• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2014.11a
• /
• pp.195-195
• /
• 2014

탄화규소(SiC)의 복합체는 고온강도, 내식성, 내마모성, 내화학 특성, 열충격성 및 기계적 특성이 우수하며 제조공정으로 CVD 공정은 많이 연구되어져 있으나 비교적 간단한 구조로 우수한 특성을 얻을 수 Si 증발입자 확산방법에 대한 체계적인 연구가 수행되고 있지 않다. 본 논문에서는 Si 증발입자가 탄소표면에서 확산 반응으로 형성되는 SiC 복합체에 대한 검토 및 연구 개발 동향을 기술한다.

• Journal of the KSME
• /
• v.31 no.3
• /
• pp.276-292
• /
• 1991

복합체 구조물을 광탄성 실험법으로 응력해석 하고자 할 때는 반드시 아래의 사항이 연구되어야 한다. (1) 복합체 구조물의 이방성 성질과 상사되는 광탄성 재료가 개발되어야 한다. (2) 광탄성 재료의 기본 물성치($E_L,E_r,G_{LT},V_{LT}$)와 응력 프린지치($f_L,f_r,f_{LT}$) 등이 측정되어야 한다. (3) 복합체 구조물의 응력 해석을 할 수 있는 광탄성 실험의 실험 방법이 개 발되어야 한다. 이론적으로 규명하기 힘들고 역학적으로 논란되고 있거나 인명에 관계되는 기 계나 구조물 등을 이론적으로 해결하였으나 실험적으로 확인하려고 할 때 광탄성 실험법은 확인 실험법으로써 매우 유용한 방법이므로 아래와 같이 요구된다. 광탄성 실험법이 앞에서 나열된 것처럼 파괴 역학의 여러 분야에도 유용하게 이용될 뿐만 아니라 의학 분야에도 매우 유용하게 이용되고 있다.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2001.10a
• /
• pp.370-370
• /
• 2001

• Elastomers and Composites
• /
• v.42 no.2
• /
• pp.107-111
• /
• 2007

Adhesion of NR and BR composites with different initial states of precured or uncured conditions was studied. Adhesion between the NR and BR sheets as well as adhesion between the same rubber sheets was investigated. Adhesion forces of the uncured/uncured specimens were larger than those of the cured/uncured and cured/cured ones. The cured/cured samples and uncured NR/cured BR specimen were fully peeled out by the peel test. When one sheet was broken during the peel test, the sheet having the higher crosslink density was broken irrespective of the rubber types. Adhesion forces of the same rubber sheets were higher than those of the different ones and adhesion force of the cured NR/uncured BR sample was higher than that of the uncured NR/cured BR one. The experimental results were explained with the crosslink density and interdiffusion of rubber chains.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.27 no.4
• /
• pp.515-523
• /
• 2003

Shape memory is physical phenomenon which a platically metal is restored to its original shape by a solid state phase change by heating. TiNi alloy the most effective material in the shape memory alloy(SMA). To study(measure) recovery stress of intelligent composite. Ti50-Ni50 shape memory matrix with prestrain SMA fiber. When SMA fiber of the intelligent composite is heated over austenite starting temperature(As) by electric heating. a recovery stress are generated. The recovery stress of the intelligent composite was measured by strain gage or photoelastic experiment. Measuring method of recovery stress by photoelastic experiment was developed in this research. It was certified that photoelastic experiment was more effective and more precise than strain gage method in the measurement of recovery stress.

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2011.03a
• /
• pp.55-55
• /
• 2011

실리카 지지체 위에 은 (silver) 나노 입자를 부착시키는 방법으로는 지지체 표면을 먼저 은입자와 친화성이 큰 amino(-NH2), mercapto(-SH), cyan(-CN) 등의 관능기로 표면처리 하는 방법이 일반적으로 사용된다. 구체적으로 설명하면 첫 단계로 지지체인 실리카입자의 표면을 아민으로 표면 처리 한다. 실리카 입자위에 부착된 아민관능기는 입자 생성의 단계에서 은 (silver) 나노 입자가 붙는 접촉점의 역할과 핵 생성 장소로서의 역할을 하게되고, 아민 관능기의 이런 역할로 실리카 입자 표면에 부착된 핵이 생장하여 입자가 됨으로써 최종적으로 은(silver) 나노 입자가 실리카 지지체위에 부착된 형태의 나노복합체가 형성된다. 분자량이 다른 PVP를 사용하여 제조한, NH2와 SH로 계면처리 된 은-실리카 나노복합체제조를 시도하였다. 사용되는 PVP의 분자량이 증가함에 따라 긴 고분자 사슬에 의하여 생성된 입체장애가 증가하게 되어, 은 핵의 성장에 대한 물리적 장벽이 증가하게 된다. 그러므로 고정화된 은 입자의 크기가 감소하게 된다. 이러한 형상은 NH2기 또는 SH기로 계면 처리된 실리카를 이용하여 제조된 은-실리카 나노복합체 입자들에서 모두 관찰되지만, SH기로 계면처리된 실리카를 사용할 경우 고정화된 은 입자의 수가 더욱 많고, 크기 역시 더욱 균일함을 알 수 있다.

• Proceedings of the Korean Fiber Society Conference
• /
• 2007.11a
• /
• pp.509-510
• /
• 2007

See Full Text

• Proceedings of the Korean Fiber Society Conference
• /
• 2007.11a
• /
• pp.403-404
• /
• 2007

See Full Text

• Polymer(Korea)
• /
• v.27 no.6
• /
• pp.583-588
• /
• 2003

Sulfated chitosan and sulfated sodium alginate were synthesized by sulfating reaction of low molecular chitosan and low molecular sodium alginate with SO$_3$-pyridine complex. When the weight ratio of SO$_3$-pyridine complex to polysaccharide was 1:5, the degrees of sulfation were the highest at 2.75 and 2.53 respectively. The anticoagulation effect was the highest when the molecular weight was 8.0${\times}$10$^3$ Da, and the anticoagulation activity was the highest at 91% of that of heparin when sulfated chitosan and sulfated sodium alginate were mixed at a weight ratio of 1:1. The anticoagulation activity was highest at 84% of that of heparin in the active plastin trombo test (aPTT) when sulfated chitosan and sulfated sodium alginate were mixed at a weight ratio of 1:1.

• Elastomers and Composites
• /
• v.46 no.3
• /
• pp.237-244
• /
• 2011

Five natural rubber (NR) composites with different reinforcing systems of unfilled, carbon black, carbon black with silane coupling agent, silica, and silica with silane coupling agent were thermally aged and change of the crosslink densities by the accelerated thermal aging was investigated. The crosslink densities on the whole increased as the aging time elapsed irrespective of the reinforcing systems. The crosslink density changes became noticeable by increasing the aging temperature. For carbon black-filled composites, the silane coupling agent made the crosslink density change to be increased. For silica-filled composites, however, the silane coupling agent made the crosslink density increment reduced at 60 and $70^{\circ}C$ and it hardly affect the degree of the crosslink density change at 80 and $90^{\circ}C$. The activation energies for the crosslink density changes of the carbon black-filled samples increased continuously in a logarithmic fashion, whereas that of the silica-filled one showed a quasi-steady state ranges at aging times of 30-150 days. The activation energy of the unfilled sample increased exponentially with the aging time. The experimental results were explained with sulfur donation from the silane coupling agent, surface modification of the filler by the silane coupling agent, adsorption of curative residues on the silica surface, and release of the adsorbed curative residues.