• Title/Summary/Keyword: 화형

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Synthesis and Properties of Self-photocuring Polyurethane Acrylate Oligomer for Color Pre-coated metal (선도장 컬러강판용 도료에 적용하기 위한 자가 광경화형 폴리우레탄 아크릴레이트 올리고머 합성 및 물성)

  • Park, So-Young;Cheon, Jungmi;Jeong, Boo Young;Lee, Do Hyeok;Chun, Jae Hwan
    • Journal of Adhesion and Interface
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    • v.21 no.1
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    • pp.14-19
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    • 2020
  • In this study, we synthesized a self-photocuring intermediate(SPI) by Michael addition reaction and synthesized polyurethane acrylate oligomer. Analysis and physical properties of the synthesized SPI and polyurethane acrylate oligomer were confirmed by FT-IR, NMR and UTM. As the content of the SPI increased, the tensile strength increased and the elongation decreased. In addition, since the film was hydrophobic, the surface energy tended to decrease. When the content of the SPI was 40 wt%, adhesion, processability, and pencil hardness were excellent, and solvent resistance was excellent overall.

Analysis and Improvement of ID-based Key Distribution Systems (개인정보에 기초한 키 분배방식의 분석 및 개선방안)

  • 임채훈
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.1 no.1
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    • pp.47-65
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    • 1991
  • An ID-based scheme provides a very efficient solution to the key distribution problem, since it can solve bothe the authentication problem and the communication complexity problem in a public key scheme. Especilly, and ID-Based ndninterative key distribution system plays an crucial roie in the one-way communication environment such as secure electronic mail, owing to its noninteractiveness. This paper aims at analyzing the previously proposed scheme s and providing possible improvements. It also demonstraes that the Maurey-Yacobi's scheme presented in Eurocry'91 is not secure, and provikdes an countemeasure to overcome the security problem.

The annual variation pattern and regional division of weather eatropy in South Korea (남한의 일기엔트로피의 연변화유형과 지역구분)

  • ;Park, Hyun-Wook
    • Journal of the Korean Geographical Society
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    • v.30 no.3
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    • pp.207-229
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    • 1995
  • The characteristics of weather and climate in South Korea has great influences on the annual variation pattern and the appearance of the prevailing weather. The purpose of this paper is to induce the quantity of the weather entropy and annual variation pattern using the information theory and the principal component analysis. And author tried to classify the region according to the variation of its space scale, The raw materials used for this study are the daily cloudiness and precipitation during the years 1990-1994 at 69 stations in South Korea. It is divided into four classes of fine, clear, cloudy and rainy. The rcsults of this study can be summarized as follows: 1. Thc characteristics of annual variation pattern of weather entropy can be chiefly divided into five categories and the accumulated contributory rate of these is 73.1%. 2. Annual variation pattern of the first principal component reaches smaller in May, April and September than national average, and becomes greater when the winter comes. This weather entropy's quantity(Rs1) is positive in most area to the western sife of Soback Mountains and negative in most seaside area to the eastern side of Soback Mountains. 3. The characteristics of annual variation pattern of the second principal component shows that the entropy is more smaller in summer than national average and the rest of seasons shows larger, especially in January, May and September. This weather entropy's quantity(Rs2) is positive in most Honam Inland area to the western side of Soback Mountains and negative in most Youngnam Inland area to the eastern side of Soback Mountains. 4. Eight type regions (S1-S11) are classified based on the occurrences of minimum weather entropy in South Korea, and annual variation pattern of weather entropy by principal component analysis may be classified into sixteen type regions (Rs1-Rs9). Putting these things together, South Korea can be classifieed into thirty one type regions (Rs1S7-Rs9S10).

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Evaluation of Physical Properties according to Mixing Ratio and the Survey of the Current Situation for Epoxy Resin used in Conservation (문화재 보존처리에 사용되는 에폭시수지의 사용현황과 배합비율에 따른 물성 변화 연구)

  • Lee, Eun Ji;Jang, Sung Yoon
    • Journal of Conservation Science
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    • v.32 no.2
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    • pp.223-234
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    • 2016
  • Two-component epoxy resin is widely used in the cultural heritage restoration field. However according to mixing ratio of resin and hardener, curing property, mechanical strength and chemical structure differ which have possibility to effect the stability of cultural heritage. Result of questionnaire survey shows hands-on workers in the conservation field tend to mix the epoxy resin with his or her eye measurement when the using amount is small or mix additional hardener to shorten the pot life of epoxy resin. This research aims to analyze the curing property, mechanical strength and chemical structure of rapid curing type epoxy resin and medium curing type one depending on relative ratio of 0.25~4 of hardener to resin. When the amount of hardener was 0.5~2 times more than the resin, exothermic heat and curing speed were both increased. In case of included hardener to resin was lower than official ratio, mechanical strength (tensile shear strength, tensile strength and compressive strength) became higher along with active cross-linking bonding of the epoxy resin. Medium curing type epoxy relatively had lower exothermic heat and slower reaction during curing process. It was observed to be put to definite point of mechanical strength under lower content of hardener than official ratio. While, hardener ratio more than twice the resin slowed down the curing greatly and lowered the adhesion strength also. In conclusion, under the lower mixing rate of hardener than official ratio would show relatively fast reaction with similar mechanical strength. Over the official ratio on the other hand, material property drops rapidly. Accordingly, mixing ratio of epoxy resin is expected to be influential to the stability of cultural heritage.

Fundamental Model Development for Rehabilitation of the Roadside Slopes (도로(道路)비탈면의 경관안정(景觀安定)을 위한 기본(基本)모델 설정(設定)에 관한 연구(硏究))

  • Woo, Bo Myeong
    • Journal of Korean Society of Forest Science
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    • v.61 no.1
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    • pp.69-79
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    • 1983
  • To develope the fundamental models suitable for slope stabilization and scenic effect improvement of the roadside slopes, this study has continuously been conducted for last about 10 years through the field survey and observations on the roadside slopes of 100 plots located in the Capital region. The results obtained could be summarized as follows: 1) In general, due to unsuitable treatments and constructions to the man-made bare slope characteristics of the roadsides, the treatment aims for stabilizing and improving the scenic beauty of the slopes have not been successfully reached in the surveyed regions. 2) Particularly, because of insufficiency of the follow-up maintenance techniques to the roadside slopes treated, denudations of slope scenery established as well as the withering of the vegetation planted have been accelerated for the most part of the slopes treated. 3) 6 fundamental models for the roadside slope treatments have been developed and could be edaptable to the nation-wide purposes. The fundamental models are the model of forest scenery match plantation, roadside scenery establishment, denuded land rehabilitation, rock slope greenification, absolute stabilization, and environmental plantation belt establishment, respectively.

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Escaping Uncertainty: Elementary Students' Emotional-Cognitive Rebuttals in the Argumentation of "Why Did the Kidney Beans not Germinate?" (불확실함에서 벗어나기까지: "왜 강낭콩이 싹트지 않았을까?" 논변 활동에서 초등학생들의 정서-인지적 반박)

  • Han, Moonhyun
    • Journal of The Korean Association For Science Education
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    • v.40 no.1
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    • pp.1-12
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    • 2020
  • In scientific argumentation, students can use rebuttals to escape uncertainty, which, in this case, can be defined as a vague and fuzzy feeling about other students' explanations. As rebuttals can play a critical role in the sophistication of arguments and the alleviation of uncertainty, this study aims to understand the dynamics of uncertainty and rebuttals by exploring the context of the uncertainty experienced by elementary school students in the argumentation of "Why did the kidney beans not germinate?" and to get insights based on the research results. Twenty fourth-grade students and their homeroom teacher in Kyong-Ki province, South Korea, took part in the research. Students engaged in argumentation in five small groups of four students. The researcher collected qualitative data through video transcriptions, student interviews, and field notes. In the data analysis, the researcher employed the constant comparative method to explore in what context students experienced uncertainty and how they used rebuttals. The results of this study were as follows: First, students tried to reduce their uncertainty through argumentation on why the kidney beans did not germinate. Second, students used elaboration-oriented rebuttals, personal opinion-oriented rebuttals, and blame-oriented rebuttals to reduce this uncertainty. However, when they used blame-oriented rebuttals, their uncertainty and negative emotions increased. Third, intervention by the teacher led students to stop using blame-oriented rebuttals. Instead, they employed elaboration-oriented rebuttals to explore why the kidney beans would not sprout, and finally, they escaped uncertainty by discovering an appropriate explanation. Based on the findings of this study, the researcher discussed how the interaction between uncertainty and elaboration-oriented rebuttals could shape and facilitate argument development in elementary school students.

UV Curing and Peeling Characteristics of Acrylic Coating Ink with Various Amounts of Photoinitiator, Oligomer and Talc (광개시제, 올리고머 그리고 Talc 함량에 따른 아크릴계 코팅제의 UV경화 및 박리특성)

  • Yang, Jee-Woo;Seo, Ah Young;Lee, Chul Woo
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.499-506
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    • 2013
  • As the usuage of tempered glass for touch panel increased rapidly with the development of industry, the amount of UV curable coating solution used to protect glass surfaces during a tempered glass manufacturing process increased as well. The UV curable coating has advantages compared to thermal curing such as shortened curing time and non-solvent. Appropriated polymer and monomer were used as an acid polymer to grant an alkali peeling ability. The monomers were 2-hydroxyl methylacrylate, 1,6-hexanediol diacrylate and dipentaerythritol hexaacrylate which have acryl groups of 1, 2, and 6, respectively. The combination of three different types of photoinhibitors were used and bisphenol A epoxy diacrylate was used as an oligomer. In this study, experiments were carried out by controlling the amount of photoinitiator, oligomer, and additive while maintaining the constant content of the acid polymer and the acrylic monomer. The changes in physical properties according to the additive content were investigated. It was found that the combination of photoinitiators was necessary to achieve the hardness above 4H and it was possible to control the delamination type of the coating film from a sheet to pieces by the addition of TPO as an initiator. The increase in oligomer contents increased the hardness and adhesiveness alongside dissection time. Talc content of 20 wt% showed the best results.

The Variation Patterns over a Period of 10 Days and Precipitation Regions of Summer Precipitation in Korea (한국의 하계 강수량의 순변화 유형과 강수지역)

  • Park Hyun-Wook;Ryu Chan-Su
    • Journal of the Korean earth science society
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    • v.26 no.5
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    • pp.417-428
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    • 2005
  • The seasonal variation and frequency of precipitation phenomenon of the Korean Peninsula in summer show strong local weather phenomena because of its topographical and geographical factors in the northeastern area of Asia. The characteristics of the prevailing weather patterns in summer precipitation in Korea have great influences on the variation patterns and the appearances over a ten-day period during the summer precipitation. The purpose of this paper is to induce variation patterns over a period 10 days during the summer precipitation, clarify the variations of their space scales, and study the subdivision of precipitation regions in Korea according to the combinations of precipitation amounts and variation pattern during the period, using the mean values during the years $1991\~2003$ at 78 stations in Korea. The classified precipitation of a period of 10 days of summer precipitation, and the principal component vector and the amplitude coefficient by the principal component analysis were used for this study. The characteristics of variation pattern over the ten-day period can be chiefly divided into two categories and the accumulated contributory rate of these is $64.3\%$. The variation patterns of summer precipitation during period of 10 days in Korea are classified into 9 types from A to K. In addition, regional divisions of summer precipitation in Korea can be classified into 17 types.

A study on the Manufacture and Application of UV-Cured Anti-stain Coating Compounds for PVC Tile (PVC 바닥상재용 광경화형 내오염 코팅액의 제조 및 응용에 관한 연구)

  • Yoon, Hyun-Jung;Ha, Jin-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.5
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    • pp.1741-1746
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    • 2010
  • This study is on development of UV-cured anti-stain coating compounds which have more improved anti-stain function to prevent a surface of PVC tile from stain. To make an anti-stain coating composition, water soluble antistatic agent made from ammonium(IV) salt, antistatic agents for acrylic and polyurethane were used. Their contents varied from 5 to 20wt% against quantities of resin in coating composition. After coating PVC tiles using bar-coating method that can adjust a thickness, we estimated surface properties of coated layer such as anti-stain, electric resistance, adhesive power, thickness of coating, and so on. Results showed that a coating composition added 15wt% of water soluble antistatic agent and coated with No.12 bar-coater had the optimum surface property in electric resistance($3.24{\times}10^9{\Omega}/cm^2$), anti-stain(ink Test, Dust Test) and adhesive power. We could also find electric resistance and anti-stain effect were improved as antistatic agent content increased. However, excessive addition of antistatic agents(over 20wt%) caused the migration.

Influences of Father's Involvement in Parenting on Child's Problematic Behaviors and Mother's Psychological Well-being: Focused on Latent Classes Growth Analysis (아버지 양육참여 변화 유형에 따른 자녀의 문제행동 및 어머니의 심리적 특성 차이 비교: 잠재계층성장모형 적용을 중심으로)

  • Yeon, Eun Mo;Choi, Hyo-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.1
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    • pp.468-476
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    • 2020
  • This study investigated how latent groups depend on the longitudinal trajectories observed in fathers' involvement in parenting over a five year period, and the study also determined differences in children's behavioral problems and mother's parenting stress, marital satisfaction, and depression among these groups. By utilizing 1,316 sets of data from 1st to 5th Panel Survey of PSKC beginning in 2008, we examined the patterns of the latent groups and the differences among them. The results showed that, first, a changing pattern of fathers' involvement in parenting is classified into four groups: a low-stable group, a decreasing group. a middle-high changeable group, and a highest changeable group. According to the results of the latent groups, the fathers' involvement in parenting commonly started to decrease at the children's age of 4 years old. Second, problematic behaviors of children appeared more from the fathers in the decreasing group. Third, parenting stress, marital conflict, and depression were more often found in the low-stable group that in the decreasing group. the middle-high changeable group and the highest changeable group (in that order), while marital satisfaction showed a completely opposite pattern. Based on these results, political intervention and the future direction of research for fathers' involvement in parenting are needed in order to increase better behaviors of their children as well as the psychological well-being of their mothers.