• Title/Summary/Keyword: 화학 영역

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Selective Epitaxy Growth of Multiple-Stacked InP/InGaAs on the Planar Type by Chemical Beam Epitaxy (화학적 빔 에피탁시에 의한 평면구조에서의 InP/InGaAs 다층구조의 선택적 영역 에피 성장)

  • Han, Il-Ki;Lee, Jung-Il
    • Journal of the Korean Vacuum Society
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    • v.18 no.6
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    • pp.468-473
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    • 2009
  • Selective area epitaxy of multiple-stacked InP/InGaAs structures were grown by chemical beam epitaxy. The width of top of the multiple-stacked InP/InGaAs layer which were selectively grown on the stripe lines parallel to the <011> direction was narrowed, while the width of top of the multiple-stacked InP/InGaAs layer on the stripe lines parallel to the <01-1> was widen. This difference according to the <011> and <01-1> direction was explained by the growth of InGaAs <311>A and B faces on the (100) InP surface on the stripe lines parallel to the <01-1> direction. Under growth rate of $1\;{\mu}m/h$, top of the multiple-stacked InP/InGaAs was flattened as the pressure of group V gas was decreased. This phenomenon was understood by the saturation of group V element on the surface.

The Study for Diffusion Mechanism of Amino Acids Through Poly(2-Hydroxyethyl Methacrylate) Membrane (Poly(2-Hydroxyethyl Methacrylate)막을 통한 아미노산의 확산 기구에 관한 연구)

  • Kim Ui-Rak;Jeong Bong-Jin;Lee Myung-Jae;Min Kyung-Sub
    • Journal of the Korean Chemical Society
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    • v.37 no.1
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    • pp.10-21
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    • 1993
  • The transport phenomena of ten amino acid molecules through poly(2-hydroxyethyl methacrylate), P(HEMA) membrane have been investigated in various range pH solutions. It is found that the permeability and diffusivity of the amino acids through membrane depended on the different shape, size and the charge of them are changed by the pH. The permeabilities and diffusivities of amino acids have the largest value in the neutral solution. In this case, they are diffused through free water in the P(HEMA) membrane and the diffusion mechanism is the pore type. The basic solution have larger value than the acidic it. Whether the diffusion mechanism of the core type or the partition type, it is depended on the effect of side chain of the amino acid in basic and acidic solution.

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Exploration of Features of Korean Students' Performance in Science (우리나라 학생들의 과학 영역 성취 특성 탐색)

  • Kim, Hyun Jung
    • Journal of the Korean Chemical Society
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    • v.65 no.1
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    • pp.25-36
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    • 2021
  • This study aimed to analyze achievement characteristics of Korean students in the results of PISA 2018 science domain. To this end, the characteristics of PISA 2009 to PISA 2018 science were analyzed in terms of the percentage of each performance level and the ratio of male and female by achievement level; in addition, the percentage of correct answers by framework subscale was compared with PISA 2015. The results showed that Korea has a higher percentage of students at the lower level of achievement as compared to the high-ranking countries of PISA, and the ratio of students at the higher level of achievement was lower. On average, the difference in achievement between boys and girls was negligible; however, but at the higher achievement level, the ratio of boys continued to be higher than that of girls. In addition, in the PISA science framework, the percentage of correct answers of the questions corresponding to 'personal' of 'contexts', 'evaluate and design scientific enquiry' of 'competencies', 'epistemic' of 'knowledge', and 'high' of 'cognitive demand' increased; similarly, and achievement improved as compared to PISA 2015. Based on these results of the study, we propose a method for improving teaching and evaluation to foster Korean students' scientific competence.

Characteristics of sub-80 nm three-layered film manufactured by continuous roll-to-roll processes (연속 롤투롤 공정을 이용한 80 나노 이하의 3층 구조 필름 제조 및 특성)

  • Nam Il Kim;Geug Tae Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.5
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    • pp.191-195
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    • 2023
  • Three-layer nano-coated films in applications for the back cover of mobile cellular phones were prepared utilizing a roll-to-roll continuous process. By introducing a coating layer with a ceramic/metal/ceramic three-layer structure, the inherent reflective properties of the metals were maintained while electrically insulating properties were maintained. The thickness of the composite coating layer on a large area PET film with a length of 1,500 nm and width of 500 nm was less than 60 nm, and a uniform thickness was maintained in all areas. The transmittance according to the wavelength range (240~1600 nm) of the nanocoating film gradually increases as the wavelength increases, and is about 48 % at 1,000 nm, which is within the infrared region, and about 35.5 % at 550 nm, which is within the visible region. These results meet the required level of coated backcover (< 40 %).

An Analysis of Inquiry Activities in the Chemistry Parts of Middle School Science Textbook Based on the Sixth Curriculum (제 6차 교육과정에 따른 중학교 과학(화학부분) 교과서의 탐구활동 분석)

  • Moon, Seong Bae;Jun, Sung Ae;Kim, Yun Hi
    • Journal of the Korean Chemical Society
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    • v.45 no.2
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    • pp.162-176
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    • 2001
  • This study was covered with the analysis of five kinds of the middle school science text books(chemistry part) based on the oth curriculum. Particularly, inquiry activities part was analyzed by the three dimension framework which consists of inquiry content dimension, inquiry process dimension and inquiry context dimension and the results are as follows;1. In the analysis of the contents in the middle school science textbooks(chemistry part), the average number of total pages was 197.6. The illustration and picture were contained 0.66 in number per a page, and the average number of further readings was 5.8.2. In the analysis of the inquiry content dimension of inquiry activities, the total number of themes in five kinds of textbooks was 222. And the number of imquiry activities in five kinds of textbooks was siverse : A textbook had 51, B texbook 49, C textbook 37 and E textbook 35.3. For the analysis of inquiry process dimension. it follows in the order of 'interpreing data and formulating generalizations (42.4%)','observation and measuring (38.1%)','seeing a problem and seeking ways to solve it (7.8%)' and 'building, testing and revising the theoretical model(11.7%)'.4. As for the analysis of the inquiry context dimension, the scientific context occupied 94.2%, the individual context 0.4%, the social context 2.7% and the technical context 2.7%. It shows that the proportion of STS(Science-Technology-Society) related contents in inquiry activities was only 5.8%.

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The Development of Performance Scoring Rubrics for the Inquiry-Based General Chemistry Experiments (탐구적 일반화학실험 수행 평가 준거 개발)

  • Kang, Soon-Hee;Kim, Yang-Hyun;Park, Jong-Yoon
    • Journal of The Korean Association For Science Education
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    • v.19 no.4
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    • pp.507-515
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    • 1999
  • This study is to develope the performance scoring rubrics for the inquiry-based experiments of general chemistry course in the college of education. Two types of analytic scoring rubrics have been developed for nine different experiments. The first one is to assess scientific process skills from the written experimental reports. These analytic scoring rubrics include seven process skills selected from the Lawson's 'creative and critical thinking skills' and other known process skills. The second one is to assess the individual manipulative skills and experimental attitudes through direct observations by the teacher. The content validity of all scoring rubrics was testified by six science educators. Also the inter-scorer reliability of analytic scoring rubrics administered on the students' experimental reports was examined. The correlation coefficient between the scores obtained from the experiments and those of the written test for theoretical knowledges was found to be r=.663(p <.01). From the variance($r^2$=.440), we would say indirectly that the 56% of this experimental assessment does not overlap with the theoretical knowledges test and assesses students' science process skills, manipulative skills, and attitudes.

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Silicone Rubber Membrane-Based Chloride Ion-Selective Electrode (실리콘러버-지지체 염화이온선택성 막전극)

  • Sakong, Dong-Sik;Kim, Jin-Mog;Cha, Jin-Mog
    • Journal of the Korean Chemical Society
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    • v.41 no.12
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    • pp.653-660
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    • 1997
  • Silicone rubber-matrix membranes doped with tetradecyltrimethylammonium chloride (TDTMACl) are used to enhance electrode performance for chloride measurements in physiological samples. The optimized membrane formulation incorporates 95.4 wt% silicone rubber and 4.6 wt% TDTMACl, and its pH response is negligible in the range of pH 6-10. The TDTMACl-doped silicone rubber membrane exhibits sub-Nernstian response to chloride from 10 to 300 mM (-37.5 mV/decade), but its selectivities for chloride over other anions are remarkably enhanced: KpotCl,NO3=1.3, KpotCl,I=2.0, KpotCl,Sal=0.8, KpotCl,SCN=2.0 and KpotCl,ClO4=0.8. Furthermore, since the silicone rubber-matrix membrane exhibits better adhesion to the solid surface than do PVC membranes, the lifetime of the coated-wire type membrane electrode is greatly improved. The response properties toward chloride and salicylate for solid-state sensor are not significantly changed after at least 35 days of use.

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Geochemistry of Orthogneisses in the Seungju-Suncheon Area, Korea (승주-순천 지역에 분포하는 정편마암류의 지구화학적 특성)

  • Ahn, Kun-Sang;Oh, Chang-Whan;Park, Bae-Young
    • Journal of the Korean earth science society
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    • v.22 no.3
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    • pp.163-178
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    • 2001
  • Granite gneiss, pophyroblastic gneiss and leucocratic gneiss are widely distributed in the Seungju-Suncheon area, the southwestern part of the Sobacksan Massif, Korea. These orthogneisses show intrusive relationships in outcrops of the study area. This study focuses on the geochemical properties and the tectonic environments for the original rocks of these orthogneisses. The pophyroblastic gneiss is plotted in diorite and granodiorite domain, and granite gneiss and leucocratic gneiss are plotted in both of granodiorite and granite domains on lUGS silica-alkali diagram. Geochemical properies of major elements suggest that these rocks are sub-alkali rock series, and were formed from S-type magma which generated in syn-collision tectonic environment. Discrimination diagrams using HFS elements suggest that original rocks of the three orthogneisses were granitoid of calc-alkali rock series, and were formed in syn-collision environment.

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Secondary Ion Man Spectrometry: Theory rind Applications in Geosciences (이차이온질량분석기의 원리와 지질학적 응용)

  • 최변각
    • The Journal of the Petrological Society of Korea
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    • v.10 no.3
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    • pp.222-232
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    • 2001
  • Secondary ion mass spectrometry (SIMS) uses focused high-speed primary ions to produce secondary ions from sample surface that are analyzed through a mass filter. SIMS is often called as ion microprobe, since it offers a micrometer-scale spatial resolution. Although the precision and accuracy of SIMS are not as good as many conventional mass spectrometers, it has several advantages such as small sample-size requirement, high spatial resolution and capability of in-situ analysis. In the field of geochemistry/cosmochemistry, SIMS is widely used for (1) stable isotope geochemistry of H, C, O, S, etc., (2) geochronology of U/Th-bearing minerals, (3) lateral distribution of trace elements in a mineral, and (4) discovery of presolar grains and investigation of their isotopic compositions.

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펄스 레이저 증착 방법으로 성장한 InGaZnO4 박막의 물리적 특성 연구

  • Hwang, Eun-Sang;Seo, Yu-Seong;Park, Su-Hwan;Bae, Jong-Seong;An, Jae-Seok;Hwang, Jeong-Sik;Park, Seong-Gyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.74-74
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    • 2011
  • 최근 새로운 형태의 디스플레이에 관한 관심이 집중되고 있다. 이들 중 특히 투명 산화물 반도체는 기존의 실리콘 기반의 반도체에 비해 가시광 영역에서 높은 투과도를 보이며, 또한 기존의 비정질 실리콘 소자에 비해서 10 cm2/Vs이상의 높은 전하 이동도 값을 가진다. 본 연구에서는 투명 산화물 반도체 소재 중 InGaZnO4를 사용하여 펄스 레이저 방법으로 Al2O3 (0001)기판 위에 비정질 상태인 a-InGaZnO4 박막을 성장 시켰다. 박막의 증착 온도를 변화(RT, $50^{\circ}C$, $150^{\circ}C$, $250^{\circ}C$, $450^{\circ}C$, $550^{\circ}C$)시켜 성장된 박막의 구조적, 화학적, 전기적 그리고 광학적 특성을 조사하였다. 증착 온도가 $450{\sim}550^{\circ}C$ 사이에서 박막의 상태가 비정질(amorphous)에서 polycrystalline으로 성장되는 것을 X-Ray Diffraction과 Field Emission-Scanning Electron Microscope를 이용하여 확인하였고 이는 InGaZnO4 박막의 결정화 온도가 $450^{\circ}C$ 이상임을 알 수 있었다. X-ray Photoelectron Spectroscopy를 통해서 target 물질과 성장된 박막의 조성 및 화학적 상태를 고찰한 결과, 박막의 결정성 변화가 화학적 상태 변화와는 무관하다는 사실을 알 수 있었다. 온도 의존 비저항 측정을 통해 박막이 반도체 성향을 가지는 것을 확인 하였다. 또한 Hall 측정 결과 증착 온도가 올라 갈수록 전하 밀도는 증가 하지만, 전하 이동도는 다결정 박막($550^{\circ}C$)에서 급격히 감소하고, 이로 인해 비저항 값이 크게 증가함을 알 수 있었다. 이는 다결정 박막 내 존재하는 grain boundary들이 이동도 값에 영향을 준다는 것으로 추측할 수 있다. Ultra violet-Visible-Near Infrared 측정을 통해 가시광 영역에서 80%이상의 투과율을 나타내며 증착 온도가 증가함에 따라 에너지 밴드갭(Eg)이 커지는 것을 확인 할 수 있는데 이는 Hall 측정 결과에서 확인한 전하 밀도의 증가로 인해 에너지 밴드갭이 커지는 Burstein-Moss 효과로 설명할 수 있다.

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