• Title/Summary/Keyword: 환경지화학

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Absorption characteristic of carbon dioxide in Ionic Liquids based sulfite anion in the pre-combustion condition (연소 전 조건에서 음이온이 Sulfite계인 이온성 액체의 CO2 흡수 특성)

  • Baek, Geun Ho;Jang, Hyun Tae;Cha, Wang Seog
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.3
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    • pp.763-769
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    • 2021
  • In this study, ionic liquids were synthesized to remove carbon dioxide (CO2) on a laboratory scale. The vapor-liquid absorption equilibrium device (VLE) was used to investigate the carbon dioxide absorption capacity. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, showing excellent regeneration. Ethyl sulfite showed the highest absorption capacity of CO2 among the ionic liquids based on the sulfite anion. In particular, the absorption capacity of [beim] ethyl sulfite was 1.1 mol CO2 / mol IL at an absorption equilibrium pressure of 22 bar. In the regeneration study, the absorption capacity after regeneration was reduced by approximately 7% for all ionic liquids, in which the anion was sulfite-based, from which regeneration is outstanding. After the absorption experiment, the viscosity of the sample tended to decrease by approximately 8% compared to that before the absorption experiment. On the other hand, the absorbent was synthesized in the first step. Moreover, the raw material used is also inexpensive and has excellent reproducibility and highly stable absorbent capacity.

Ballistic Protection Effectiveness Analysis of Armor Plates with Various Incident angles using Small Caliber Live Fire Test (소화기 실사격 실험 기반의 장갑 재질에 따른 입사각도별 방호성능 효과분석)

  • Lee, Gun-woo;Baek, Jang-Woon;Lee, Byoung-hwak;Kim, Jin-young;Kim, Jong-Hwan
    • Journal of the Korea Society for Simulation
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    • v.30 no.1
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    • pp.55-63
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    • 2021
  • As a study on ballistic protection performance of a weapon system that is used in combat simulation, this paper aims to propose an improvement effect of the ballistic protection performance varying with incident angle of a bullet. For this, live-fire ballistic tests were performed to determine either complete penetration(CP) and partial penetration(PP) of three types of general armor plates made of uniformly rolled steel plates against a small caliber threat using 5.45 mm bullets with various speed. The major test parameter was the material of the weapon system and incident angle of the bullet with the target. Further, to quantitatively analyze the ballistic protection performance, three existing measurement methods were used for ballistic limit velocity. The test results showed that the ballistic protection performance with the incident angle of 30 degrees was 4% to 14% varying with the material of the armor plates greater than that of 0 degrees, which was approximately 1.1 times the performance improvement on average when compared to the conventional angle of incidence of the 0 degree. Those test results are expected to contribute to developing a more realistic combat simulation addressing the parameter improving the ballistic protection performance of an armor plate.

Development of Adsorbent for Vapor Phase Elemental Mercury and Study of Adsorption Characteristics (증기상 원소수은의 흡착제 개발 및 흡착특성 연구)

  • Cho, Namjun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.5
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    • pp.1-6
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    • 2021
  • Mercury, once released, is not destroyed but accumulates and circulates in the natural environment, causing serious harm to ecosystems and human health. In the United States, sulfur-impregnated activated carbon is being considered for the removal of vapor mercury from the flue gas of coal-fired power plants, which accounts for about 32 % of the anthropogenic emissions of mercury. In this study, a high-efficiency porous mercury adsorption material was developed to reduce the mercury vapor in the exhaust gas of coal combustion facilities, and the mercury adsorption characteristics of the material were investigated. As a result of the investigation of the vapor mercury adsorption capacity at 30℃, the silica nanotube MCM-41 was only about 35 % compared to the activated carbon Darco FGD commercially used for mercury adsorption, but it increased to 133 % when impregnated with 1.5 % sulfur. In addition, the furnace fly ash recovered from the waste copper regeneration process showed an efficiency of 523 %. Furthermore, the adsorption capacity was investigated at temperatures of 30 ℃, 80 ℃, and 120 ℃, and the best adsorption performance was found to be 80 ℃. MCM-41 is a silica nanotube that can be reused many times due to its rigid structure and has additional advantages, including no possibility of fire due to the formation of hot spots, which is a concern when using activated carbon.

Developing Local Human Resources Program by Analyzing the Preference Factors for Enrollment of Higher Education in Seoul-Metropolitan Area: Focused on High School Students in Jeonbuk (수도권대학 진학 선호 요인 분석을 통한 지역인재 양성 프로그램의 방향 모색: 전북지역 고등학생을 중심으로)

  • Pak, Sungsine;Kim, Seok-soon
    • Journal of Practical Engineering Education
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    • v.14 no.1
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    • pp.205-217
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    • 2022
  • For high school students in Jeonbuk, this study aims to identify the problems caused by outflow of local youth population and their preference factors to enter university in Seoul-metropolitan area, and to draw out the direction of local human resources program, through questionnaire investigation and focused group interview. The main findings are as follows: First, 68.8% of high school students, especially the top grade students prefer to enter university in metropolitan area. The metropolitan cultural characteristics, such as reputation of universities and ranking, openness and anonymity, and urban infrastructure attract students. Second, there is a close relationship between the individual background, growth area - enrollment area - employment area, and the location dependency without return migration is very strong. Third, local human resources program was evaluated as a meaningful activity for high school students, in order to understand the further education and career, and have an interest in local universities. Therefore, it is necessary to discover industries consistent with local identity, create networks, develop and implement programs considering the actual educational conditions. The gender-free program, supplement program for the integrated curriculum, and contents that to supplement science subjects should be developed. Additionally, this issue could be resolved expanding the perspective of balanced national development and improve the local environment to enhance the urban attraction points.

The Relation of the Quality of Oriental Tobaccos to their Chemical Constituents II. Quality and Chemical Properties as Affected by Soil Moisture (환경요인에 따른 오리엔트종 잎담배의 화학적 특성과 품질과의 관계 II. 토양수분의 영향)

  • Ryu, Myong-Hyun;Jung, Hyung-Jin;Kim, Yong-Ok;Lee, Byung-Chul;Yu, Ik-Sang
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.33 no.3
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    • pp.242-247
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    • 1988
  • To elucidate the relationship of the quality of aromatic tobaccos to their chemical constituents, certain chemical components and leaf quality by price were compared among cured leaves produced under different soil moisture levels during growing season. As the soil moisture increased, plant height and the length and width of largest leaf increased. days to flower was shortened and total chlorophyll and carotenoid content of green leaf decreased. As the soil moisture increased, leaf quality was deteriorated. The content of nicotine, pet. ether ext. and total nitrogen increased with slight increment of nonvolatile organic acids and higher fatty acids, but ash content and pH of cured leaves decreased under high soil moisture content. Volatile organic acids such as 3-methyl pentanoic acid, the main compounds contributing to the aroma of oriental tobacco, and most volatile neutrals decreased conspicuously under high soil moisture. The content of pet. ether ext., volatile organic acids, volatile neutrals, ash and pH of cured leaves were found to be the appropriate factors for the quality evaluation of aromatic leaves grown under under different soil moisture.

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Ecological Monitoring on Changes in Microclimate, Vegetation and Soil Properties after 2 Years in Restoration Project Sites Linking the Ridgeline of Baekdudaegan (백두대간 생태축 복원사업 2년 후 산림미기상, 식생 및 토양특성 변화 모니터링)

  • Park, Yeong Dae;Kwon, Tae Ho;Ma, Ho Seop
    • Journal of agriculture & life science
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    • v.50 no.1
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    • pp.125-136
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    • 2016
  • The Korea Forest Service(KFS) has been initiating restoration activities of ridgeline in damaged and fragmented areas of Baekdudaegan since 2011. Completed project in Ihwaryeong, Yuksimnyeong & Beoljae(2012; 2013) were selected as sites for this study. The changes in microclimate condition, vegetation composition and soil properties between project sites and adjacent stands were compared to evaluate the effect of restoration at early stage(after 2years). Pinus densiflora was planted mainly for these restoration sites, however Robinia pseudoacacia and Alnus sibirica invaded the area two years after the restoration activities. Ihwaryeong showed the most changes in understory vegetation among the study sites. Exotic species, such as Ambrosia artemisiifolia, Oenothera odorata, Erigeron annuus, and Coreopsis tinctoria invaded Ihwaryeong, and the dominance have invaded currently. It resulted from the poor survival rate of trees and high difference in microclimate wherein there's an increased temperature and decreased humidity in both restored sites and adjacent stands. In addition, it is also caused by poor soil chemical property, especially pH and organic matter content due to lack of humus layer and its accumulation, compared to adjacent forest soil in restored sites. Significant difference on chemical soil property was observed between restored sites and adjacent forest but no significant difference was observed after two years of restoration. Ecological monitoring is needed to understand the ecological changes after restoration and to establish a long-term management strategy.

History of Disease Control of Korean Ginseng over the Past 50 Years (과거 50년간 고려인삼 병 방제 변천사)

  • Dae-Hui Cho
    • Journal of Ginseng Culture
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    • v.6
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    • pp.51-79
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    • 2024
  • In the 1970s and 1980s, during the nascent phase of ginseng disease research, efforts concentrated on isolating and identifying pathogens. Subsequently, their physiological ecology and pathogenesis characteristics were scrutinized. This led to the establishment of a comprehensive control approach for safeguarding major aerial part diseases like Alternaria blight, anthracnose, and Phytophthora blight, along with underground part diseases such as Rhizoctonia seedling damping-off, Pythium seedling damping-off, and Sclerotinia white rot. In the 1980s, the sunshade was changed from traditional rice straw to polyethylene (PE) net. From 1987 to 1989, focused research aimed at enhancing disease control methods. Notably, the introduction of a four-layer woven P.E. light-shading net minimized rainwater leakage, curbing Alternaria blight occurrence. Since 1990, identification of the bacterial soft stem rot pathogen facilitated the establishment of a flower stem removal method to mitigate outbreaks. Concurrently, efforts were directed towards identifying root rot pathogens causing continuous crop failure, employing soil fumigation and filling methods for sustainable crop land use. In 2000, adapting to rapid climate changes became imperative, prompting modifications and supplements to control methods. New approaches were devised, including a crop protection agent method for Alternaria stem blight triggered by excessive rainfall during sprouting and a control method for gray mold disease. A comprehensive plan to enhance control methods for Rhizoctonia seedling damping-off and Rhizoctonia damping-off was also devised. Over the past 50 years, the initial emphasis was on understanding the causes and control of ginseng diseases, followed by refining established control methods. Drawing on these findings, future ginseng cultivation and disease control methods should be innovatively developed to proactively address evolving factors such as climate fluctuations, diminishing cultivation areas, escalating labor costs, and heightened consumer safety awareness.

Petroleum Geochemistry of Organic Matter from the core samples in the Tertiary Pohang Basin (포항 분지 제3기층 시추코아 유기물의 석유 지화학적 특성)

  • Lee Youngjoo;Kwak Young Hoon;Yun Hye Su;Cheong Tae Jin;Oh Jae Ho;Kim Hagju;Kang Moohee
    • The Korean Journal of Petroleum Geology
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    • v.5 no.1_2 s.6
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    • pp.48-58
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    • 1997
  • Core samples from the B, E, F, H wells in the Tertiary Pohang Basin were analysed for total organic carbon (TOC) content and subject to Rock-Eval pyrolysis in order to assess petroleum geochemical characteristics of organic matter. Following geochemical screening, we selected samples from each well for the study of bitumen and kerogens such as optical observation, infra-red spectroscopy and biomarker analyses. Sediments of the Tertiary Yonil Group contain total organic carbon ranging from $0.55{\%} to 3.74{\%}$ with S1+S2 values higher than 2mgHC/g Rock in B, E and F wells, which indicates fair hydrocarbon generation potential. Most organic matter in the B, E, F wells is compared to type II based on the Rock-Eval pyrolysis, infra-red spectroscopy and optical observation. However, organic matter in the H well is compared to type III because the well is located at the margin of the basin where the preservation of terrestrial material is dominant. Geochemical analyses show that organic matter in the Yonil Group is thermally immature although thermal maturity slightly increases with depth. Maturity levels of the extracted kerogens are similar to those of bulk samples ($Tmax<435^{\circ}C$. Petroleum geochemical charateristics of the sediments in the Tertairy Yonil Group is fair in terms of the organic richness and hydrocarbon genetic potential, but organic matter is thermally immature due to the shallow burial depth. Optical observation of the kerogens and biomarker analysis show that organic matter in the Yonil Group is both marine and terrestrial origin, although it was deposited in marine environment. Pristane/phytane ratio suggests rather anoxic depositional environment. Transitional characteristics of organic matter indicate that the marine Yonil Group was deposited near the terrestrial environments. Input of terrestrial organic matter is more prevalent in the samples recovered from the lowermost horizon in the wells due to the terrestrial environment at the time of basin formation.

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Evaluation of Lead, Copper, Cadmium, and Mercury Species in the Leachate of Steel Making Slag by Seawater (해수에 의한 제강 슬래그의 납, 구리, 카드뮴 및 수은 화합물의 용출특성 평가)

  • Lee, Han-Kook;Lee, Dong-Hoon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.75-84
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    • 2005
  • The aim of this study is to evaluate the leaching characteristics of lead, copper, cadmium, and mercury from steel making slag by seawater. To demonstrate the leaching characteristics of heavy metals from steel making slag by seawater, it was carried to various leaching tests such as regular leaching tests, liquid/sold(LS) leaching test and pH static test. From the leachability of $Pb^{+2},\;Cu^{+2},\;and\;Cd^{+2}$ from steel making slag in pH static test, it is distinguished between distilled water and seawater. With distilled water, it is very low between pH 7-8 and pH 11-12. On the other hands, with the seawater, its leaching is higher than that of distilled water. In particular, concentration of $Hg^{+2}$ leached from slag by seawater is lower than that of distilled water. Meanwhile, we found that the heavy metals from steel making slag would be dissolved and precipitated using geochemcial equilibrium program such as visual minteq. Lead and copper leached from steel making slag with seawater were dissolved nearly in the range of pH 11-12, but in the range of pH 7-10 those were precipitated about 90%. And cadmium leached from steel making slag with seawater were dissolved completely. On pH static test with distilled water, lead leached from steel making slag seemed to be similar to pH static test with seawater. However, copper and cadmium leached from steel making slag were dissolved. In general, the species of lead leached from steel making slag were formed mainly of $PbCl^+,\;PbSO_4$, the species of copper were formed mainly of $CuSO_4,\;CuCO_3$, the species of cadmium were formed mainly of $CdCl^+,\;CdSO_4$ due to being sorbed with the anions($Cl^-,\;CO_3^{-2},\;SO_4^{-2}$) of the seawater. Both pH static test with seawater and distilled water, it is not in the case of the mercury. Most of mercury leached from steel making slag was precipitated(SI=0). Because the decreasing of $Hg^{+2}$ concentrations depends ferociously on the variation of chloride($Cl^-$) existed in the seawater. $Hg^{+2}$ leached from steel making slag could be sorbed strongly with chloride($Cl^-$) compared of carbonate($CO_3^{-2}$) and sulfate($SO_4^{-2}$) in the seawater. On the basis of that result, we found that the species of mercury was formed of calomel($Hg_2Cl_2$) as one of finite solid. Due to forming a calomel($Hg_2Cl_2$) in the seawater, the stability of mercury species by steel making slag should be higher than those of lead, copper, and cadmium species. Regarding the results stated above, we postulated that the steel making slag could be recycled to sea aggregates due to being distinguishing leachability of heavy metals($Pb^{+2},\;Cu^{+2},\;Cd^{+2},\;and\;Hg^{+2}$) between leaching tests by distilled water and seawater.

Behaviour of the Soil Residues of the Acaricide-Insecticide, [$^{14}C$]Acrinathrin;II. Degradation in Soil (살비살충제 [$^{14}C$Acrinathrin 토양 잔류물의 행적 규명;II. 토양중 분해)

  • Lee, Jae-Koo;Kyung, Kee-Sung;Oh, Kyeong-Seok
    • Korean Journal of Environmental Agriculture
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    • v.14 no.2
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    • pp.202-212
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    • 1995
  • In order to elucidate the degrading characteristics of the pyrethroid acaricide-insecticide, acrinathrin in two different types of soils, Soil A(pH, 5.8; organic matter, 3.4%; C.E.C., 115 mmol(+)/kg soil; texture, sandy loam) and Soil B(pH, 5.7; organic matter, 2.0%; C.E.C., 71 mmol(+)/kg soil; texture, sandy loam), residualities of the non-labeled compound under the field and laboratory conditions, extractability with organic solvents and formation of non-extractable bound residues, and degradabilities of [$^{14}C$]acrinathrin as a function of aging temperature and aging period were investigated. The half lives of acrinathrin in Soil A treated once and twice were about 18 and 22 days and in Soil B about 13 and 15 days, respectively, in the field, whereas, in the laboratory, those in Soil A and B were about 36 and 18 days, respectively, suggesting that the compound would be non-persistent in the environment. The amounts of $^{14}CO_2$ evolved from [$^{14}C$]acrinathrin in Soil A and B during the aging period of 24 weeks were 81 and 62%, respectively, of the originally applied $^{14}C$ activity, and those of the non-extractable soil-bound residues of [$^{14}C$]acrinathrin were about 70% of the total $^{14}C$ activity remaining in both soils, increasing gradually with the aging period. Degradation of [$^{14}C$]acrinathrin in both soils increased with the aging temperature. Three degradation products of m/z 198(3-phenoxy benzaldehyde), m/z 214(3-phenoxybenzoic acid), and m/z 228(methyl 3-phenoxybenzoate) as well as an unknown were detected by autoradiography of acetone extracts of both soils treated with [$^{14}C$]acrinathrin and aged for 15, 30, 60, 90, 120, and 150 days, respectively, and the degradation pattern of acrinathrin was identical in both soils. Acrinathrin in soil turned out to be degraded to 3-phenoxybenzaldehyde cyanohydrin by hydrolytic cleavage of the ester linkage adjacent to the $^{14}C$ with a cyano group, the removal of hydrogen cyanide therefrom led to the formation of 3-phenoxybenzaldehyde as one of the major products, and the subsequent oxidation of the aldehyde to 3-phenoxybenzoic acid, followed by decarboxylation would lead to the evolution of $^{14}CO_2$.

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