• Title/Summary/Keyword: 흡착율

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Changes in Physical and Chemical Properties of Sandy Loam Soils by Hematite Addition (적철석 첨가에 의한 사질양토의 물리·화학적 특성변화)

  • Kim, Jae Gon;Dixon, Joe B.;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.31 no.4
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    • pp.291-296
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    • 1998
  • Pedogenic hematite is a well known agent for sink of pollutants and nutrients and for aggregation of particles in soils. Changes in physical and chemical properties of two sandy loam soils (Anahuac and Crowley soils) from the Southern Coastal Plain, the United States of America, were tested after adding finely ground crystalline hematite prepared for drilling fluid weighting material. There was an increase in hydraulic conductivity (HC) of the soils with addition of up to 3% by weight of hematite but a decrease in HC with addition of more hematite. The aggregate stability (AS) of the soils was not affected by adding hematite. Anahuac soil with higher content of organic matter and lower sodium adsorption ratio (SAR) had higher values of HC and AS than Crowley soil. Adding hematite also resulted in a slight increase in zinc (Zn) adsorption by the soils, but had no influence on the adsorption of phosphate.

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Studies on the Synthesis of Aminated PP-g-GMA Fibrous ion Exchanger by E-beam Pre-irradiation and Their Properties of Selective Adsorption for $NO_{3} ^{-}$ (E-beam 전조사에 의한 $NO_{3} ^{-}$ 선택 흡착용 아민화 PP-g-GMA 섬유 이온교환체의 합성과 그 특성에 관한 연구)

  • 황택성;이선아;이면주
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.153-159
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    • 2002
  • In order to remove $NO_3;^-$ ion from ground-water, fibrous ion -exchangers, APP-g-GMA, were synthesized by GMA grafting onto PP trunk polymer with E-beam accelerator for pre-irradiation. Their degrees of grafting and amination yield increased up to $60^{\circ}C$ and showed maximum values as 133%, 88%, respectively. And their swelling ratio and ion exchange capacity at the maximum values are 86%, 2.5 meq/g, respectively which was higher than commercial ion-exchangers such as IMAC HP555 and Amberlite IRA 400. Optimum adsorption condition of $NO_3;^-$ ion was measured at pH 5~6 and -Cl form of APP-g-GMA containing trimethylammonium group showed the highest adsorption capacity.

Packing Tower Design of Waste Oyster Shells using Bohart-Adams Equation (Bohart-Adams 식을 이용한 폐굴껍질 충진탑의 설계)

  • Kim, Eun-Ho;Kim, Seok-Taek;Kim, Il-Bae;Kim, Hyeong-Seok
    • Korean Journal of Environmental Agriculture
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    • v.18 no.3
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    • pp.209-214
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    • 1999
  • Objective of the research is to estimate neutralization capacity and to determine practical running parameters required in packing tower design of waste oyster shells using Bohart-Adams equation. It is expected that waste oyster shells are able to be recycled for removal of heavy metals through neutralization of plating wastewater because those contain approximate 93% $CaCO_3$. By applying the results of the continuous experiment to Bohart-Adams equation, service time decreases in the order of Cr>Fe>Cu, while removal efficiencies of metals become less in the order of Fe>Cr>Cu.

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Effects of Storage Duration, Medium and Viscin on in vitro seed Germination in Endangered Species, Loranthus tanakae (저장기간, 배지종류 및 viscin이 멸종위기종 꼬리겨우살이의 기내 종자발아에 미치는 영향)

  • Lee, Su-Gwang;Lee, Song-Hee;Kang, Ho-Duck
    • Journal of Korean Society of Forest Science
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    • v.99 no.4
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    • pp.618-624
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    • 2010
  • This study was conducted to establish the in vitro seed germination of Loranthus tanakae. A factorial experiment evaluated the effects of seed storage duration (0, 8, 16 weeks), media (MS, SH, White, WPM), presence of viscin, GA3, gelling agent and concentrations. Seed germinated after one week culture in in vitro condition and produced radicles. In vitro seed germination was optimal when the seeds removed viscin placed on SH medium (69%) and the addition of 0.35% gelrite (75%) in the same medium. As seed storage duration was expanded to 8 or 16 weeks, in vitro seed germination rate was reduced rapidly. Holdfasts were also produced at the side of radicles. The important factors to produce holdfast and haustorium was kind of media as an optimal condition in White medium without any supplements to be shown 98% and 8% respectively. Process of in vitro germination of Loranthus tanakae was followed to radicle elongation, holdfast development and then haustorium formation sequencially.

Synthesis and Characterization of Zeolite Using Water Treatment Sludge (정수슬러지를 이용한 제올라이트의 합성 및 특성연구)

  • Ko, Hyun Jin;Ko, Yong Sig
    • Clean Technology
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    • v.26 no.4
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    • pp.263-269
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    • 2020
  • Zeolite was synthesized hydrothermally using the water-treatment sludge, and the effects of various synthesis parameters like reaction temperature, reaction time, and Na2O/SiO2 molar ratio on the crystallization of zeolite were investigated. Crystal structure, physical property, and thermal stability of zeolite crystals were characterized by X-ray powder diffraction, FTIR spectroscopy, BET nitrogen adsorption, and TGA measurements. The removal efficiencies of nitrogen in ammonia, heavy metal ions, and TOC were calculated to evaluate zeolite's adsorption capacity. The primary chemical composition of water-treatment sludge was 28.79% Al2O3 and 27.06% SiO2. The zeolites were synthesized by merely employing the water-treatment sludge as silica and alumina sources without additional chemicals. Zeolite crystals synthesized through the water-treatment sludge were confirmed as an A-type zeolite structure. Zeolite A had the highest crystallinity obtained from a gel with the molar composition 2.1Na2O-Al2O3-1.6SiO2-65H2O after 5 h at a temperature of 90 ℃. The specific surface area of zeolite obtained was 55 ㎡ g-1, which was higher than commercial zeolite A. The removal efficiency of nitrogen in ammonia was 68% after 3 h of reaction time, while the removal efficiencies of Pb2+ and Cd2+ ions were 99.1% and 99.3%, respectively. These results indicate active ion exchange between Pb2+ or Cd2+ ion and Na+ ion in the zeolite framework. The adsorption experiments on the different zeolite addition conditions were performed for 3 h with 300 ppm humic acid. Based on the results, TOC's highest efficiency was 83% when 5 g of zeolite was added.

Synthesis of Aminated PP-g-styrene Fibrous Ion-Exchanger for Separation of Boron from Ground-Water (지하수로부터 붕소이온 분리를 위한 아민화 PP-g-styrene 이온교환체 섬유의 합성과 붕소 음이온 흡착에 관한 연구)

  • Hwang, Taek-Sung;Lee, Jin-Hyok;Lee, Myun-Joo
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.451-459
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    • 2001
  • Fabric ion-exchanger, aminated PP-g-styrene was synthesized with styrene monomer onto PP staple fiber by pre-irradiational grafting with E-beam and subsequent chloromethylation and amination. Degree of grafting was increased with increasing the styrene monomer concentration and the highest degree of grafting was obtained 118% at a monomer concentration of 80% styrene. Optimum condition of Mohr's salt and sulphuric acid were 1.0 ${\times}\;10^{-3}$ M and 0.1 M. Amount of amination was increased with increasing degree of grafting. Swelling ratio of aminated PP-g styrene was higher than that of trunk polymer. Ion-exchange capacity was 6.7 meq/g, which was three times greater than commercial ion-exchanger. Optimum condition of baron ion adsorption was pH 4 and amount of adsorption were increased with increasing the amount of amination.

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Changes of Carbohydrate Composition and Enzyme Adsorption on the Hydrolysis of Steam Exploded Wood by Cellulase (Cellulase에 의한 폭쇄재의 가수분해에 있어서 탄수화물조성 및 효소흡착량 변화)

  • Yang, Jae-Kyung;Kim, Chul-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.29 no.4
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    • pp.67-78
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    • 2001
  • Two species(Quercus mongolica, populus euramericana) of hardwood chips were subjected to steam explosion 25 kg/$cm^2$, for 6 min. The exploded woods were treated by the single or multi-stage chemical process with sodium hydroxide, sodium hypochlorite and sodium chlorite. The multi-stage treatment of exploded wood can be successfully removed lignin. Enzymatic hydrolysis rate of substrate varied from 25% for exploded wood to about 80% for the multi-chemical treated exploded wood. The enzymatic susceptibility was different among wood species. The multi chemical treatment of the exploded wood resulted in the high rate of glucose in the enzymatic hydrolyzate. Cellulase adsorption increased at high lignin content of substrates, while crystallinity, pore area and specific surface area of substrates did not affected enzyme adsorption. According to the proposed pretreatment and saccharification process in this study, it can be acquired about 37~40 kg of glucose from 100 kg of hardwood.

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Synthesis of Naphthalene Superplasticizers and Their Interaction with Cements (나프탈렌계 고성능감수제의 합성 및 그들의 시멘트와의 상호작용)

  • 김화중;강인규;황재현;김성훈
    • Magazine of the Korea Concrete Institute
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    • v.5 no.2
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    • pp.121-128
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    • 1993
  • 나프탈렌 또는 나프톨을 황산화하고 포름알데히드와 축합 반응시켜 나프탈렌 축합물 및 나프톨 축합물을 합성하였다. 또한, 나프탈렌과 나프톨을 모두 함유하는 공축합물도 합성하였다. 이들 축합물의 확인은 핵자기공명스텍트럼, 적외분광스펙트럼, 자외분광스펙트럼으로 행하였다. 한편 이들 축합물들의 시멘트에 대한 분산성을 예측하기 위하여 시멘트 표면에의 흡착실험을 행하였다. 그 결과 수산기를 함유하는 나프톨 축합물(TSC)>나프탈렌-나프톨공축합물(NSS)의 순으로 시멘트에 대한 흡착율이 증가했다. 위의 결과들로부터 주쇄(main chain)에 나프톨을 함유하는 합성축합물(TCS, NT5)은 시멘트분산제로서의 가능성이 시사되었다.

Development of pre-filter for airconditioner using of illite found in youngdong area (영동산 일 라이트를 이용한 공조기의 프리필터 개발)

  • 김진철;구경완;류명환;한위생
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.507-510
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    • 2001
  • 본 논문은 일 라이트의 항균 방취 및 세균 흡착 능력을 공기조화기 및 공기청정기의 프리필터로 함침하여 사용함으로서 필터의 탈취 시험결과는 암모니아, 메틸멀캅탄, 트리메틸아민, 황화수소를 가지고 실험결과 거의 모든 가스를 흡착하였고 필터의 항균시험 결과 두가지의 균주를 사용하였는데 균주 1 - Staphylococcus aureus ATCC 6538과 균주 2 - Escherichia coli ATCC 25922는 균 감소율이 99.9% 이상을 보였다. 따라서 본 논문이 의도하였던 모든 특성을 만족한 결과가 도출되었다.

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고정화 $TiO_2$와 유동층 반응기를 이용한 Rhodamin B의 색도 제거

  • 박영식
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11b
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    • pp.295-299
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    • 2003
  • 1. 고정화 $TiO_2$의 경우도 분말을 이용한 것과 같이 최적 광촉매 투입량이 나타났으며, 최적 투입량은 33.8 g/L이었고, 분말 $TiO_2$를 이용한 경우보다 빠른 초기반응속도를 보였으며, 최종반응시간도 빠른 것으로 나타났다. 2. 수용액에서 빠른 초기 제거속도의 1차적인 기작은 고정화 $TiO_2$ 표면으로의 흡착 때문이었으며, 빠른 흡착으로 인해 수용액 중의 RhB 농도가 빠르게 감소하여 광 투과율이 증가하므로 전체 반옹속도가 빠른 것으로 사료되었다. 3. 고정화 $TiO_2$를 이용한 유동층 반응기의 경우 최적 공기 공급량은 의한 Rhodamine B의 초기 제거속도는 분말보다 빠르지만 전체적인 제거시간은 흡착된 Rhodamine B의 분해 때문에 분말 $TiO_2$보다 느린 것으로 나타났다.

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