• 제목/요약/키워드: 황동

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Chalcopyrite Disease in Sphalerite: A Case of the Soowang Ore Deposits in Muju, Republic of Korea (무주 수왕광산에서 산출되는 섬아연석의 황동석 병변에 관한 연구)

  • Youn, Seok-Tai
    • Journal of the Korean earth science society
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    • v.29 no.7
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    • pp.551-558
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    • 2008
  • The Soowang deposits occur in the quartz veins that were filled fissures in the middle Cretaceous porphyritic granite and/or the Precambrian Sobaegsan gneiss complex. Paragenetic studies suggest that the vein filling can be divided into four identifiable stages. Sphalerites were deposited by the cooling fluids at stages I, II, and III. The results of microscopic observation and EPMA analysis suggest that the chalcopyrite dots and disease in sphalerite are replacement products by later hydrothermal solution at the early stage III. The inferred processes of chalcopyrite disease are as follows: (1) Fe enrichment to the margins and along the cracks of the Fe-poor sphalerite by Fe-rich solution, (2) Formation of chalcopyrite dots in the Fe-enriched sphalerite formed at the stage II, and Fe reduction of sphalerite near the chalcopyrite dots by Cu-bearing solution, (3) Formation of "chalcopyrite disease" penetrating the compositional zoning of sphalerite at the early stage III.

Comparison and validation of Brass mesh bolus using tissue equivalent bolus in the breast cancer radiotherapy (유방암 방사선치료시 조직등가보상체와의 비교를 통한 Brass mesh bolus의 유용성 평가)

  • Bong, Juyeon;Kim, Kyungtae;jeon, Mijin;Ha, Jinsook;Shin, Dongbong;Kim, Seijoon;Kim, Jongdae
    • The Journal of Korean Society for Radiation Therapy
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    • v.29 no.1
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    • pp.93-101
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    • 2017
  • Purpose: In breast cancer radiotherapy, brass mesh bolus has been recently studied to overcome disadvantage of conventional bolus. The purpose of this study is to investigate the stability of first introduced the brass mesh in the country, and evaluate the skin surface dose of that. Materials and Methods: The measurement of skin surface dose was evaluated to verify similar thickness of the Brass mesh bolus that compared conformal tissue equivalent bolus with 5 mm thickness. We used 6 MV photons on an ELEKTA VERSA linear accelerator and optically stimulated luminescent dosimeter (OSLD). In addition, two opposed beam using IMRT phantom was applied to comparative study of brass mesh bolus between tissue equivalent bolus. Results: The results showed that similar thickness of the Brass mesh bolus was 3 mm compared with 5 mm tissue equivalent bolus by measuring the skin surface dose of solid phantom. The surface dose for IMRT thorax phantom using 3 mm brass mesh bolus was about 1.069 times greater than that using tissue equivalent bolus. Conclusion: In this study, we found that the brass mesh bolus improved better reduction of skin sparing effect and dose uniformity than tissue equivalent bolus. However evaluation for various clinic cases should be investigated.

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Dynamic Compressive Deformation Characteristics of Free-Cutting Brass And Yellow Brass at High Strain Rates (고변형률 압축 하중에서 쾌삭 황동과 황동의 동적 변형 거동 특성)

  • Lee, Ouk-Sub;Kim, Kyoung-Joon;Lee, Jong-Won
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.107-112
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    • 2003
  • Mechanical properties of the materials used for transportations and industrial machinery under high strain rate loading conditions such as high impact loading are required to provide appropriate safety assessment to varying dynamically loaded mechanical structures. The Split Hopkinson Pressure Bar(SHPB) technique with a special experimental apparatus can be used to obtain the material behavior under high strain rate loading conditions. In this paper, the dynamic deformation behavior of a brass under both high strain rate compressive loading conditions has been determined using the SHPB technique.

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Pigments in the Letters of Hanging Boards of the Joseon Royal Court and Reproduction Experiments (조선왕실 현판 글자의 금색 안료와 재현 실험 연구)

  • LEE Hyeyoun;LEE Minhye;LEE Heeseung
    • Korean Journal of Heritage: History & Science
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    • v.56 no.3
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    • pp.118-135
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    • 2023
  • Hanging boards of the Joseon royal court are hung on buildings related to the royal family, such as palaces and Jongmyo Shrine, to show the hierarchy and character of the building. In addition, the manufacturing method and materials are recorded in the royal protocols of the Joseon Dynasty, so it is an important material for studying the manufacturing method and material changes at that time. However, the hanging boards were restored several times due to fire or war, and it is presumed that there is a change in the original form and material of the hanging boards. In particular, many hanging boards of the Joseon royal court were written with calligraphy by kings, so there are many forms consisting of gold letters on a black background. This study tried to analyze the pigments remaining in the letters of 44 of the Joseon royal hanging boards, which are presumed to be gold letters, and to find out the changes in the hanging board production method and materials by referring to the analysis results. The letters of the hanging boards studied were classified according to the current state of the gold pigment and the detected components. As a result of the analysis of character pigments, 24 embossing techniques and 5 intaglio techniques were mainly detected with gold (Au), but 15 embossing techniques were detected with brass (Cu, Zn). Only blue-green substances, not gold pigments, remain in some of the hanging boards in which brass components were detected. A reproduction experiment was conducted because the pigments of the brass component were not recorded in the literature and were not currently used as Dancheong pigments. In the reproduction experiment, it was difficult to confirm the application and use of brass pigments due to the limitations of materials, but it is judged that research on the timing and method of using brass pigments is needed in the future.

The Effect of Surface State of Brass Coated Steel Cord on the Adhesion between Cord and Rubber Compound (황동이 피복된 코드의 표면 상태가 배합고무와 코드의 접착에 미치는 영향)

  • Seo, Gon;Ryoo, Min-Woong;Jeon, Dae-Jin;Sohn, Bong-Young
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.1056-1061
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    • 1994
  • Adhesion between cord and rubber compound of brass plated steel cords pretreated at $80^{\circ}C$ in air and at $80^{\circ}C$ and 85% of relative humidity was studied. Surface change of brass with pretreatment was also studied. Brass was oxidized at thermal treatment and oxidation was accelerated with water at humid treatment. Adhesion of pretreated cords decreased with treatment period. The decreasing tendency of rubber coverage was severe. Decrease in adhesion properties due to brass oxidation was discussed relating to the overgrowth of zinc oxide layer.

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Sulfur Isotope Study on the Wolf River Batholith, Wisconsin in U.S.A. (미국 위스콘신주의 올프리버 저반에 대한 황동위원소 연구)

  • Sun-Joon Kim;Yuch-Ning Shieh
    • The Journal of the Petrological Society of Korea
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    • v.4 no.2
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    • pp.134-143
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    • 1995
  • Sulfur isotope compositions have been determined for the granitic and related rocks from the Wolf River Batholith, Wisconsin in U.S.A. Sulfur content and isotope composition of granitic rocks of the Wolf River Ratholith range from 30 to 140 ppm and from 1.1 to 6.5 permil respectively, and are considered to be magmatic. Sulfur content and isotope composition of the Penokean plutonic rocks, surrounding country rocks, range from 31to 381 ppm and from -1.7 to 7.2 permil respectively. The positive correlation observed between sulfur and oxygen isotope data of granitic rocks and the Penokean plutonic rocks may be due to the assimilation of the Penokean plutonic rocks by a primary magma of deep-crustal origin, or to mixing at depth, of a primary magma with another magma having higher ${\delta}^{18}O$ and ${\delta}^{34}S$.

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The Oxidation of Chalcopyrite and Geochemical Behavior of Heavy Metals in the Manjang Cu Mine (만장광산에서 산출되는 황동석의 산화과정과 중금속 거동 특성)

  • 이평구;이인경;최상훈;김지수
    • Economic and Environmental Geology
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    • v.37 no.3
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    • pp.291-301
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    • 2004
  • In order to charaterize weathering of chalcopyrite and behavior of dissolved metal ions in waste rocks from Manjang Cu mine, mineralogical studies such as refractive microscope, XRD and SEM/EDS analyses carried out. The weathering was mainly occurred in fractures and edge of the chalcopyrite within the mine waste rocks. The weathering process can be seen to reflect four stages based on the weathering degree of chalcopyrite. The main secondary minerals are goethite, covellite, azurite, malachite and brochantite. Dissolved Cu and As were mainly adsorbed Fe-hydroxide. Poorly crystalline Fe-oxide contains relatively high As contents. In oxdizing condition, the weathering of chalcopyrite mainly occurs along the fracture, while the replacement of chalcopyrite observed mainly in the grain and produced covellite and brochantite. The dissolved metals (Cu, Fe, As) in waste rocks from the abandoned Manjang mine area could attenuate naturally by precipitation, adsorption and replacement reaction.

Sulfur Isotope Composition of Seafloor Hydrothermal Vents in the Convergent Plate Boundaries of the Western Pacific: A Role of Magma on Generation of Hydrothermal Fluid (서태평양 지판소멸대의 해저열수분출구에서 관찰되는 황동위원소 조성변화: 열수 생성의 다양성과 마그마의 역할)

  • Kim, Jong-Uk;Moon, Jai-Woon;Lee, Kyeong-Yong;Lee, In-Sung
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.145-156
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    • 2012
  • Seafloor hydrothermal system occurs along the volcanic mid-ocean ridge, back-arc spreading center, and other submarine volcanic regions. The hydrothermal system is one of the fundamental processes controlling the transfer of energy and matter between crust/mantle and ocean; it forms hydrothermal vents where various deepsea biological communities are inhabited and precipitates metal sulfide deposits. Hydrothermal systems at convergence plate boundaries show diverse geochemical properties due to recycle of subducted material compared to simple systems at mid-ocean ridges. Sulfur isotopes can be used to evaluate such diversity in generation and evolution of hydrothermal system. In this paper, we review the sulfur isotope composition and geochemistry of hydrothermal precipitates sampled from several hydrothermal vents in the divergent plate boundaries in the western Pacific region. Both sulfide and sulfate minerals of the hydrothermal vents in the arc and backarc tectonic settings commonly show low sulfur isotope compositions, which can be attributed to input of magmatic $SO_2$ gas. Diversity in geochemistry of hydrothermal system suggests an active role of magma in the formation of seafloor hydrothermal system.