• Economic and Environmental Geology
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• v.36 no.2
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• pp.75-87
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• 2003

The Haman-Gunbuk mineralized area is located within the Cretaceous Gyeongsang Basin along the southeastern part of the Korean peninsula. Major ore minerals, magnetite, scheelite, molybdenite and chalcopyrite, together with base-metal sulfides and minor sulfosalts, occur in fissure-filling tourmaline, quartz and carbonates veins contained within Cretaceous sedimentary and volcanic rocks anu/or granodiorite (118{\pm}$3.0 Ma). The ore and gangue mineral paragenesis can be divided into three distinct stages: Stage 1, tourmaline+quartz+Fe-Cu ore mineralization; Stage II, quartz+sulfides+sulfosalts+carbonates; Stage 111, barren calcite. Earliest fluids are recorded in stage I and early por-tions of stage II veins as hypersaline (35~70 equiv. wt.% NaCl+KCl) and vapor-rich inclusions which homogenize from ~30$0^{\circ}C$ to $\geq$50$0^{\circ}C$. The high-salinity fluids are complex chloride brines with significant concentrations of sodium, potassium, iron, copper, and sulfur, though sulfide minerals are not associated with the early mineral assemblage produced by this fluid. Later solutions circulated through newly formed fractures and reopened veins, and are recorded as lower-salinity(less than ~20 equiv. wt.% NaCl) fluid inclusions which homogenize primarily from ~200 to 40$0^{\circ}C$. The oxygen and hydrogen isotopic compositions of fluid in the Haman-Gunbuk hydrothermal system represents a progressive shift from magmatic-hydrothermal dominance during early mineralization stage toward meteoric-hydrothermal dominance during late mineralization stage. The earliest hydrothermal fiuids to circu-late within the granodiorite stock localiring the ore body at Haman-Gunbuk could have exsolved from the crystal-lizing magma and unmixed into hypersaline liquid and $H_2O$-NaCl vapor. As these magmatic fluids moved throughfractures, tourmaline and early Fe, W, Mo, Cu ore mineralization occurred without concomitant deposition of othersulfides and sulfosalts. Later solutions of dominantly meteoric origin progressively formed hypogene copper and base-metal sulfides, and sulfosalt mineralization.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.1
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• pp.57-67
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• 2021

The geology of the Iskaycruz project are mainly composed of sedimentary rocks within Cretaceous basin. The basal part is composed up of dark-gray shale, gray sandstone, and clastic rock of Oyon formation interbedded with coal measures. In the folded zone in the eastern part of the survey area, there is Chimu formation that has medium-grained massive and white quarztite. In terms of geological structure, the Iskaykruz region is located in the folded and overthrust zones of the central part of the Occidental Mountains. Ore body was formed by hydrothermal replacement process and consists of zinc, lead, silver, and copper. Stratabound-type deposits are hosted in limestone of Santa formation. It extends 12 kilometers discontinuously from northern Canaypata to southern Antapampa. Irregular iron oxide and sulfide minerals hosted in Santa and Parihuanca formations are observed. The mineralization observed on the surface consist of primary sulfides consisting of sphalerite with galena and chalcopyrite, and iron and manganese oxide produced from oxidation of primary sulfides. Skarn minerals are accompanied by tremolite, garnet, epidote and quartz.

• Proceedings of KOSOMES biannual meeting
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• 2006.11a
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• pp.271-275
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• 2006

여수 하수처리장 하수처리 방류수가 배출구 인근해역에 미칠 수 있는 영향정도를 파악하기 위하여 해양수질 및 저질 환경을 조사하였다. 조사는 총 30개 지점에서 수질과 저질의 일반항목과 영양염류에 대하여 실시하였다. 조사시기는 2005년 9월 3일 (하계), 2005년 11월 20일(추계), 2006년 2월 13일 (동계), 2006년 5월 28일 (춘계) 에 4 계절에 걸쳐 밀물시와 썰물시에 현장 조사를 실시하였다. 배출수는 해양수질환경의 특성을 통해 추정한 결과 직접영향권은 0.5km, 간접 영향권은 반경 약 2km까지로 추정되었다. 저질의 결과를 보면 산 휘발성 황화물의 농도가 많은 해역에서 저질의 오염기준을 초과하는 동 오염된 저질의 특성을 보였으며, 산 휘발성 황화물과 화학적 산소요구량의 분포는 니질 퇴적상이 두드러지게 나타나는 배출구 동측과 돌산도 남동쪽, 돌산도 서측과 대경도 동측사이에 위치한 해역에서는 대체적으로 높은 값들을 보이고 있으며, 조립질 퇴적상이 주로 분포하고 있는 배출구와 국동항사이의 수로에서는 대체적으로 낮은 분포를 나타내었다.

• Journal of the Korean Chemical Society
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• v.23 no.4
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• pp.259-266
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• 1979

Linear polyethers were prepared by the reaction of diphenoxide anions from 2,2-bis (4-hydroxyphenyl) propane, bis (4-hydroxylphenyl) sulfide, and bis (khydroxyphenyl) sulfone with 1,6-dibromohexane in aqueous/nitrobenzene heterogeneous phases. Tetrabutylammonium bromide was employed as a phase transfer catalyst. The polymerizations were dependent both on stirring speed and catalyst level, but only up to certain maximum values. Distribution studies demonstrated transference of diphenoxide anions from aqueous phase into nitrobenzene in the presence of the catalyst. Some of polymers were characterized with respect to their intrinsic viscosities (0.09-O.16), number average molecular weight (2400-4800)) and thermal properties. The use of a new terminology, 'phase transfer polymerization?, is proposed to differentiate this type of polymerizations from interfacial polycondensations.

• Economic and Environmental Geology
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• v.42 no.1
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• pp.1-8
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• 2009

The Haman mineralized area is located within the Cretaceous Gyeongsang Basin along the southeastern part of the Korean peninsula. Almost all occurrences in the Haman area are representative of copper-bearing polymetallic hydrothermal vein-type mineralization. Within the area are a number of fissure-filling hydrothermal veins which contain tourmaline, quartz and carbonates with Fe-oxide, base-metal sulfide and sulfosalt minerals. The Gunbuk, Jeilgunbuk and Haman mines are each located on such veins. The ore and gangue mineral paragenesis can be divided into three distinct stages: Stage I, tourmaline + quartz + Fe-Cu ore mineralization; Stage II, quartz + sulfides + sulfosalts + carbonates; Stage III, barren calcite. Equilibrium thermodynamic data combined with mineral paragenesis indicate that copper minerals precipitated mainly within a temperature range of $350^{\circ}C$ to $250^{\circ}C$. During early mineralization at $350^{\circ}C$, significant amounts of copper ($10^3$ to $10^2\;ppm$) could be dissolved in weakly acid NaCl solutions. For late mineralization at $250^{\circ}C$, about $10^0$ to $10^{-1}\;ppm$ copper could be dissolved. Equilibrium thermodynamic interpretation indicates that the copper in the Haman-Gunbuk systems could have been transported as a chloride complex and the copper precipitation occurred as a result of cooling accompanied by changes in the geochemical environments ($fs_2$, $fo_2$, pH, etc.) resulting in decrease of solubility of copper chloride complexes.

• Journal of Bio-Environment Control
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• v.25 no.4
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• pp.283-287
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• 2016

This study was conducted to examine the effects of defoliation levels during winter season on the yield and soluble solid contents of fruits. To achieve this strawberry 'Seolhyang' cultivated forcingly in the year of 2013 to 2014 as well as 2014 to 2015. The three treatments include periodical removing of leaves remaining 6 fully expanded leaves, those remaining 9 leaves, and only removing of old and infected leaves during the period from early December to end of February. In the early marketable fruit yield until the end of February and total marketable fruit yield, the treatment of non-defoliation was significantly higher than those of the treatment of 6 and 9 leaves in the year of 2014 to 2015 cropping season. Soluble solid contents of fruits among January and March increased significantly as the number of leaves get higher. Soluble solid contents were higher and stable around $12^{\circ}Brix$ in the treatment of non-defoliation. Assimilation of photosynthetic products into plant tissue are insufficient due to the lack of irradiation and short day in winter season forcing cultivation of strawberry. Thus, it is considered to manage the leaves with defoliation for only old and infected leaves from December to February for increasing of fruit yield and improvement of fruit quality.

• Economic and Environmental Geology
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• v.35 no.3
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• pp.211-220
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• 2002

The Xiaoxinancha Cu-Au deposit in the Jilin province, located in NNE 800 km of Beijing, is hosted by diorite. The ore mineralization of Xiaoxinancha Cu-Au deposit show a stockwork occurrence that is concentrated on the potassic and phyllic alteration zones. The Xiaoxinancha Cu-Au deposit in the south is being mined with its reserves grading 0.8% Cu, 3.64 g/t Au and 16.8 g/t Ag and in the north, grading 0.63% Cu, 3.80 g/t Au and 6.8 glt Ag. The alteration assemblage occurs as a supergene blanket over deposit. Hydrothermal alteration at the Xiaoxinancha Cu-Au deposit is centered about the stock and was extensively related to the emplacement of the stock. Early hydrothermal alteration was dominantly potassic and followed by propylitic alteration. Chalcocite, often associated with hematite, account for the ore-grade copper, while chalcopyrite, bornite, quartz, epidote, chlorite and calcite constitute the typical gangue assemblage. Other minor opaque phases include pyrite, marcasite, native gold, electrum, hessite, hedleyite, volynskite, galenobismutite, covellite and goethite. Fluid inclusion data indicate that the formation of this porphyry copper deposit is thought to be a result of cooling followed by mixing with dilute and cooler meteoric water with time. In stage II vein, early boiling occurred at 497$^{\circ}$C was succeeded by the occurrence of halite-bearing type III fluid inclusion with homogenization temperature as much as 100$^{\circ}$C lower. The salinities of type 1II fluid inclusion in stage II vein are 54.3 to 66.9 wt.% NaCI + KCI equiv. at 383$^{\circ}$ to 495$^{\circ}$C, indicating the formation depth less than 1 km. Type I cupriferous fluids in stage III vein have the homogenization temperatures and salinity of 168$^{\circ}$ to 365$^{\circ}$C and 1.1 to 9.0 wt.% NaCI equiv. These fluid inclusions in stage III veins were trapped in quartz veins containing highly fractured breccia, indicating the predominance of boiling evidence. This corresponds to hydrostatic pressure of 50 to 80 bars. The $\delta$$^{34}S$ value of sulfide minerals increase slightly with paragenetic time and yield calculated $\delta$$^{34}S_{H2S}$ values of 0.8 to 3.7$\textperthousand$. There is no mineralogical evidence that fugacity of oxygen decreased, and it is thought that the oxygen fugacity of the mineralizing fluids have been buffered through reaction with magnetite. We interpreted the range of the calculated $\delta$$^{34}S_{H2S}$ values for sulfides to represent the incorporation of sulfur from two sources into the Xiaoxinancha Cu-Au hydrothermal fluids: (1) an isotopically light source with a $\delta$$^{34}S$ value of I to 2$\textperthousand$, probably a Mesozoic granitoid related to the ore mineralization. We can infer from the fact that diorite as the host rock in the Xiaoxinancha Cu-Au deposit area intruded plagiogranite; (2) an isotopically heavier source with a $\delta$$^{34}S$ value of > 4.0$\textperthousand$, probably the local porphyry.

• Economic and Environmental Geology
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• v.30 no.4
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• pp.289-301
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• 1997

The Boguk cobalt mine is located within the Cretaceous Gyeongsang Sedimentary Basin. Major ore minerals including cobalt-bearing minerals (loellingite, cobaltite, and glaucodot) and Co-bearing arsenopyrite occur together with base-metal sulfides (pyrrhotite, chalcopyrite, pyrite, sphalerite, etc.) and minor amounts of oxides (magnetite and hematite) within fracture-filling $quartz{\pm}actinolite{\pm}carbonate$ veins. These veins are developed within an epicrustal micrographic granite stock which intrudes the Konchonri Formation (mainly of shale). Radiometric date of the granite (85.98 Ma) indicates a Late Cretaceous age for granite emplacement and associated cobalt mineralization. The vein mineralogy is relatively complex and changes with time: cobalt-bearing minerals with actinolite, carbonates, and quartz gangues (stages I and II) ${\rightarrow}$ base-metal sulfides, gold, and Fe oxides with quartz gangues (stage III) ${\rightarrow}$ barren carbonates (stages IV and V). The common occurrence of high-temperature minerals (cobalt-bearing minerals, molybdenite and actinolite) with low-temperature minerals (base-metal sulfides, gold and carbonates) in veins indicates a xenothermal condition of the hydrothermal mineralization. High enrichment of Co in the granite (avg. 50.90 ppm) indicates the magmatic hydrothermal derivation of cobalt from this cooling granite stock, whereas higher amounts of Cu and Zn in the Konchonri Formation shale suggest their derivations largely from shale. The decrease in temperature of hydrothermal fluids with a concomitant increase in fugacity of oxygen with time (for cobalt deposition in stages I and II, $T=560^{\circ}C-390^{\circ}C$ and log $fO_2=$ >-32.7 to -30.7 atm at $350^{\circ}C$; for base-metal sulfide deposition in stage III, $T=380^{\circ}-345^{\circ}C$ and log $fO_2={\geq}-30.7$ atm at $350^{\circ}C$) indicates a transition of the hydrothermal system from a magmatic-water domination toward a less-evolved meteoric-water domination. Sulfur isotope data of stage II sulfide minerals evidence that early, Co-bearing hydrothermal fluids derived originally from an igneous source with a ${\delta}^{34}S_{{\Sigma}S}$ value near 3 to 5‰. The remarkable increase in ${\delta}^{34}S_{H2S}$ values of hydrothermal fluids with time from cobalt deposition in stage II (3-5‰) to base-metal sulfide deposition in stage III (up to about 20‰) also indicates the change of the hydrothermal system toward the meteoric water domination, which resulted in the leaching-out and concentration of isotopically heavier sulfur (sedimentary sulfates), base metals (Cu, Zn, etc.) and gold from surrounding sedimentary rocks during the huge, meteoric water circulation. We suggest that without the formation of the later, meteoric water circulation extensively through surrounding sedimentary rocks the Boguk cobalt deposits would be simple veins only with actinolite + quartz + cobalt-bearing minerals. Furthermore, the formation of the meteoric water circulation after the culmination of a magmatic hydrothermal system resulted in the common occurrence of high-temperature minerals with later, lower-temperature minerals, resulting in a xenothermal feature of the mineralization.

• Journal of the Institute of Electronics and Information Engineers
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• v.49 no.9
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• pp.314-321
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• 2012

Harmful gases which are generated from various rout at growth environment of livestock ban have a direct and indirect bad influence to the livestock and farmers, and also step-up breeding density and long-term exposure to the sealed environment of winter can be fatal. In this paper, we propose a gas measurement system for monitoring gases of ammonia, hydrogen sulfide, volatile organic compounds, etc. which arise from the muck. The measurement system consist of both wireless gas sensor node and gas recognition software using a Fuzzy Min-Max neural network. To evaluate the performance of suggested system, gas measurement experiments are performed in laboratory environment by using the designed wireless gas sensor node. And we show the performance through classification test for the target gases by the designed gas recognition software.

• Conservation Science in Museum
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• v.1
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• pp.87-91
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• 1999

During the process of conservation treatment for the shoes[object No. Bon 7038], a red piece of textile was discovered. It was confirmed that hematite(Fe₂O₃) was used as pigment, through the following scientific examinations as color measurements, solubility in a particular solvent, discoloration, thin-section investigation of cross section under the microscope, composition analysis by SEM-EDS and etc. This is the first red pigment of Kaya period discovered so far, and it is significant because it exists on textile. Besides, red pigment discovered on the shield trace excavated from Tomb No. 11 of Daesung-dong in Kimhae was confirmed as Mercury sulfide(HgS). These two facts testify that similar red pigments had been used both in Kaya and Three Kingdoms around the same period.