• Membrane Journal
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• v.10 no.3
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• pp.139-147
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• 2000

Non-Fickian (or anomalous) diffusion was observed in transient sorption of aromatic solvents(such as benzene, toluene, and chlorobenzene) in fluoropolymers (such as ETFE, ECTFE and PVDF). In this study, five other transient sorption models (Crank, Long ＆ Richman, Berens ＆ Hopfenberg, Neogi, Li) based on Fick's law were employed to fit the anomalous sorption data for aromatic solvents. The adjustable parameters were determined by least square analysis of the measured and predicted fractional uptake. For ETFE sorption data slightly deviating from Fickian behavior, all the models exhibited satisfactory results in fitting the anomalous sorption data. In particular, Neogj model predicted intrinsic diffusivity (0.4～0.8$\times$10$^{-5}$ $\textrm{cm}^2$/day) and equilibrium diffusivity (0.13～0.31$\times$10$^{-4}$ $\textrm{cm}^2$/day) as well as relaxation kinetics related to non-Fickain diffusion. For a typical sigmoidal sorption behavior in PVDF, only Crank's model could give the reasonable evaluation on transport properties. The ratio of intial diffusivity (D$_{i}$) to final equilibrium diffusivity (D$_{\infty}$) was ranged from 80 to 200. For the final stage of uptake In ECTFE with drastic acceleration, all the models exhibited significant deviations from the sorption data. New diffusion models based on thermodynamics and continuum mechanics should be employed to get valuable information on transport properties as well as relaxation kinetics coupled with non-Fickian diffusion.

• The Journal of the Acoustical Society of Korea
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• v.10 no.6
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• pp.77-81
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• 1991

단백질수용액중의 초음파흠수 mechanism을 규명하기 위하여 천연단백질인 egg white의 초음파 흡수측정을 주파수 0.2-10MHz, 온도 10-50℃에서 행하엿다. 측정방법은 0.2-10MHz 주파수범위에서 초 음파흡수측정이 가능한 plano-concave 공명법을 사용하였다. 그 결과 0.2-10MHz의 주파수범위에 대해 흡수계수는 측정한 전 온도에서 주파수의 1.25(±0.02) 승에 비례하고, egg white의 농후부분과 수용성부 분 및 aging 효과에 대한 음향학적인 차는 나타나지 않았다.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2010.10a
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• pp.13-15
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• 2010

본 논문에서는 Flake Sendust 금속분말을 이용하여 ISM 대역에서 PCB 노이즈 억제용 전파흡수체를 설계 제작하고 검토한 결과를 보고한다. 먼저 자성손실 재료인 Sendust 금속분말을 사용한 전파흡수체의 특성을 예비 시험한 후, 그 특성을 개선하기 위하여 Flake Sendust 분말과 CPE의 조성비를 각각 60 : 40 wt.%, 70 : 30 wt.%, 80 : 20 wt.%로 하고, 두께 1 mm, 2 mm의 sheet형 전파흡수체 샘플을 제작하였다. Network Analyzer를 이용하여 제작한 샘플의 반사계수를 측정하고, -2법으로 재료정수(복소비유전율, 복소비투자율)을 계산하였다. 계산된 재료정수값을 이용하여 최적의 전파흡수체를 설계하여, 조성비 Flake Sendust : CPE = 70 : 30 wt.%, 두께 0.55 mm의 전파흡수체를 제작하였다. 이 전파흡수체는 2.44 GHz 대역에서 5.45 dB의 흡수능을 나타냄으로써 목표치인 5 dB를 달성하였다.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2004.04a
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• pp.23-27
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• 2004

Developing of electromagnetic wave absorbers for GHz frequency, we used cast Alnico magnets. It is the first research paper to show that electromagnetic wave absorbers with Alnico magnets have good reflectivity in the GHz frequencies. Especially in this study, we used recycled cast Alnico magnets for natural resources problems and natural environment problems. New electromagnetic wave absorbers developed in this study are useful for X-band and C-band.

• Proceedings of the Optical Society of Korea Conference
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• 2000.02a
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• pp.166-167
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• 2000

일반적으로 수십 피코초 레이저 펄스를 이용한 GaAs bulk 상태 시료의 비선형 흡수 관찰 실험에서는 200Mw/$cm^{2b}$ 이하에서는 여기된 자유전하 운반자 흡수효과는 무시한다.$^{(1)}$ 그러나 수 나노초의 레이저 펄스를 이용할 경우, 이광자 흡수에 의해 여기된 자유전하 운반자들이 긴 수명시간으로 인해 재결합되지 않고 여기된 상태에 축적되어 짐에 따라, 레이저 빛을 재흡수 하는 확률이 높아져 낮은 세기의 빛에도 불구하고 비선형 흡수 효과가 크게 나타난다.$^{(2)}$ 불순물이 첨가되지 않은 GaAs bulk 상태의 경우 자유전하 운반자 소멸 시간은 수 나노초 영역으로 알려지고 있다.$^{(4)}$ 본 실험에서는 수 MW/$cm^2$의 매우 낮은 영역의 세기에서 순수한 GaAs의 bulk에 대하여 실험한 결과 비선형 흡수가 나타남을 관찰하였으며, 더불어 자유전하 흡수 계수를 여러 가지 세기의 빛에서 측정한 결과 자유전하 흡수 단면적이 빛의 세기에 따라 변화하는 것을 관찰하였다. (중략)략)

• Applied Chemistry for Engineering
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• v.21 no.1
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• pp.71-75
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• 2010

The efficient performance of absorber is of great importance for the absorption heat pump cycle. The experimental study of absorber with spiral tube of tangential feeding of liquid phase has been investigated using methanol-glycerine as a working fluid. The effect of change in absorber operating conditions was analyzed to improve the performance. The increase in solution flow rate and cooling flow rate positively affects the absorber performance while an increse in the solution concentration negatively affects the absorber performance. The results showed that mass absorption flux was in the range of $0.2{\sim}0.6kgm^{-2}sec^{-1}$, the solution heat transfer coefficient between 1.6 and $4.2kwm^{-2}K^{-1}$, the absorber thermal load from 0.9 to 1.5kw and the mass transfer coefficient from 0.9 to 1.7 m/sec.

• Korean Chemical Engineering Research
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• v.54 no.5
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• pp.648-652
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• 2016

The study of $CO_2$ absorption in a packed column by 1,1,3,3-tetramethylguanidine (TMG) dissolved in ethylene glycol is presented. Absorption column of inner diameter 1 in and 0.6 m length was filled with Protruded-packing $0.16in{\times}0.16in$. We investigated the effect of operating conditions on overall mass transfer coefficients as well as on $CO_2$ removal efficiency. The loading values reached at about $1.0mol_{CO2}/mol_{TMG}$. In case of absorbent with lean $CO_2$ loading, the overall mass transfer coefficient was proportional to the concentration of TMG. However, in the range of more than ${\alpha}=0.5molCO_2/molTMG$, the overall mass transfer coefficients decreased with the concentration of TMG. It is due to the increasing of mass transfer resistance in liquid phase as increasing of viscosity at higher loading values.

• Korean Journal of Environment and Ecology
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• v.14 no.2
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• pp.119-126
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• 2000

충남 사문암 지역인 광천, 홍성, 백동, 대흥 및 유구지역의 토양, 식물체(참억새, 쑥, 리기다소나무) 및 지표수, 갱내수의 중금속 함량을 분석한 결과 사문암 토양의 Ni, Cr 및 Co 원소가 변성암 토양에 비하여 10~13배높았으며 이 원소들이 serpentine factor로 생각된다 사문암 지역간에는 이들원소의 차이가 뚜렷하지 않았다 변성암 토양식물에서보다 사문암 토양 식물에서 Ni, Cr, Co등이 높았다 리기다소나무의 원소 흡수량은 비교적 낮았고 3종 식물에서 대체로 뿌리의 원소 함량이 지상부 함량보다 높았으며 사문암 토양에서는 Ni, Cr, Co, Mo, Sc, As 및 Fe 원소들이 쑥보다 참억새에서 높았다 사문암 토양에서 생육하는 식물체 지상부의 생물학적 흡수계수는 Ni, Cr, Co, Zn, Sc, As 및 Fe 원소는 참억새에 높고Zn은 쑥에서 높았다,. 사문암 토양에서 뿌리로부터 지상부로의 원소 전이는 Ni, Cr, Co, Zn As 및 Fe 원소에 대해 쑥에서 높았고 Mo와 Sc 원소는 리기다소나무에서 높았다. 따라서 사문암 토양에서 참억새가 중금속의 흡수율은 높고 중금속에 대한 내성은 강할 것으로 사료된다 대흥지역에서 광산의 오염이 지표수 및 갱내수의 Ni. Cr, Co, Zn 및 Fe 등의 원소 농도를 높게 하였으며 비오염 계류는 오염계류의 원소 농도를 희석시켰다.

• Journal of the Korean Geosynthetics Society
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• v.10 no.3
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• pp.25-32
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• 2011

The matric suction and volumetric water content of dredging soils obtained from Saemangeum area were measured by the automated Soil-Water Characteristic Curve (SWCC) apparatus under both drying and wetting conditions. Based on the test result, SWCCs of the dredging soils were estimated by the van Genuchten(1980) model. The matric suction of drying process is larger than that of wetting process at a same effective degree of saturation. The suction stresses for various matirc suctions were estimated using Lu and Likos(2006) model and the Suction Stress Characteristic Curves (SSCC) were predicted using the independent parameter of SWCC. The suction stress of drying path was increased and decreased, while the suction stress of wetting path was continuously decreased with increasing the effective degree. Also, the suction stress of drying path is larger than that of wetting path at a same effective degree of saturation. The Hydraulic Conductivity Function(HCF) was also predicted by the van Genuchten(1980) model. The hydraulic conductivity was increased with increasing the volumetric water content. The hydraulic conductivity of drying path is larger than that of wetting path at a same matric suction. According to the results of SWCCs and SSCCs, the hysteresis phenomenon of suction stress or matric suction during both drying and wetting paths was occurred. The main reason of hysteresis phenomenon is a ink bottle effect of water among soil particles.

• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.582-587
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• 2022

Biphasic solvents are attracting attention as energy-reducing solvents for capturing CO₂ from flue gas in combustion process. In this study, considering diethylenetriamine (DETA) and diethylethanolamine (DEEA) mixed solvents, one of the biphasic solvents by blending of two types of amines, the CO₂ absorption rates of DETA and DEEA was measured by wetted wall column. The effects of DETA and DEEA concentrations and operating temperature on the overall mass transfer coefficient were investigated. As a result, the overall mass transfer coefficient was proportional to the DETA concentration. However, in the case of the DEEA concentration, the effect was small and when the concentration was exceeded, the overall mass transfer coefficient decreased. The DETA aqueous solution showed little change in the overall mass transfer coefficient with the operating temperature, whereas the DEEA aqueous solution increased the overall mass transfer coefficient with the operating temperature. As a result of obtaining the observed reaction rate constant under the pseudo-first-order reaction assumption, it was found that the observed reaction rate constant in DETA aqueous solution was proportional to the DETA concentration, but DEEA did not fit the pseudo-first-order reaction assumption.