significantly in both the groups, and the increase was statistically significantly higher in the Alt-RAMEC/FM group. Although no significant intergroup differences were observed in PA volumes, both lower ($1,011.19mm^3$) and total ($1,601.21mm^3$), PA volume increased significantly in the Alt-RAMEC/FM group. Conclusions: The different expansion devices and protocols used with FM therapy do not seem to affect the forward movement of the maxilla and PA volumes. In contrast, the increase in maxillary sinus volume was greater in the Alt-RAMEC/FM protocol.

• Bulletin of the Korean Chemical Society
• /
• 제31권11호
• /
• pp.3247-3251
• /
• 2010

Molecular structures of the various conformers for the four stereoisomers of tetra-t-butyl-tetra-O-methylsulfinylcalix[4]arene (1) were optimized using DFT BLYP and mPW1PW91/6-31G(d,p) (hybrid HF-DF) calculation methods. We have analyzed the total electronic and Gibbs free energies and normal vibrational frequencies of 16 different structures from four major conformations (cone (CONE), partial cone (PC), 1,2-alternate (1,2-A), 1,3-alternate (1,3-A)) of the four stereoisomers [1(rccc), 1(rcct), 1(rctt), 1(rtct)]. The mPW1PW91/6-31G(d,p) calculations suggested that the $1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, and $1(rtct)_{1,3-A}$ were the most stable conformations of the respective stereoisomers. These outcomes are in accordance with the experimental structures obtained from X-ray crystallography. The electrostatic repulsion between the sulfinyl and methoxy groups is a primary factor for the relative stabilities of the four different conformations. The IR spectra of the most stable conformers [$1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, $1(rtct)_{1,3-A}$] of each stereoisomer were compared to each other.

• 말소리와 음성과학
• /
• 제7권3호
• /
• pp.55-64
• /
• 2015

Previous research on syntactic processing shows that the interpretation of a syntactically ambiguous sentence is frequently strongly biased towards one meaning over another. The current study investigated the effect of bias strength on the production of disambiguating prosody for English ambiguous sentences. In Experiment 1, 40 speakers gave default readings of 18 syntactically ambiguous sentences. Questioning was used to prove intended meanings behind default readings. Intended meanings were treated as interpretation biases when a majority of speakers read a sentence with the same intended meaning. The size of the majority was used to establish bias strength. In Experiment 2, 10 speakers were instructed to use prosody to disambiguate given alternate meanings of the sentences from Experiment 1. The results indicated an effect of bias strength on disambiguating prosody: speakers used temporal juncture cues to reliably disambiguate alternate meanings for sentences with a weak interpretation bias, but not for those with a strong bias. Overall, the results indicated that interpretation biases strongly affect the production of prosody.

• Bulletin of the Korean Chemical Society
• /
• 제20권8호
• /
• pp.905-909
• /
• 1999

Reaction of tetrahomodioxa p-phenylcalix[4]arene with ethyl bromoacetate and potassium carbonate in ace-tone leads to the title tetra ester derivative, 7,13,21,27-tetra-phenyl-29,30,31,32 -tetrakis(ethoxycarbonyl)meth-oxy-2,3,16,17-tetrahomo-3,17-dioxacalix[4]arene, its structure was determined by NMR spectra as 1,4-alternate conformation. The molecular structure has been solved by X-ray diffraction methods. The molecule has a conformation with pseudo center of symmetry. The benzene ring A is up, ring C is down, B and D rings are flat with respect to the plane of the macrocyclic ring.

• Bulletin of the Korean Chemical Society
• /
• 제15권6호
• /
• pp.483-488
• /
• 1994

Tetra acyl esters of p-tert-butylcalix[4]arene and calix[4]arene, including acetyl, propionyl, butyryl and isobutyryl, are synthesized and their conformations are inferred from $^1H-NMR$ and $^{13}C-NMR$ spectra. The conformer distribution is affected by the presence of t-butyl group, whereas the acylation products of p-t-butylcalix[4]arene are the cone conformers, those of calix[4]arene are mostly partial cone and/or 1,3-alternate conformers. The conformational outcome is also affected by the method of preparation, the NaH-induced reaction is prefered to the acid-induced reaction for cone and partial cone. Interestingly, 1,2-alternate conformer was isolated in 14% yield from the butyrylation of calix[4]arene.

• 대한화학회지
• /
• 제53권5호
• /
• pp.521-529
• /
• 2009

1,3-디메톡시-티아캘릭스[4]크라운-5-에테르 (3)의 다양한 이형체들(cone_oo, cone_oi, pc_oo, pc_io, pc_oi, pc_ii, 13a_oo, 13a_io)에 대한 구조들이 DFT B3LYP/6 - 31 + G(d,p)와 mPW1PW91/6 - 31 + G (d,p) (hybrid HF-DF) 계산 방법들에 의하여 최적화 되었다. 13a_oo (1,3-alternate 이형체에서 두 개의 메 톡시기가 모두 밖으로 향해 있는 구조)가 가장 안정하였으며, 기존에 보고된 실험 결과와 잘 일치하였다. mPW1PW91/6 - 31 + G(d,p) 계산에 의한 상대적인 안정성은 다음과 같았다: 13a_oo (가장 안정) > 13a_io$\sim$ pc_io$\sim$cone_oo > cone_oi$\sim$pc_oo$\sim$pc_oi > pc_ii.

• 여성건강간호학회지
• /
• 제14권3호
• /
• pp.173-180
• /
• 2008

Purpose: This study was to explore the perception about menstruation and discomforts of using disposable menstrual pads in menstruating women. Method: A survey was conducted of 132 menstrual women recruited by convenience sampling. Data were collected by a face-to-face interview and a study questionnaire, and analyzed by frequency and $X^2$-test. Result: More than half of the subjects expressed a negative perception about menstruation, while 25% expressed a mixed perception and 24.2% expressed a positive perception. Women who perceived their menstruation negatively had more menstrual pain than the others (p<.001). The most frequently experienced discomforts of using disposable pads were an unpleasant smell (18.9%), leakage (18.9%), and discomfort (16.6%). Adverse effects of using disposable pads were reported as an itching sense (23.1%). skin rash (20.2%), and skin irritation (10.6%). Alternate materials were reported with tampons, alternate washable pads, and maternity pads. Conclusion: The results indicate that disposable menstrual pads cause several discomforts and common adverse effects such as skin problems. To decrease these discomforts and relieve adverse effects, planned nursing education including women's personal hygiene methods and information about an alternate pad may be helpful.