• Title/Summary/Keyword: 휘발성 물질

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Analysis of Aldehyde Compounds in Air by GC (GC에 의한 대기중 Aldehyde 화합물의 분석)

  • 유혜경;허귀석;김대원;신호상
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.336-337
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    • 2001
  • 악취는 산업이 발전함에 따라 급격히 늘어나는 환경 공해 중의 하나이다. 이 중 알데히드 화합물은 여러 가지 악취물질중의 하나로서 공기 중에 미량으로 존재하면서 냄새를 일으키며, 건강 위해성도 큰 물질이다. 본 연구에서는 휘발성이 강하면서 건강에 유해하여 문제가 되고 있는 이러한 알데히드 화합물 (formaldehyde, acetaldehyde, propionaldehyde, butyraldehyde, benzaldehyde)을 간편하고 신속, 정확하게 분석할 수 있는 방법을 개발하고자 하였다. (중략)

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UV/H2O2 Oxidation for Treatment of Organic Compound-spilled Water (UV/H2O2 산화를 활용한 유기오염물질 유출수 처리용 공정 연구)

  • Kim, Nahee;Lee, Sangbin;Park, Gunn;Park, Jae-Woo
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.10
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    • pp.5-12
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    • 2022
  • In this study, we investigated the UV/H2O2 process to treat organic compound-spilled water. In consideration of usage and properties, benzene, toluene, phenol, and methyl ethyl ketone were selected as representative organic compounds. The selected material was first removed by natural volatilization and aeration that simulated the pretreatment of the prcoess. After that, UV/H2O2 oxidation experiments were conducted under various H2O2 concentration conditions. Benzene and toluene were mostly volatilized before reaching the oxidation process due to high volatility. Considering the volatility, oxidation experiments were performed at an initial concentration of 5 mg/L for benzene and toluene. The UV/H2O2 oxidation process achieved 100% of benzene and toluene removal after 20 minutes under all hydrogen peroxide concentration conditions. The phenol was rarely removed from the volatile experiments and oxidation tests were performed at an initial concentration of 50 mg/L. The process showed 100 % phenol removal after 30 minutes under 0.12 v/v% of hydrogen peroxide concentration condition. Methyl ethyl ketone was removed 58 % after 2 hours of volatile experiments. The process showed 99.7% Methyl ethyl ketone removal after 40 minutes under 0.08 v/v% of hydrogen peroxide concentration condition. It was confirmed that the UV/H2O2 process showed high decomposition efficiency for the four selected organic compounds, and identified the amount of hydrogen peroxide in classified organic contaminants.

Volatile Hazardous Compounds in Alcoholic Beverages (주류 중 휘발성 유해성분)

  • Chung, Hyun;Yoon, Mi Kyung;Kim, Meehye;Park, Sung-Kug;Lee, Joongoo;Kim, Young-Suk
    • Journal of Applied Biological Chemistry
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    • v.55 no.3
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    • pp.141-148
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    • 2012
  • Recently, concerns about the volatile hazardous compounds including acetaldehyde, methanol, and fusel oils in alcoholic beverages, which cause hangover such as headache and dizziness after consumption, have been raised. The volatile hazardous compounds might also lead to an increased incidence of liver diseases and even cancers with a high consumption of alcoholic beverages. Acetaldehyde is a volatile compound naturally found in alcoholic beverages and used as flavor in many foods. However this is also regarded as possibly being carcinogenic to humans. Furthermore, acetaldehyde with alcoholic consumption is recently classified as Group 1, carcinogenic to humans. On the other hand, methanol is generated from demethoxylation of pectin by pectinolytic enzyme during alcoholic fermentation. Higher alcohols occur naturally in alcoholic beverages as by-products of alcoholic fermentation and are generally regarded as important flavor compounds. In the current study, we reviewed on the health concern, maximum levels, analytical methods, and current levels of hazardous volatile compounds in alcoholic beverages.

Natural Dissipation of Chlorinated Volatile Organic Compounds Released in Soil : Effect of Moisture Content and Carbon Source (토양에 유출된 염소계 휘발성 유기물질의 자연저감 : 수분과 탄소원의 영향)

  • Cho Chang-Hwan;Choi Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.10 no.3
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    • pp.46-51
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    • 2005
  • This study was to evaluate sorption and biodegradation rate affecting the natural dissipation of chlorinated volatile organic compounds (CVOCs) in surface soil. To show the effect of sorption and biodegradation on the natural dissipation of 1,1,1-trichloroethane (TCA), trichloroethylene (TCE) and tetrachloroethylene (PCE), three types of vial experiments were employed; (1) sterilized, (2) non-sterilized, (3) non-sterilized/substrate enriched. Also three moisture contents was applied to find the moisture effect in each vial; (1) wilting point (12%, w/w), (2) field capacity (29%, w/w), (3) saturation (48%, w/w). The results suggested that keeping the soil moisture content at field capacity was desirable for TCA and TCE natural dissipation in the vial study.

Solvent Extracted Volatile Components of Mushroom Mycelia Cultivated with Citrus Juice Processing Wastes (감귤 주스 착즙박을 이용하여 재배된 버섯균사체의 용매추출에 의한 휘발성 성분)

  • Lee, Chang-Hwan;Yang, Min-Ho;Park, Seung-Rim;Kang, Young-Joo
    • Food Science and Preservation
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    • v.14 no.4
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    • pp.351-355
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    • 2007
  • Solvent-extracted volatile components from dry powder prepared from Citrus unshiu products such as immature Citrus unshiu (PCU), mature Citrus unshiu (MCU), Citrus unshiu peel (CUP), and citrus juice processing wastes (CJPW), were examined. Also, solvent-extracted volatile components from mushroom mycelia of Pycnoporus coccineus (PC), Lentinus edodes (LE), Pleurotus eryngii (PE), Hericium coralloides (HC), Panellus serotinus (PS), and Ganoderma lucidum(GL), all cultivated using citrus pulp solid media, were assayed. Twenty-nine volatile components were identified in dry powder prepared Citrus unshiu and 18 volatile components were characterized from mushroom mycelia. Of these, ${\beta}-elemene$, germacrene-D, and ${\delta}-cadinene$, were derived from CJPW, but caryophyllene, hexadecanoic acid, decanoic acid, and tetradecanoic acid were synthesized by mushroom mycelia.

Antifungal and Insecticidal Activities of Ohyang (Five Medicinal Plants) (오향(五香) 성분의 살균 및 살충효과)

  • Chung, Yong Jae;Lee, Kyu Shik;Han, Sung Hee;Kang, Dai Ill;Lee, Myeong Hui
    • 한국문화재보존과학회:학술대회논문집
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    • 2001.11a
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    • pp.49-58
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    • 2001
  • The antibacterial and insecticidal properties of ethanol extracts and volatile components extracted from Eugenia caryophyllata, Boswellia carerii, Agastache rugosa, Aristolochia contorta, and Aquilaria agallocha were evaluated. The ethanol extract and volatile component of E. caryophyllata showed strong antimicrobial effect against all strains (Mucor hiemalis, Aspergillus niger, Penicillium funiculosum, Trichodema viride) and the volatile component of B. carterii showed antimicrobial effect against all strains except T. viride. The ethanol extract of E. caryophyllata and A. contorta showed $100\%\;and\;32\%$ mortality against Reticulitermes spertus kyushuensis Morimoto for 48 hours and 72 hours, respectively. In the case of volatile component, R. aryophyllata showed $100\%\;and\;20\%$ mortality against R. spertus and Lyctus linearis GOZE, respectively. The main constitute, eugenol $(92\%)$ among nine components from volatile component of E. aryophyllata were identified as antibacterial active substance.

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Measurement of Atmospheric VOC Concentrations at a Roadside in a Large Urban Area(II) (대도시 도로변 대기 중 휘발성 유기화합물의 농도측정(II))

  • 백성옥;김미현;황승만;정진욱;박상곤
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2000.04a
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    • pp.108-109
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    • 2000
  • 도시대기 중에서 질소산화물과 공존시 태양광의 작용을 받아 광화화학 반응을 일으키는 동시에 사람의 건강상에 유해한 성분(발암성 혹은 돌연변이성)들이 많이 존재하는 것으로 알려진 대기오염물질 중에서도 탄화수소성분에 대한 관심이 최근 들어 고조되고 있다. 본 연구에서는 도시 도로변에서 시료를 24시간 연속적으로 채취하여 휘발성유기회합물(Volatile Organic Compounds;이하 VOCs)의 시간별 농도수준 및 거동을 파악하고 나아가 각 VOCs 농도에 영향을 주는 인자에 대해 평가하고자 한다. (중략)

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Allelopathic Effects of Volatile Compounds from Ambrosia artemisiifolia Leaves on the Selected Species (돼지풀 잎의 휘발성 물질이 수용체 유식물 생장에 미치는 알레로파시 효과)

  • Kim, Hae-Su;Kim, Jong-Hui
    • The Korean Journal of Ecology
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    • v.24 no.1
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    • pp.61-66
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    • 2001
  • The total amount of monoterpenoids in A. artemisiifolia var. elatior leaves was increased continuously after Apr. and the highest amount was in Jul. The major monoterpenoids in A. artemisiifolia var. elatior leaves were consisted of 29 compounds and were dominated by No. 2, octene, α -pinene, β -myrcene ,1,3,6-octatrine, endo-borneol and (-)-bornyl acetate. The allelopathic effects of A. artemisiifolia var elatior leaves on the roots and shoots elongation of the selected plants were studied and there were significant allelopathic effects. The effects were much different between the selected plants and the effects signifcantly became higher with the quantity of leaves used in the experiment. The Lactuca sativa, Achyranthes japonica, and Oenothera odorta were suffered much higher effects than the other species. The allelopathic effects were also different with the leaves sampled in different seasons and the effects in july were found a little higher than in June and May.

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비정질 인듐-갈륨-아연 산화막의 비휘발성 메모리에의 응용

  • Jang, Gyeong-Su;Baek, Gyeong-Hyeon;Choe, U-Jin;Lee, Jun-Sin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.294-294
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    • 2011
  • 비정질 인듐-갈륨-아연 산화막은 저온 공정 및 높은 투과도의 가능성으로 인해 플라스틱 기판과 같은 플렉서블 디스플레이에 적합한 물질이다. 이번 연구에서 비정질 인듐-갈륨-아연 산화막을 비휘발성 메모리에 채널 영역으로 응용하였다. 비휘발성 메모리의 경우 전하 저장 영역으로 가장 널리 이용되는 실리콘 질화막이 아닌 실리콘 산화막을 이용하여 산화막/산화막/산화막의 구조를 이용하였다. +8V의 낮은 프로그래밍 전압에서 2V 이상의 메모리 윈도우를 얻을 수 있었다. 이를 통해 비정질 인듐-갈륨-아연 산화막을 비휘발성 메모리에 적용할 수 있는 가능성이 있다.

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Seasonal concentrations and emission characteristics of odorous compounds produced from swine facilities in Jeju Island (제주지역 양돈시설에서 발생하는 악취물질의 계절별 농도 및 배출 특성)

  • Song, Jung-Min;Yang, Hyo-Sun;Ko, Han-Jong;Kim, Young Ju;Kim, Ki Youn;Kang, Chang-Hee
    • Analytical Science and Technology
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    • v.26 no.6
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    • pp.364-374
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    • 2013
  • The major ten odorous compounds have been analyzed from four swine facilities in Jeju Island, in order to investigate the emission characteristics and odor contribution by different ventilation systems and manure treating types. From the study, the concentrations of $NH_3$ and TMA were high at the enclosed ventilation and scraper type facilities in winter season, and the sulfur compounds ($H_2S$, $CH_3SH$, DMS, DMDS) as well as volatile fatty acids (PA, n-BA, n-VA, iso-VA) showed high concentrations at the enclosed ventilation type facilities during winter season. The concentrations of nitrogen and sulfur compounds were high at slurry manure treat facilities. However, the volatile fatty acids (VFA) were relatively high in the scraper type swine facilities. The odor quotients of n-BA were high at four swine facilities, therefore the volatile fatty might be considered as the major odor causing compounds. Moreover the sum of odor quotient (SOQ) was high at the enclosed ventilation and scraper type facilities, and the odor contributions by volatile fatty acids were high in all swine facilities.