• Title/Summary/Keyword: 확산계수(D)

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Experimental Study of the Relationship between Weight Variation and Thermal Conductivity in Polyurethane Foam (단열재의 무게변화와 열전도도와의 상관관계에 관한 실험적 연구)

  • Lee, Hyo-Jin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.27 no.5
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    • pp.241-246
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    • 2015
  • Cellular foamed insulation such as polyurethane foam ages and degrades the thermal conductivity. Aging of foam is a result from the diffusion of gases, initially consisting of $CO_2$ but eventually replaced by air from the environment. The variation of the cell gas content with time is primarily influenced by the increase of thermal conductivity of the cellular foam. The weight of foam also changes as the gas diffuses and exchanges. In this study, a weight measurement method has been proposed to evaluate the effective diffusion coefficients of $CO_2$ and Air, $D_{CO2}=7.08504E-11$ and $D_{air}=4.86086E-12$, respectively and are compared with the gas analysis method.

The Drying Characteristics of Apples at Various Drying Conditions (사과의 건조조건(乾燥條件)에 따른 건조특성(乾燥特性))

  • Jung, Shin-Kyo;Choi, Yong-Hee;Shon, Tae-Hwa;Choi, Jong-Uck
    • Korean Journal of Food Science and Technology
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    • v.18 no.1
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    • pp.61-65
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    • 1986
  • This study was performed to examine the drying characteristics of apples at various drying conditions. Air velocity has no effect on the drying rate except the constant rate period. In this experiment the diffusion coefficients of moisture in the apple tissue were in the range of $1.1470-2.2148{\times}10cm^2/sec$. As a result of balance of heat and mass transfer during the falling rate period. an empirical equation based on Fick's law was obtained as follows; $log{\Delta}t\;=\;log\;t_o\;-\;D{\frac{{\pi}^2{\theta}}{4d.}}$ This equation can be used to calculate the temperature of apples during the falling rate period, provided the diffusion coefficients of apple are known. The experimental values of the internal moisture distribution during apple dehydration were nearly in accord with the theoretical values.

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Kinetic Studies on Hydration of Akibare and Milyang 23 Brown Rice (아끼바레와 밀양 23호 현미의 수화속도)

  • Kim, Kwang-Joong;Pyun, Yu-Ryang;Cho, Eun-Kyung;Lee, Sang-Kyu;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.16 no.3
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    • pp.297-302
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    • 1984
  • Kinetics of water diffusion during soaking of two brown rice varieties, Akibare (traditional rice) and Milyang 23 (high-yielding rice), were studied. Brown rice reached at the equilibrium moisture content after 18 hours. The absorption of liquid water by brown rice grain was directly proportional to the square root of hydration time and could be described by the simplified solution of Fick's diffusion equation. The diffusion coefficient was given by the Arrhenius relation: $D\;=\;2.738{\time}10^{-1}\;exp\;(-9,300/RT)$ for Akibare and $D\;=\;4.302{\time}10^{-1}\;exp\;(-9,500/RT)$ for Milyang 23. Hydration rate calculated from hardness change followed the equation of a first order reaction. Hydration mechanism of brown rice was changed at the gelatinization temperature of rice starch.

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Modeling of thermal fluidized desorption for diesel-oil contaminated soils (Diesel-oil에 오염된 토양의 유동상 열탈착 모델링)

  • 이상화;김병욱;이상득;박달근;이중기
    • Journal of Korea Soil Environment Society
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    • v.4 no.2
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    • pp.137-147
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    • 1999
  • Fluidized-bed thermal desorber coupled with a heat pipe was investigated for the remediation of soil contaminated with diesel oils. Thermal gravimetric analysis by Cahn-balance indicated that the desorption of diesel oils from the soil particles was mainly governed by the internal diffusion at low concentration of less than 0.5 wt. % of oils in the soil particles. In fluidized-bed experiments. increase of fluidizing gas velocity reduced the residual oils of the contaminated soils, the increase of soil feed rate decreased efficiency of fluidized-bed desorber. A mathematical model was developed by incorporating Fickian diffusion kinetics into the Kunii-Levenspiel model Simulation results showed reasonable agreement for the performance of fluidized-bed thermal desorber.

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On the Crystal Growth of Gap by Synthesis Solute Diffusion Method and Electroluminescence Properties. (합성용질확산법에 의한 GaP결정의 성장과 전기루미네센스 특성)

  • Kim, Seon-Tae;Mun, Dong-Chan
    • Korean Journal of Materials Research
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    • v.3 no.2
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    • pp.121-130
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    • 1993
  • The GaP crystals were grown by synthesis solute diffusion method and its properties were investigated. High quality single crystals were obtained by pull-down the crystal growing ampoule with velocity of 1.75mm/day. Etch pits density along vertical direction of ingot was increased from 3.8 ${\times}{10^4}$c$m^{-2}$ of the first freeze to 2.3 ${\times}{10^5}$c$m^2$ of the last freeze part. The carrier concentration and mobilities at room temperature were measured to 197.49cc$m^2$/V.sec and 6.75 ${\times}{10^{15}}$c$m^{-3]$, respectively. The temperature dependence of optical energy gap was empirically fitted to $E_g$(T)=[2.3383-(6.082${\times}{10^{-4}}$)$T^2$/(373. 096+TJeV. Photoluminescence spectra measured at low temperature were consist with sharp line-spectra near band-gap energy due to bound-exciton and phonon participation in band edge recombination process. Zn-diffusion depth in GaP was increased with square root of diffusion time and temperature dependence of diffusion coefficient was D(Tl = 3.2 ${\times}{10^3}$exp( - 3.486/$k_{\theta}$T)c$m^2$/sec. Electroluminescence spectra of p-n GaP homojunction diode are consisted with emission at 630nm due to recombination of donor in Zn-O complex center with shallow acceptors and near band edge emission at 550nm. Photon emission at current injection level of lower than 100m A was due to the band-filling mechanism.

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Measurement and Comparative Analysis of Propagation Characteristics in 3, 6, 10, and 17 GHz in Two Different Indoor Corridors (두 가지 서로 다른 실내 복도에서 3, 6, 10, 17 GHz의 전파 특성 측정 및 비교 분석)

  • Seong-Hun Lee;Byung-Lok Cho
    • The Journal of the Korea institute of electronic communication sciences
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    • v.18 no.6
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    • pp.1031-1040
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    • 2023
  • Propagation characteristics in line-of-sight(LOS) paths in 3, 6, 10, and 17 GHz frequency bands were measured and analyzed in two different indoor corridors: second floors of Buildings D2 and E2. The measurement was designed to measure when the receiving antenna moved at 0.5 m intervals from 3 m to 30 m, while the transmission antenna was fixed. The analysis of the two indoor corridors was compared by applying basic transmission loss, root mean square (RMS) delay spread, and K-factor. For basic transmission loss, the loss coefficient of the floating intercept path loss model was higher in the indoor corridor of Building E2 than in that of Building D2. Similarly, the RMS delay spread in the time domain was greater in the indoor corridor of Building E2. However, the indoor corridor of Building D2 exhibited higher K-factor in the 3, 6, and 17 GHz bands with lower wave propagation in the 10 GHz band. Despite the 2 indoor corridors being identical, the propagation characteristics varied due to different internal structures and materials. The results provide measurement data for ITU-R Recommendations regarding various indoor environments.

An Experimental Study on the Chloride Attack Resistibility of Alkali-Activated Ternary Blended Cement Concrete (알칼리 활성화 3성분계 혼합시멘트의 염해 저항성에 관한 실험적 연구)

  • Yang, Wan-Hee;Hwang, Ji-Soon;Jeon, Chan-Soo;Lee, Sea-Hyun
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.4
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    • pp.321-329
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    • 2016
  • The use of ternary blended cement consisting of Portland cement, granulated blast-furnace slag (GGBFS) and fly ash has been on the rise to improve marine concrete structure's resistance to chloride attack. Therefore, this study attempted to investigate changes in chloride attack resistibility of concrete through NT Build 492-based chloride migration experiments and test of concrete's ability to resist chloride ion penetration under ASTM C 1202(KS F 2271) when 1.5-2.0% of alkali-sulfate activator (modified alkali sulfate type) was added to the ternary blended cement mixtures (40% ordinary Portland cement + 40% GGBFS + 20% fly ash). Then, the results found the followings: Even though the slump for the plain concrete slightly declined depending on the use of the alkali-sulfate activator, compressive strength from day 2 to day 7 improved by 17-42%. In addition, the coefficient from non-steady-state migration experiments for the plain concrete measured at day 28 decreased by 36-56% depending on the use of alkali-sulfate. Furthermore, total charge passed according to the test for electrical indication of concrete's ability to resist chloride ion penetration decreased by 33-62% at day 7 and by 31-48% at day 28. As confirmed in previous studies, reactivity in the GGBFS and fly ash improved because of alkali activation. As a result, concrete strength increased due to reduced total porosity.

A Study on the Migration Characteristics of Cs-137 in a Packed Column (충전층에서의 세슘-137의 이동특성에 관한 연구)

  • Lee, Jae-Owan;Cho, Won-Jin;Han, Kyung-Won;Park, Hun-Hwee
    • Nuclear Engineering and Technology
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    • v.22 no.1
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    • pp.20-28
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    • 1990
  • In this study the migration experiment using packed column with crushed tuff was conducted as a basic research to develop migration model of radionuclides through geologic media. The main emphasis was put on evaluating the validity of migration models. For this, two models were introduced: one is the model which is based on the assumption of instantaneous equilibrium reaction and the other the model based on kinetic process such as intraparticle diffusion. The coefficient of hydrodynamic dispersion in packed column was determined using iodine as nonsorbing tracer. The hydrodynamic dispersion coefficient, D$_{L}$ was shown to be 0.11$\times$10$^{-2}$ $\textrm{cm}^2$/min under the condition of the column porosity of 0.483 and the average water velocity of 0.915$\times$10$^{-2}$ cm/min. The distribution coefficient, Kd of Cs-137 on crushed tuff was 11.3 cc/g at the concentration of 2$\times$10$^{-6}$ M and the temperature of 2$0^{\circ}C$. The breakthrough curve of Cs-137 through packed column was shown to have an asymmetric curve in which long trailing tail appears at the end part of the curve. The results obtained from the comparison of introduced models with experimental data indicated that the mass transfer model with intraparticle diffusion as rate-controlling step simulated the behaviors of Cs-137 migration more adequately, when compared with the bulk reaction model in which the assumption of instantaneous equilibrium reaction was maded. Consequently, the intraparticle diffusion was found to be an important factor in the migration of Cs-137 through packed column.n.

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Study on Characteristics of Transient Soulte Transport in the Vadose Zone by Using TDR: (2) Application (TDR(Time Domain Reflectometry)를 이용한 비포화 토양에서 천이상태의 오염원 이송확산 특성에 관한 연구 : (2) 적용)

  • Park, Jae-Hyeon;Seo, Il-Won
    • Journal of Korea Water Resources Association
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    • v.32 no.6
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    • pp.751-762
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    • 1999
  • In this study, a 1-D laboratory experiment was conducted to investigate the characteristics of transient unsaturated solute transport by using two kinds of soils of which properties were known by test. Especially the TDR method which is proposed in this study was used to measure water content and solute concentration. As results, in the transient flow, the wetting front moves down rapidly, and the distribution of solute concentration near the wetting front showed the similar type of the water content distribution(semi-bell type). A numerical model HYDRUS was used to compare with the experimental results. Numerical results for the water movement are similar to experimental result. However, numerical results of the distribution of solute concentration are more scattered than experimental results. It means that measured dispersivity, numerical dispersion, adsorption coefficient, and soil sample size etc. should be considered in order to determine the dispersivity used in the numerical model. The present measuring method was proved to be superior to other formula and to be an available method to apply to solute transport test. The measuring error of the developed method is estimated smaller than 10% while water content is larger than 0.15.

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Effects of Lower-Bound Resistances on Resistance Factors Calibration for Drilled Shafts (하한지지력이 현장타설말뚝의 저항계수에 미치는 영향)

  • Kim, Seok-Jung;Park, Jae-Hyun;Kim, Myoung-Mo
    • Journal of the Korean Geotechnical Society
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    • v.30 no.11
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    • pp.51-60
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    • 2014
  • Load and Resistance Factor Design (LRFD) is one of the limit state design methods, and has been used worldwide, especially in North America. Also, the study for LRFD has been actively conducted in Korea. However, the data for LRFD in Korea were not sufficient, so resistance factors suggested by AASTTO have been used for the design in Korea. But the resistance factors suggested by AASHTO represent the characteristics of bedrocks defined in the US, therefore, it is necessary to determine the resistance factors for designs in Korea, which can reflect the characteristics of bedrocks in Korea. Also, the calculated probabilities of failure from conventional reliability analyses which commonly use log-normal distribution are not realistic because of the lower tail that can be extended to zero. Therefore, it is necessary to calibrate the resistance factors considering the lower-bound resistance. Thus, this study calculates the resistance factors using thirteen sets of drilled shaft load test results, and then calibrates the resistance factors considering the lower-bound resistance corresponding to a target reliability index of 3.0. As a result, resistance factors from conventional reliability analyses were determined in the range of 0.13-0.32 for the shaft resistance, and 0.19-0.29 for the base resistance, respectively. Also, the lower bounds of resistance were determined based on the Hoek-Brown failure criteria (2002) and GSI downgrading. Considering the lower-bound resistances, resistance factors increased by 0~8% for the shaft, and 0~13% for the base, respectively.