• Journal of the Korean Institute of Gas
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• v.13 no.5
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• pp.33-38
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• 2009

Synthetic natural gas was producd by the reaction of carbon monoxide and hydrogen via methanation. Ni-Co bimetallic catalyst supported on $Al_2O_3$ for methanation was prepared using deposition-precipitation method. For the comparison, Ni, Co monometallic catalyst was prepared using the same method. The prepared catalysts were characterized by TEM, XRD and TPR and applied to methanation reaction. The catalysts prepared using deposition-precipitation method showed the high metal dispersion. The activity of Ni-Co bimetallic catalyst was higher than that of Ni, Co monometallic catalyst. TPR measurements indicated that Ni-Co bimetallic catalyst had more active hydrogen species than Ni, Co monometallic catalyst due to the synergetic effect in the presence of Ni and Co.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.156.2-156.2
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• 2011

본 연구에서는 일단 수성가스전이반응 (Single stage water gas shift reaction)을 위해 높은 활성을 가진 백금 담지 촉매를 함침법 (Incipient wetness impregnation method)으로 제조하여 높은 공간 속도 (Gas hourly space velocity) $45,515h^{-1}$에서 담체에 따른 촉매 활성을 평가하였다. 담체는 $CeO_2$, $ZrO_2$, MgO, MgO-$Al_2O_3$ (MgO = 30 wt%) 그리고 $Al_2O_3$를 사용하였으며 백금의 담지량은 1 wt%로 고정하였다. BET, XRD, TPR, CO-chemisorption 분석을 통하여 담체의 구조적 특성이 촉매 활성에 미치는 영향에 대하여 조사하였다.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.216-219
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• 2007

Pulse current 전기 도금법을 사용해 균일하고 넓은 표면적을 갖는 Pt 나노구조가 제조되었다. 도금된 Pt 나노구조의 형태와 크기 분석을 위해 SFM과 TEM이 사용되었으며, 결정성 분석에는 XRD가 사용되었다. 고분자 첨가제를 첨가하여 도금되는 Pt의 크기를 제어할 수 있었는데, 순수한 Pt에 비해 첨가제의 영향으로 크기가 제어된 나노구조의 Pt들의 평균크기는 각각 3.4 nm와 2.9 nm로 순수한 Pt 360 nm의 것에 비해 훨씬 작아진 결과를 나타낼 뿐 아니라 크기가 제어된 나노구조 Pt는 메탄올 전기 산화반응에서도 순수한 Pt보다 뛰어난 촉매활성을 가짐을 보여주었다.

• Journal of the Korean Electrochemical Society
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• v.11 no.4
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• pp.313-318
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• 2008

The influence of the particle size of platinum(Pt) on the stability and activity was studied. The particle size of platinum was controlled in the range of $3.5{\sim}9\;nm$ by heat treatment of commercial Pt/C and confirmed by XRD and TEM. An accelerated degradation test was performed to evaluate the stability of platinum catalysts. Oxygen reduction reaction was monitored for the measurement of activity. As increasing the Pt particle size, the stability of Pt/C electrode was enhanced and the activity was reduced. It was confirmed that the stability of Pt/C electrode was in inverse proportion to the activity. PtCo/C alloy catalyst was used to improve the activity and stability of large-sized platinum particle. The maximum power density of commercial Pt/C was $507.6\;mV/cm^2$ and PtCo/C alloy catalyst was $585.8\;mV/cm^2$. The decrement of electrochemical surface area showed Pt/C(60%) and PtCo/C alloy catalyst(24%). It was possible to enhance both of stability and activity of catalyst by the combination of particle size control and alloying.

• Resources Recycling
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• v.15 no.5 s.73
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• pp.17-25
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• 2006

Al-MCM-48 was used as a catalyst to decompose high density polyethylene(HDPE). Catalytic activity of Al-MCM-48 was compared with those of Al-MCM-41, Beta, and ZSM-5. Catalytic decomposition rate over Al-MCM-48 was much higher than at of non-catalytic pyrolysis only. Compared to other catalysts, Al-MCM-48 revealed the little higher activation energy value. The progressive deactivation behavior of the catalysts has also studied. ZSM-5 and Al-MCM-48 showed slower deactivation rates than Al-MCM-41 and Beta. Pyrolysis coupled with gas chromatographic separation and flame ionization detection (Py-GC/ FID) was also performed to assess the characteristics of pyrolysis products. ZSM-5 gave a higher fraction of gaseous products ($C_1-C_4$). Al-MCM-41 and Beta produced mainly $C_5-C_{12}$ products. The selectivity to oil product ($C_5-C_{22}$) obtained with Al- MCM-48 is higher an that with the other catalysts employed in this study.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2008.11a
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• pp.96-99
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• 2008

악취물질 중 특히 황계열 물질인 Dimethyl disulfide(DMDS)는 광촉매 산화 시 촉매비 활성에 의해 촉매의 효율이 떨어진다. 이는 Dimethyl disulfide(DMDS) 분해과정에서 발생되는 중간생성물이 촉매 표면에 강하게 흡착되기 때문이다. 이러한 비활성을 해결하기 위해 촉매를 재생하여 사용할 수 있다. 'Burning out'에 의한 재생은 촉매 표면에 흡착된 일부 유기 종들을 배출시켜 촉매능을 53% 회복시켰다.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2005.05a
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• pp.207-209
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• 2005

현재 고정원에서 상용화 촉매로서 사용되는 V$_{2}$O$_{5}$/TiO$_{2}$계 촉매는 고온 영역에서 최적 활성반응을 보이나 NH$_{3}$의 산화반응으로 인해 NO$_{X}$의 제거효율을 낮추는 원인과 가열설비의 추가적인 설치에 따른 초기 투자비, 운전비용 상승 및 촉매 수명 단축 등의 경제적, 기술적인 문제점을 나타내고 있다. 본 연구에서는 저온 영역에서 높은 활성반응을 나타내는 촉매기술의 SCR적용시 배출가스 온도의 100$^{\circ}C$ 감소에 따른 동력비의 절감과 촉매 수명 연장, 경제적, 기술적인 문제점을 해결할 수 있을 것으로 사료된다.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.11b
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• pp.577-582
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• 1996

삼중수소수와 수소간의 수소동위원소 교환반응을 수행하였다. 촉매로는 백금/SDB고분자촉매, 백금/활성탄촉매 및 니켈/SiO$_2$-A1$_2$O$_3$촉매를 사용하였다. 촉매층의 높이 및 수소유속이 촉매반응효율에 미치는 영향을 관찰하였다. 수소동위원소 교환반응에는 고분자촉매가 가장 높은 효율을 갖는 것이 확인되었다.

• Korean Chemical Engineering Research
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• v.46 no.1
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• pp.137-141
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• 2008

Copolymerization of ethylene and ${\alpha}$-olefin using $rac-Et[Ind]_2ZrCl_2/MAO$ catalyst embedded onto polysty-rene was examined. The embedded catalyst was prepared by polymerizing a small amount of styrene with $rac-Et[Ind]_2ZrCl_2$. The catalytic activities of the embedded catalyst were higher than those of the homogeneous catalystregardless of comonomer type and the characteristic of the active sites of the embedded catalyst was not affected duringthe embedding process. Based on the DSC and NMR analyses of the produced copolymers, it was thought that theembedded catalyst had similar or slightly better comonomer incorporation ability. Furthermore, the copolymers produced by the embedded catalyst had higher bulk densities and better particle morphology than those by the homogeneous catalyst.

• Polymer(Korea)
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• v.24 no.2
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• pp.252-258
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• 2000

Various crosslinked poly(4-vinylpyridines) (CHP4VP) having different degrees of crosslinking were synthesized by radical copolymerization of 4-vinylpyridine with if N,N' -1, 6-hexamethylenebisacrylamide, and CHP4VP- Cu(II) complexes were prepared by the method of adsorption equilibrium. The catalytic activity of the complexes for the oxidation of ascorbic acid (AA) was investigated. The oxidation of AA by these complexes showed a kinetic behavior of the Michaelis-Menten type. The catalytic activity of CHP4VP-Cu(I ) catalytic system was increased with increasing the degree of crosslinking of CHP4VP, and its activity was scarcely decreased even after repeated use. However, the tendency of the catalytic activity of CHP4VP-Cu(II) complexes was decreased for the oxidation of AA when compared with that of the previously reported catalytic system containing crosslinked poly(4-vinylpyridine) prepared using N,N'-methylenebisacrylamide as a crosslinker. These results indicate that the degree of crosslinking of CHP4VP and the hydrophobicity of the crosslinker play an important role in the catalytic system of the oxidation of AA.